Color photographic recording material containing color couplers

Claim 2

A color photographic recording material comprising at least one silver halide emulsion layer unit and at least two non-diffusing magenta color couplers, one colorless and the other colored, associated with the silver halide emulsion layer unit, wherein the colored non-diffusing color coupler contains, attached to the coupling position, a diffusion-proofing primary ballast group attached through an azo group and being releasable during the color coupling reaction and optionally, in non-coupling positions, one or more secondary ballast groups so that a hydrophobic dye of limited mobility is formed in the color coupling reaction, wherein the colored color coupler is a magenta coupler corresponding to the following formula ##STR19## in which Ac is a acyl group containing in all at most 9 carbon atoms which does not contain an alkali-solubilizing group, the acyl group being derived from an aliphatic or aromatic carboxylic or sulfonic acid, a carbamic acid or a carbonic acid monoester; represents one, two or three alkyl groups which are attached directly or through --O--, --S--, --NH--CO or NH--SO 2 -- and which together contain in all at least 8carbon atoms; Y represents hydrogen, --OH, halogen; and Z represents hydrogen or one or more substituents selected from halogen, alkyl, alkoxy, alkylthio, acylamino, alkylsulfonyl and sulfonyl, the substituents mentioned together containing in all no more than 5 carbon atoms.

Claim 3

A recording material as claimed in claim 1, wherein the colorless non-diffusing color coupler and the colored non-diffusing color coupler are associated with a green-sensitive silver halide emulsion layer unit.

Claim 4

A recording material as claimed in claims 1 or 2, wherein the non-diffusing colorless color coupler is a magenta coupler corresponding to one of general formulae III, IV and V: ##STR20## in which R 3 represents alkyl, aryl or an amino group, including a cyclic amino group, optionally substituted by alkyl, aryl or acyl; R 4 represents alkyl, aralkyl or aryl; R 5 represents halogen, alkyl, alkoxy, aroxy, amino, acylamino, carbamoyl, sulfamoyl, alkylsulfonyl; n=1to 4; T represents hydrogen or a group releasable during the color coupling reaction; at least one of the substituents T, R 3 and R 4 (or R 5 ) containing a ballast group.

Claim 5

A recording material as claimed in claim 1, wherein the colorless magenta coupler and the colored magenta coupler are associated with a silver halide emulsion layer unit consisting of at least two partial silver halide emulsion layers having different sensitivity, but the same spectral sensitivity.

Claim 6

A recording material as claimed in claim 4, wherein at least one partial silver halide emulsion layer of relatively high sensitivity or a non-photosensitive intermediate layer arranged between a partial silver halide emulsion layer of relatively high sensitivity and a less sensitive partial silver halide emulsion layer of a green-sensitive silver halide emulsion layer unit contains a non-diffusing colorless magenta coupler and a non-diffusing colored magenta coupler corresponding to the following general formula ##STR21## in which Ac represents an acyl group containing in all at most 9 carbon atoms which does not contain an alkali-solubilizing group, the acyl group being derived from an aliphatic or aromatic carboxylic or sulfonic acid, a carbamic acid or a carbonic acid monoester; X represents one, two or three alkyl groups which are attached directly or through --O--, --S--, --NH--CO-- or NH--SO 2 -- and which together contain in all at least 8 carbon atoms; Y represents hydrogen, --OH, halogen; and Z represents hydrogen or one or more substituents selected from halogen, alkyl, alkoxy, alkylthio, acylamino, alkylsulfonyl and sulfonyl, the substituents mentioned together containing in all no more than 5 carbon atoms.

Claim 7

A recording material as claimed in claim 5, wherein the colored magenta coupler is present in all partial silver halide emulsion layers of a green-sensitive silver halide emulsion layer unit and all non-photosensitive intermediate layers arranged in between.

Claim 8

A color photographic recording material comprising at least one silver halide emulsion layer unit and at least two non-diffusing magenta color couplers, one colorless and the other colored, associated with the silver halide emulsion layer unit, wherein the colored non-diffusing color coupler contains, attached to the coupling position, a diffusion-proofing primary ballast group attached through an azo group and being releasable during the color coupling reaction and optionally, in non-coupling positions, one or more secondary ballast groups so that a hydrophobic dye of limited mobility is formed in the color coupling reaction, wherein the colored color coupler is a magenta coupler corresponding to the following formula ##STR22## in which Ac is a acyl group containing in all at most 9 carbon atoms which does not contain an alkali-solubilizing group, the acyl group being derived from an aliphatic or aromatic carboxylic or sulfonic acid, a carbamic acid or a carbonic acid monoester; X represents one, two or three alkyl groups which are attached directly or through --O--, --S--, --NH--CO or NH--SO 2 -- and which together contain in all at least 8 carbon atoms; Y represents hydrogen, --OH, halogen; and Z represents hydrogen or one or more substituents selected from halogen, alkyl, alkoxy, alkythio, acylamino, alkylsulfonyl and sulfonyl, the substituents mentioned together containing in all no more than 5 carbon atoms; wherein the non-diffusing colorless color coupler is a magenta coupler corresponding to one of general formulae IV or V: ##STR23## in which R 3 represents alkyl, aryl or an amino group, including a cyclic amino group, optionally substituted by alkyl, aryl or acyl; R 4 represents alkyl, aralkyl or aryl; R 5 represents halogen, alkyl, alkoxy, aroxy, amino, acylamino, carbamoyl, sulfamoyl, alkylsulfonyl; n=1 to 4; T represents hydrogen or a group releasable during the color coupling reaction; at least one of the substituents T, R 3 and R 4 (or R 5 ) containing a ballast group; and wherein the amount of the colored magenta color coupler is 21.8 to 25.2 mole percent based on the amount of all couplers in said layer.

Claim 9

A color photographic recording material comprising at least one silver halide emulsion layer unit and at least two non-diffusing magenta color couplers, one colorless and the other colored, associated with the silver halide emulsion layer unit, wherein the colored non-diffusing color coupler contains, attached to the coupling position, a diffusion-proofing primary ballast group attached through an azo group and being releasable during the color coupling reaction and optionally, in non-coupling positions, one or more secondary ballast groups so that a hydrophobic dye of limited mobility is formed in the color coupling reaction, wherein the colored color coupler is a magenta coupler corresponding to the following formula ##STR22## in which Ac is a acyl group containing in all at most 9 carbon atoms which does not contain an alkali-solubilizing group, the acyl group being derived from an aliphatic or aromatic carboxylic or sulfonic acid, a carbamic acid or a carbonic acid monoester; X represents one, two or three alkyl groups which are attached directly or through --O--, --S--, --NH--CO or NH--SO 2 -- and which together contain in all at least 8 carbon atoms; Y represents hydrogen, --OH, halogen; and Z represents hydrogen or one or more substituents selected from halogen, alkyl, alkoxy, alkythio, acylamino, alkylsulfonyl and sulfonyl, the substituents mentioned together containing in all no more than 5 carbon atoms; wherein the non-diffusing colorless color coupler is a magenta coupler corresponding to one of general formulae IV or V: ##STR23## in which R 3 represents alkyl, aryl or an amino group, including a cyclic amino group, optionally substituted by alkyl, aryl or acyl; R 4 represents alkyl, aralkyl or aryl; R 5 represents halogen, alkyl, alkoxy, aroxy, amino, acylamino, carbamoyl, sulfamoyl, alkylsulfonyl; n=1 to 4; T represents hydrogen or a group releasable during the color coupling reaction; at least one of the substituents T, R 3 and R 4 (or R 5 ) containing a ballast group; and wherein the amount of the colored magenta color coupler is 21.8 to 25.2 mole percent based on the amount of all couplers in said layer.