Benzotriazole and oxanilide UV absorber hydrazides

Claim 2

A polymeric compound comprising the reaction product of a polymer containing (a) at least one ester, epoxide or anhydride functional group, or combinations thereof, in the polymer backbone, on grafted side chains, as a pendant unit or combinations thereof and (b) a compound of formula ##STR11## where R 1 is hydrogen, substituted or unsubstituted aliphatic of 1-8 carbons, substituted or unsubstituted alkoxy of 1-8 carbons, substituted or unsubstituted alkoxycarbonyl of 2-8 carbons, alkylaminocarbonyl of 2-5 carbons, dialkylaminocarbonyl of 3-9 carbons, substituted or unsubstituted N-(alkyl)-N-(aryl)aminocarbonyl of 8-15 carbons, alkoxysulfonyl of 1-4 carbons, --C(═O)--OH--, --C(═O)NH 2 , or --S(═O) 2 --OH; R 2 is hydrogen, substituted or unsubstituted aliphatic of 1-8 carbons, substituted or unsubstituted aryl of 6-14 carbons, substituted or unsubstituted araliphatic of 7-22 carbons, substituted or unsubstituted alkoxy of 1-8 carbons, alkylaminocarbonyl of 2-5 carbons, dialkylaminocarbonyl of 3-9 carbons, or substituted or unsubstituted N-(alkyl)-N-(aryl)aminocarbonyl of 8-15 carbons; R 3 is hydrogen, substituted or unsubstituted aliphatic of 1-20 carbons, substituted or unsubstituted araliphatic of 7-22 cartons, or substituted or unsubstituted alicyclic of 5-12 carbons;

Claim 3

R 4 , R 5 , R 6 and R 7 are independently hydrogen, hydroxy, substituted or unsubstituted aliphatic of 1-8 carbons, substituted or unsubstituted aryl of 6-14 carbons, substituted or unsubstituted araliphatic of 7-22 carbons, substituted or unsubstituted alkoxy of 1-12 carbons or substituted or unsubstituted alkylthio of 1-12 carbons, chloro, bromo, or substituted or unsubstituted alkoxycarbonyl or 2-8 carbons; X is X a when attached to ring A, X b when attached to ring B and X e when attached either ring E; X a is a direct bond; X b and X e are divalent radicals of formula --Z x --R 8 --{--N(R 9 )═O)] y --R 10 --) z --; Z is --O--, --N(R 11 )--, --S--, or --S(═O) 2 --; x and z are independently 1; y is independently 0 or 1; R 8 is a direct bond or substituted or unsubstituted alkylene diradical of 1-4 carbons; R 9 is hydrogen, substituted or unsubstituted aliphatic of 1-20 carbons, substituted or unsubstituted alicyclic of 5-12 carbons, substituted or unsubstituted aryl of 6-14 carbons, or substituted or unsubstituted araliphatic of 7-22 carbons; R 10 is a direct bond, substituted or unsubstituted aliphatic diradical of 1-20 carbons, substituted or unsubstituted aryl diradical of 6-12 carbons, substituted or unsubstituted alicyclic diradical of 5-12 carbons, or substituted or unsubstituted araliphatic diradical of 7-22 carbons; R 11 is hydrogen, substituted or unsubstituted aliphatic of 1-20 carbons, substituted or unsubstituted alicyclic of 5-12 carbons, substituted or unsubstituted aryl of 6-14 carbons, or substituted or unsubstituted araliphatic of 7-22 carbons; n is 1; Y is ##STR12## R 12 is hydrogen; R 13 is hydrogen, substituted or unsubstituted aliphatic of 1-20 carbons, substituted or unsubstituted alicyclic of 5-12 carbons, substituted or unsubstituted aryl of 6-14 carbons, or substituted or unsubstituted araliphatic of 7-22 carbons, and when alicyclic, R 13 may optionally contain 1-6 heteroatoms --O--, --S-- or --N(R 21 )--, with the proviso that multiple heteroatoms must be separated from each other and the chain ends by at least one carbon atom; Q is a direct bond between the nitrogen and R 13 ; R 21 is hydrogen, aliphatic of 1 to 8 carbons, aliphatic acyl of 2-6 carbons, or substituted or unsubstituted benzoyl; optional substituents for R 1 , R 2 , R 3 , R 8 , R 9 , R 10 , R 11 , R 13 and R 21 are independently one or more of the following: chloro, bromo, alkyl of 1-4 carbons, alkoxy of 1-8 carbons, phenoxy, cyano, hydroxy, epoxy, carboxy, alkyoxycarbonyl of 2-6 carbons, acyloxy of 1-4 carbons, acryloyl, acryloyoxy, methacryloyl, methacryloyoxy, hydroxymethyl, hydroxyethyl, alkylthio of 1-4 carbons or trialkoxysilyl of 3-12 carbons; and additional optional substituents for R 13 are aliphatic of 1-20 carbons, cycloaliphatic of 5-12 carbons, aryl of 6-14 carbons, aralkyl of 7-22 carbons, alkoxy of 1-20 carbons, cycloalkoxy of 5-12 carbons, aryloxy of 6-14 carbons, aralkoxy of 7-15 carbons, aliphatic acyloxy of 2-20 carbons, alicyclic acyloxy of 6-13 carbons, aryl acyloxy of 7-15 carbons, or araliphatic acyloxy of 8-16 carbons.

Claim 4

R 4 , R 5 , R 6 and R 7 are independently hydrogen, hydroxy, substituted or unsubstituted aliphatic of 1-8 carbons, substituted or unsubstituted aryl of 6-14 carbons, substituted or unsubstituted araliphatic of 7-22 carbons, substituted or unsubstituted alkoxy of 1-12 carbons or substituted or unsubstituted alkylthio of 1-12 carbons, chloro, bromo, or substituted or unsubstituted alkoxycarbonyl or 2-8 carbons; X is X a when attached to ring A, X b when attached to ring B and X e when attached either ring E; X a is a direct bond; X b and X e are divalent radicals of formula --Z x --R 8 --{--N(R 9 )═O)] y --R 10 --) z --; Z is --O--, --N(R 11 )--, --S--, or --S(═O) 2 --; x and z are independently 1; y is independently 0 or 1; R 8 is a direct bond or substituted or unsubstituted alkylene diradical of 1-4 carbons; R 9 is hydrogen, substituted or unsubstituted aliphatic of 1-20 carbons, substituted or unsubstituted alicyclic of 5-12 carbons, substituted or unsubstituted aryl of 6-14 carbons, or substituted or unsubstituted araliphatic of 7-22 carbons; R 10 is a direct bond, substituted or unsubstituted aliphatic diradical of 1-20 carbons, substituted or unsubstituted aryl diradical of 6-12 carbons, substituted or unsubstituted alicyclic diradical of 5-12 carbons, or substituted or unsubstituted araliphatic diradical of 7-22 carbons; R 11 is hydrogen, substituted or unsubstituted aliphatic of 1-20 carbons, substituted or unsubstituted alicyclic of 5-12 carbons, substituted or unsubstituted aryl of 6-14 carbons, or substituted or unsubstituted araliphatic of 7-22 carbons; n is 1; Y is ##STR12## R 12 is hydrogen; R 13 is hydrogen, substituted or unsubstituted aliphatic of 1-20 carbons, substituted or unsubstituted alicyclic of 5-12 carbons, substituted or unsubstituted aryl of 6-14 carbons, or substituted or unsubstituted araliphatic of 7-22 carbons, and when alicyclic, R 13 may optionally contain 1-6 heteroatoms --O--, --S-- or --N(R 21 )--, with the proviso that multiple heteroatoms must be separated from each other and the chain ends by at least one carbon atom; Q is a direct bond between the nitrogen and R 13 ; R 21 is hydrogen, aliphatic of 1 to 8 carbons, aliphatic acyl of 2-6 carbons, or substituted or unsubstituted benzoyl; optional substituents for R 1 , R 2 , R 3 , R 8 , R 9 , R 10 , R 11 , R 13 and R 21 are independently one or more of the following: chloro, bromo, alkyl of 1-4 carbons, alkoxy of 1-8 carbons, phenoxy, cyano, hydroxy, epoxy, carboxy, alkyoxycarbonyl of 2-6 carbons, acyloxy of 1-4 carbons, acryloyl, acryloyoxy, methacryloyl, methacryloyoxy, hydroxymethyl, hydroxyethyl, alkylthio of 1-4 carbons or trialkoxysilyl of 3-12 carbons; and additional optional substituents for R 13 are aliphatic of 1-20 carbons, cycloaliphatic of 5-12 carbons, aryl of 6-14 carbons, aralkyl of 7-22 carbons, alkoxy of 1-20 carbons, cycloalkoxy of 5-12 carbons, aryloxy of 6-14 carbons, aralkoxy of 7-15 carbons, aliphatic acyloxy of 2-20 carbons, alicyclic acyloxy of 6-13 carbons, aryl acyloxy of 7-15 carbons, or araliphatic acyloxy of 8-16 carbons.

Claim 5

The polymeric compound of claim 1 which is a reaction product of the polymer and (2-[(phenylamino)-2-oxoacetamido]phenoxy)acetyl hydrazide.

Claim 6

The polymeric compound of claim 1 which is a reaction product of the polymer and 2-([2-hydroxy-3-(2H-benzotriazol-2-yl)-5-methylphenyl]methylamini)-2-oxoacetyl hydrazide.

Claim 7

The polymeric compound of claim 1 which is a reaction product of the polymer and 4-([2-hydroxy-3-(2H-benzotriazol-2-yl)-5-methylphenyl]methylamino)-4-oxobutanoyl hydrazide.