US4976315A
Expired / Lapsed
US
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Use of taurine additives in enhanced oil recovery with anionic surfactants
Assignee: Texaco Inc
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Filing: 1989-11-06
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Granted: 1990-12-11
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Expires: 2009-11-06
Abstract
Abstract A method is disclosed for increasing the recovery of oil in enhanced oil recovery operations employing anionic surfactant by blending a taurine with said anionic surfactant. The taurine may also increase the salt and divalent ion tolerance of the anionic surfactant.
Inventors
- 👤 Gabriel Prukop
- 👤 Chhiv K. Chea
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 17:35
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/58; C09K8/584; Y; Y10; Y10S; Y10S507/00; Y10S507/935; Y10S507/936
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR4## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 2
Dependent Claim
143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR4## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 3
Dependent Claim
11 words
The method of claim 1 wherein said taurine is 2-aminoethanesulfonic acid.
Claim 4
Dependent Claim
11 words
The method of claim 1 wherein said taurine is dimethyl taurine.
Claim 5
Independent Claim
100 words
A method for increasing the salt tolerance of an anionic surfactant for use in enhanced oil recovery operations, said method comprising blending an effective amount of a taurine with said anionic surfactant prior to said use, said taurine having the formula ##STR5## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 6
Independent Claim
100 words
A method for increasing the salt tolerance of an anionic surfactant for use in enhanced oil recovery operations, said method comprising blending an effective amount of a taurine with said anionic surfactant prior to said use, said taurine having the formula ##STR5## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 7
Independent Claim
101 words
A method for increasing the divalent ion tolerance of an anionic surfactant for use in enhanced oil recovery operations, said method comprising blending an effective amount of a taurine with said anionic surfactant prior to said use, said taurine having the formula ##STR6## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 8
Independent Claim
101 words
A method for increasing the divalent ion tolerance of an anionic surfactant for use in enhanced oil recovery operations, said method comprising blending an effective amount of a taurine with said anionic surfactant prior to said use, said taurine having the formula ##STR6## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 9
Dependent Claim
33 words
The method of claim 1, wherein said method comprises adding a taurine to said anionic surfactant in an amount greater than about 0.05% by weight but less than the amount of anionic surfactant.
Claim 10
Independent Claim
145 words
A method for recovering petroleum from a subterranean petroleum-bearing formation, penetrated by at least one injection well and at least one production well, said method comprising: injecting into said formation via said injection well an aqueous fluid comprising an effective amount of a taurine blended with an amount of an anionic surfactant system greater than the amount of taurine; said taurine having the formula ##STR7## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + , driving said aqueous fluid through said formation toward said production well; and recovering displaced oil from said formation via said production well.
Claim 11
Independent Claim
145 words
A method for recovering petroleum from a subterranean petroleum-bearing formation, penetrated by at least one injection well and at least one production well, said method comprising: injecting into said formation via said injection well an aqueous fluid comprising an effective amount of a taurine blended with an amount of an anionic surfactant system greater than the amount of taurine; said taurine having the formula ##STR7## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + , driving said aqueous fluid through said formation toward said production well; and recovering displaced oil from said formation via said production well.
Claim 12
Dependent Claim
37 words
The method of claim 1 wherein the concentration in said aqueous fluid of said taurine is less than about 2% by weight and the concentration of said anionic surfactant system is about 5% by weight or less.
Claim 13
Dependent Claim
14 words
The method of claim 1 wherein said drive fluid comprises a mobility control fluid.
Claim 14
Dependent Claim
143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR8## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 15
Dependent Claim
143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR8## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 16
Dependent Claim
143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR9## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 17
Dependent Claim
143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR9## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
References Cited (Backward Citations)
US3858656A
Cited
USRE29219E
Cited
US3939911A
Cited
US4008768A
Cited
US4076743A
Cited
GB2001377A
Cited
US4216097A
Cited
US4166038A
Cited
US4222881A
Cited
US4193452A
Cited
US4502540A
Cited
US4482634A
Cited
US4490676A
Cited
US4438045A
Cited
US4554974A
Cited
US4585065A
Cited
US4825950A
Cited
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