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US4981773A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for stabilization of organic base substances against light

Assignee: Fujifilm Corp
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Filing: 1988-09-12
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Granted: 1991-01-01
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Expires: 2008-09-12
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Abstract

Abstract The present invention relates to a method of stabilizing an organic base substance having an absorption mixture in the range of from about 300 nm to about 200 nm, against light, by combining the organic substance and at least one complex of formulae (I), (II) or (III): ##STR1## in which each of R 1 to R 5 , R 10 to R 14 and R 17 to R 21 , each of which may be the same or different within an individual compound, represents a halogen atom, a hydrogen atom, or an alkyl, aryl, cycloalkyl or heterocyclic group which is bonded to the carbon atom on the benzene ring directly or indirectly via a divalent linking group, and these may be same or different and the adjacent substituents may be bonded together to form a ring; R 6 and R 7 each represents an alkyl group or an aryl group, and these may be the same or different; R 8 , R 9 , R 15 , R 16 , R 22 and R 23 each represents a hydrogen atom, an alkyl group, an aryl group or a cyano group, and these may be same or different; and R 8 and R 9 , R 15 and R 16 , and R 22 and R 23 may be bonded together to form a ring. The method is especially effective for stabilizing colors and dyes in color photographic materials, against light, without adversely affecting the hue and purity of the colors and dyes.

Inventors

  • 👤 Yoshiaki Suzuki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 10:58
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/392; G03C7/39208; G03C7/39284

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 257 words
A method of stabilizing an organic base substance, which has an absorption maximum in the range of about 300 nm to about 2,000 nm, against light, which comprises combining said organic substance which is selected from the group consisting of a water-soluble dye and an insoluble dye and at least one complex of the following formulae(I), (II) or (III): ##STR14## ##STR15## in which each of R 1 to R 5 , each of R 10 and R 14 and each of R 17 to R 21 , each of which may be the same or different within an individual compound, represents a halogen atom, a hydrogen atom, or an alkyl, aryl, cocloalkyl or heterocyclic group which is bonded to the carbon atom on the benzene right directly or indirectly via a divalent linking group, and adjacent substituents of R 1 to R 5 , R 10 to R 14 , and R 17 to R 21 may be bonded together to form a ring; R 6 and R 7 each represents an alkyl group or an aryl group, and these may be the same or different; R 8 , R 9 , R 15 , R 16 , R 22 and R 23 each represents a hydrogen atom, an alkyl group, an aryl group or a cyano group, and these may be the same or different within an individual compound; and R 8 and R 9 , R 15 and R 16 , and R 22 and R 23 may be bonded together to form a ring.
Claim 2
Independent Claim 257 words
A method of stabilizing an organic base substance, which has an absorption maximum in the range of about 300 nm to about 2,000 nm, against light, which comprises combining said organic substance which is selected from the group consisting of a water-soluble dye and an insoluble dye and at least one complex of the following formulae(I), (II) or (III): ##STR14## ##STR15## in which each of R 1 to R 5 , each of R 10 and R 14 and each of R 17 to R 21 , each of which may be the same or different within an individual compound, represents a halogen atom, a hydrogen atom, or an alkyl, aryl, cocloalkyl or heterocyclic group which is bonded to the carbon atom on the benzene right directly or indirectly via a divalent linking group, and adjacent substituents of R 1 to R 5 , R 10 to R 14 , and R 17 to R 21 may be bonded together to form a ring; R 6 and R 7 each represents an alkyl group or an aryl group, and these may be the same or different; R 8 , R 9 , R 15 , R 16 , R 22 and R 23 each represents a hydrogen atom, an alkyl group, an aryl group or a cyano group, and these may be the same or different within an individual compound; and R 8 and R 9 , R 15 and R 16 , and R 22 and R 23 may be bonded together to form a ring.
Claim 3
Dependent Claim 42 words
The method as in claim 1, wherein the dye is a quinoneimine dye, a methine or polymethine dye, an azo dye, an anthraquinone dye, an indoamine or indophenol dye, an indigoid dye, a carbonium dye, a formazane dye or a pyrazolazole dye.
Claim 4
Dependent Claim 42 words
The method as in claim 1, wherein the organic base substance to be stabilized in a polymer is selected from the group consisting of polyolefins, polyamides, polydienes, polyvinyl chlorides, polyacrylic acids, polystyrenes, polyvinyl alcohols, polyesters, polyethers, polyurethanes, polyacetals, polycarbonates and polyphenylene oxides.
Claim 5
Dependent Claim 20 words
The method as in claim 3, wherein the polymer is selected from the group consisting of polyolefins, polydienes and polystyrenes.
Claim 6
Dependent Claim 24 words
The method as in claim 1, wherein the organic base substance to be stabilized is an image-forming dye for use in a photographic field.
Claim 7
Dependent Claim 29 words
The method as in claim 5, wherein the image-forming dye is derived from color couplers, DRR compounds, DRR couplers, amidorazone compounds, dye couplers or dyes for silver dye-bleaching process.
Claim 8
Dependent Claim 17 words
The method as in claim 6, wherein the color couplers are yellow, magenta or cyan dye-forming couplers.
Claim 9
Dependent Claim 376 words
The method as in claim 7, wherein the couplers are selected from the group consisting of compounds of the following formulae (IV), (V), (VI) and (VII): ##STR16## in which R 24 , R 25 , R 26 and R 27 each represents a hydrogen atom, a halogen atom, an alkyl group, a carbamoyl group, a sulfamoyl group, an amido group, a sulfonamido group, a phosphoric acid amido group or an ureido group; R 24 and R 26 may be bonded together to form a 6-membered ring; X 1 represents a hydrogen atom, a halogen atom or a group capable of being released by reaction with an oxidation product of a developing agent; ##STR17## in which R 28 represents an alkyl group, an aryl group, an acyl group or a carbamoyl group; Ar represents an unsubstituted phenyl group or a phenyl group substituted by one or more substituents selected from a halogen atom, an alkyl group, a cyano group, an alkoxy group, an alkoxycarbonyl group and an acylamino group; X 2 represents a hydrogen atom or a group capable of being released by reaction with the oxidation product of an aromatic primary amine color developing agent; the formula may form a dimer or a higher polymer at the position of Rzs, Ar or Xz; ##STR18## in which R 29 represents a hydrogen atom or a substituent; X 2 represents a hydrogen atom or a group capable of being released by reaction with the oxidation product of an aromatic primary amine color developing agent; X 3 , X 4 and X 5 each represents ##STR19## --N═or --NH--, and one of X 5 --X 4 bond and X 4 --X 3 bond is a double bond and the other is a single bond, and when X 4 --X 3 is a carbon-carbon double bond, this may be a part of an aromatic ring; the formula may form a dimer or a higher polymer at the position of R 29 or X 2 ; ##STR20## in which R 3 o represents an alkyl group or an aryl group; R 31 represents an aryl group; X 6 represents a hydrogen atom, a halogen atom or a group capable of being released by reaction with the oxidation product of a developing agent.
Claim 10
Dependent Claim 22 words
The method as in claim 1, wherein the alkyl group for R 1 to R 23 has 1 to 20 carbon atoms.
Claim 11
Dependent Claim 34 words
The method as in claim 1, wherein the aryl group for R 1 to R 5 , R 10 to R 14 and R 17 to R 21 has 6 to 14 carbon atoms.
Claim 12
Dependent Claim 37 words
The method as in claim 1, wherein the heterocyclic group or the cycloalkyl group for R 1 to R 5 , to R 14 and R 17 to R 21 is a 5-membered or a 6-membered group.
Claim 13
Dependent Claim 48 words
The method as in claim 1, wherein the alkyl group for R 1 to R 5 , R 10 to R 14 and R 17 to R 21 is selected from the group consisting of methyl, ethyl, propyl, butyl, hexyl, octyl, decyl, dodecyl, tetradecyl, hexadecyl and octadecyl groups.
Claim 14
Dependent Claim 38 words
The method as in claim 1, wherein the aryl group for R 1 to R 5 , R 10 to R 14 and R 17 to R 21 is selected from the group consisting of phenyl and napthyl.
Claim 15
Dependent Claim 48 words
The method as in claim 1, wherein the heterocyclic group for R 1 to R 5 , R 10 to R 14 and R 17 to R 21 is selected from the group consisting of furyl, hedrofuryl, thienyl, pyrrolyl, pyrrolidiyl, pyridyl, imidazolyl, pyrazolyl, quinolyl, indolyl, oxazlyl and thiazolyl.
Claim 16
Dependent Claim 40 words
The method as in claim 1, wherein the cycloalkyl group for R 1 to R 5 , R 10 to R 14 and R 17 to R 21 is selected form the group consisting of cyclopentyl, cyclohexyl, cyclohexenyl, and cyclohexadienyl.
Claim 17
Dependent Claim 35 words
The method as in claim 1, wherein the aryl group for R 6 to R 9 , R 15 , R 16 , R 22 and R 23 is a substituted or unsubstituted phenyl group.
Claim 18
Dependent Claim 42 words
The method as in claim 2, wherein the dye is selected from the group consisting of methine, polymethine, indoamine and indophenol, said dyes having the following group: ##STR21## wherein the phenyl group is an unsubstituted phenyl group or a substituted phenyl group.

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