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US4981908A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic elastomer blends

Assignee: EIDP Inc
•
Filing: 1988-02-02
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Granted: 1991-01-01
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Expires: 2008-02-02
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Abstract

Abstract Blends of 20-99 parts by weight of a multi-block copolyester thermoplastic elastomer melting above 100° C. with 80-1 parts by weight of a polyacrylate elastomer.

Inventors

  • 👤 James R. Wolfe, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 14:45
CPC Classifications
C; C08; C08L; C08L33/00; C08L33/04; C08L33/06; C08L33/08; C08L67/00; C08L67/02; C08L67/025

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 241 words
A thermoplastic composition comprising about 20-99 parts by weight total polymers of a thermoplastic multi-block copolyester elastomer melting above 100° C. consisting essentially of (A) repeating high melting point blocks comprising repeating short chain ester units having the formula ##STR6## wherein D is a divalent radical remaining after removal of hydroxyl groups from a low molecular weight diol having a molecular weight not greater than 250 and R is a divalent radical remaining after the removal of carboxyl groups from a dicarboxylic acid having a molecular weight not greater than 300, D and R being selected so that a polymer which consists essentially of short chain ester units having a number average molecular weight of at least 5000 has melting points above 100° C., (B) repeating low melting point blocks which are derived from compounds containing hydroxyl or carboxyl groups or mixtures thereof having number average molecular weights of 400-4000 and melting points not greater than 100° C., and (C) an amount of difunctional radicals sufficient to join repeating blocks of (A) and (B) to form multi-block copolymer elastomers, the weight ratio of (A) to (B) being from about 1:4 to 1:0.1, and from 1-80 parts by weight total polymers of a polyacrylate elastomer consisting essentially of repeating units of the structures selected from ##STR7## where n is 2 or 4 and m is 1 or 2 and up to 5 weight percent, based on polyacrylate elastomer, of a cure-site monomer.
Claim 2
Dependent Claim 241 words
A thermoplastic composition comprising about 20-99 parts by weight total polymers of a thermoplastic multi-block copolyester elastomer melting above 100° C. consisting essentially of (A) repeating high melting point blocks comprising repeating short chain ester units having the formula ##STR6## wherein D is a divalent radical remaining after removal of hydroxyl groups from a low molecular weight diol having a molecular weight not greater than 250 and R is a divalent radical remaining after the removal of carboxyl groups from a dicarboxylic acid having a molecular weight not greater than 300, D and R being selected so that a polymer which consists essentially of short chain ester units having a number average molecular weight of at least 5000 has melting points above 100° C., (B) repeating low melting point blocks which are derived from compounds containing hydroxyl or carboxyl groups or mixtures thereof having number average molecular weights of 400-4000 and melting points not greater than 100° C., and (C) an amount of difunctional radicals sufficient to join repeating blocks of (A) and (B) to form multi-block copolymer elastomers, the weight ratio of (A) to (B) being from about 1:4 to 1:0.1, and from 1-80 parts by weight total polymers of a polyacrylate elastomer consisting essentially of repeating units of the structures selected from ##STR7## where n is 2 or 4 and m is 1 or 2 and up to 5 weight percent, based on polyacrylate elastomer, of a cure-site monomer.
Claim 3
Dependent Claim 37 words
The composition of claim 1 wherein the polyacrylate elastomer is not crosslinked and the composition contains about 70-99 parts by weight total polymers of multi-block copolyester elastomer and 30-1 parts by weight total polymers of polyacrylate elastomer.
Claim 4
Dependent Claim 34 words
The composition of claim 1 wherein crosslinking agent is present and crosslinking of the polyacrylate elastomer took place during mixing and shearing and said crosslinked polyacrylate elastomer is dispersed in the multi-block copolyester elastomer.
Claim 5
Dependent Claim 28 words
The composition of claim 3 comprising 30-70 parts by weight total polymers of a multi-block copolyester elastomer and 70-30 parts by weight total polymers of a polyacrylate elastomer.
Claim 6
Dependent Claim 36 words
The composition of claim 1 wherein the copolyester has high melting point blocks derived from ethylene glycol or 1,4-butanediol and terephthalic acid or mixtures thereof containing up to about 30% by weight isophthalic or phthalic acid.
Claim 7
Dependent Claim 35 words
The composition of claim 1 wherein the copolyester has low melting point blocks derived from poly(alkylene oxide) glycols having a carbon-to-oxygen ratio of about 2.0-4.3 and a number average molecular weight of from about 400-4000.
Claim 8
Dependent Claim 24 words
The composition of claim 6 wherein the poly(alkylene oxide) glycol is poly(tetramethylene oxide) glycol having a number average molecular weight of from about 600-2000.
Claim 9
Dependent Claim 34 words
The composition of claim 6 wherein the poly(alkylene oxide) glycol is ethylene oxide capped poly(propylene oxide) glycol having a number average molecular weight of 1500-2800 and an ethylene oxide content of 15-35% by weight.
Claim 10
Dependent Claim 16 words
The composition of claim 1 wherein the low melting point blocks are derived from polyester glycols.
Claim 11
Dependent Claim 25 words
The composition of claim 9 wherein the polyester glycol is poly(tetramethylene adipate) glycol or polycaprolactone glycol having a number average molecular weight of from 800-2500.
Claim 12
Dependent Claim 19 words
The composition of claim 2 wherein the polyacrylate elastomer is based on repeating units principally of the structure ##STR8##

References Cited (Backward Citations)

US4275180A Cited
WO1986004913A1 Cited
US4629761A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-12-31 1994-07-02 1995-01-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-12-31 1998-07-02 1999-01-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-12-31 2002-07-02 2003-01-01 $7700.00 Window Closed / Lapsed

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