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US4983470A Expired / Lapsed US ⏱️ 0.0 years remaining

Protective material for molten carbonate fuel cell

Assignee: Mitsubishi Electric Corp
•
Filing: 1990-02-28
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Granted: 1991-01-08
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Expires: 2010-02-28
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Abstract

Abstract A protective material for a molten carbonate fuel cell, which comprises a ceramic comprising an oxide material capable of chemically reacting with an electrolyte used in the molten carbonate fuel cell for generating electric energy by consuming hydrogen formed from a raw fuel such as hydrocarbons, or with a substance formed from the electrolyte. The protective material protects a reforming catalyst or component materials of the fuel cell power generation system from the electrolyte or the substance formed from the electrolyte.

Inventors

  • 👤 Hiroshi Kimura
  • 👤 Kazunao Sato
  • 👤 Mitsuie Matsumura
  • 👤 Chika Hirai

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 22:20
CPC Classifications
H; H01; H01M; H01M8/00; H01M8/06; H01M8/0606; H01M8/0612; H01M8/0625; H01M8/02; H01M8/14; H01M2008/147; H01M2300/00; H01M2300/0017; H01M2300/0048; H01M2300/0051; H01M8/24; H01M8/249; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 78 words
A molten carbonate fuel cell including a protective material for use in protecting components of said fuel cell from a carbonate electrolyte or a substance formed from a carbonate electrolyte, the protective material comprising a ceramic formed from an oxide material chemically reactive with a carbonate electrolyte or with a substance formed from the electrolyte, the oxide material including at least one substance having a melting point lower than the temperature at which the fuel cell is used.
Claim 2
Dependent Claim 78 words
A molten carbonate fuel cell including a protective material for use in protecting components of said fuel cell from a carbonate electrolyte or a substance formed from a carbonate electrolyte, the protective material comprising a ceramic formed from an oxide material chemically reactive with a carbonate electrolyte or with a substance formed from the electrolyte, the oxide material including at least one substance having a melting point lower than the temperature at which the fuel cell is used.
Claim 3
Dependent Claim 21 words
A molten carbonate fuel cell as set forth in claim 1 wherein the oxide material is in the form of pellets.
Claim 4
Dependent Claim 24 words
A molten carbonate fuel cell as set forth in claim 1 wherein the oxide material comprises TiO 2 and B 2 O 3 .
Claim 5
Dependent Claim 24 words
A molten carbonate fuel cell as set forth in claim 1 wherein the oxide material comprises SiO 2 and B 2 O 3 .
Claim 6
Dependent Claim 27 words
A molten carbonate fuel cell as set forth in claim 1 wherein the oxide material comprises TiO 2 , SiO 2 and B 2 O 3 .
Claim 7
Dependent Claim 20 words
A molten carbonate fuel cell as set forth in claim 1 wherein said components comprise at least a reforming catalyst.
Claim 8
Dependent Claim 83 words
A molten carbonate fuel cell including a protective material for use in protecting components of said fuel cell from a carbonate electrolyte or a substance formed from a carbonate electrolyte, the protective material comprising an oxide material chemically reactive with a carbonate electrolyte or with a substance formed from the electrolyte, the oxide material including B 2 O 3 and at least one of TiO 2 , SiO 2 , MoO 3 , WO 3 , ZrO 2 , and GeO 2 .
Claim 9
Dependent Claim 83 words
A molten carbonate fuel cell including a protective material for use in protecting components of said fuel cell from a carbonate electrolyte or a substance formed from a carbonate electrolyte, the protective material comprising an oxide material chemically reactive with a carbonate electrolyte or with a substance formed from the electrolyte, the oxide material including B 2 O 3 and at least one of TiO 2 , SiO 2 , MoO 3 , WO 3 , ZrO 2 , and GeO 2 .
Claim 10
Dependent Claim 21 words
A molten carbonate fuel cell as set forth in claim 7 wherein the oxide material is in the form of pellets.
Claim 11
Dependent Claim 24 words
A molten carbonate fuel cell as set forth in claim 7 wherein the oxide material comprises TiO 2 and B 2 O 3 .
Claim 12
Dependent Claim 24 words
A molten carbonate fuel cell as set forth in claim 7 wherein the oxide material comprises SiO 2 and B 2 O 3 .
Claim 13
Dependent Claim 27 words
A molten carbonate fuel cell as set forth in claim 7 wherein the oxide material comprises TiO 2 , SiO 2 and B 2 O 3 .
Claim 14
Dependent Claim 72 words
A molten carbonate fuel cell including a protective material for use in protecting components of said fuel cell from a carbonate electrolyte or a substance formed from a carbonate electrolyte, the protective material comprising a ceramic formed from an oxide material chemically reactive with a carbonate electrolyte or with a substance formed from the electrolyte, the oxide material containing about 2% to about 50% by weight of B 2 O 3 .
Claim 15
Dependent Claim 72 words
A molten carbonate fuel cell including a protective material for use in protecting components of said fuel cell from a carbonate electrolyte or a substance formed from a carbonate electrolyte, the protective material comprising a ceramic formed from an oxide material chemically reactive with a carbonate electrolyte or with a substance formed from the electrolyte, the oxide material containing about 2% to about 50% by weight of B 2 O 3 .
Claim 16
Dependent Claim 21 words
A molten carbonate fuel cell as set forth in claim 12 wherein the oxide material is in the form of pellets.
Claim 17
Dependent Claim 24 words
A molten carbonate fuel cell as set forth in claim 12 wherein the oxide material comprises TiO 2 and B 2 O 3 .
Claim 18
Dependent Claim 24 words
A molten carbonate fuel cell as set forth in claim 12 wherein the oxide material comprises SiO 2 and B 2 O 3 .
Claim 19
Dependent Claim 27 words
A molten carbonate fuel cell as set forth in claim 12 wherein the oxide material comprises TiO 2 , SiO 2 and B 2 O 3 .
Claim 20
Independent Claim 74 words
A method of protecting components of a molten carbonate fuel cell from a carbonate electrolyte or a substance formed from a carbonate electrolyte comprising placing in a molten carbonate fuel cell a ceramic formed from an oxide material chemically reactive with a carbonate electrolyte or a substance formed from the electrolyte, the oxide material including at least one substance having a melting point lower than the temperature at which the fuel cell is used.
Claim 21
Independent Claim 74 words
A method of protecting components of a molten carbonate fuel cell from a carbonate electrolyte or a substance formed from a carbonate electrolyte comprising placing in a molten carbonate fuel cell a ceramic formed from an oxide material chemically reactive with a carbonate electrolyte or a substance formed from the electrolyte, the oxide material including at least one substance having a melting point lower than the temperature at which the fuel cell is used.
Claim 22
Dependent Claim 30 words
A method of protecting components of a molten carbonate fuel cell as set forth in claim 17 wherein the ceramic is interposed between an electrolyte matrix and a reforming catalyst.

References Cited (Backward Citations)

US4182795A Cited
US4437192A Cited
US4774152A Cited
US4788110A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-01-07 1994-07-09 1995-01-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-01-07 1998-07-09 1999-01-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-01-07 2002-07-09 2003-01-08 $7700.00 Window Closed / Lapsed

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