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US4976315A Expired / Lapsed US ⏱️ 0.0 years remaining

Use of taurine additives in enhanced oil recovery with anionic surfactants

Assignee: Texaco Inc
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Filing: 1989-11-06
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Granted: 1990-12-11
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Expires: 2009-11-06
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Abstract

Abstract A method is disclosed for increasing the recovery of oil in enhanced oil recovery operations employing anionic surfactant by blending a taurine with said anionic surfactant. The taurine may also increase the salt and divalent ion tolerance of the anionic surfactant.

Inventors

  • 👤 Gabriel Prukop
  • 👤 Chhiv K. Chea

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 17:35
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/58; C09K8/584; Y; Y10; Y10S; Y10S507/00; Y10S507/935; Y10S507/936

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR4## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 2
Dependent Claim 143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR4## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 3
Dependent Claim 11 words
The method of claim 1 wherein said taurine is 2-aminoethanesulfonic acid.
Claim 4
Dependent Claim 11 words
The method of claim 1 wherein said taurine is dimethyl taurine.
Claim 5
Independent Claim 100 words
A method for increasing the salt tolerance of an anionic surfactant for use in enhanced oil recovery operations, said method comprising blending an effective amount of a taurine with said anionic surfactant prior to said use, said taurine having the formula ##STR5## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 6
Independent Claim 100 words
A method for increasing the salt tolerance of an anionic surfactant for use in enhanced oil recovery operations, said method comprising blending an effective amount of a taurine with said anionic surfactant prior to said use, said taurine having the formula ##STR5## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 7
Independent Claim 101 words
A method for increasing the divalent ion tolerance of an anionic surfactant for use in enhanced oil recovery operations, said method comprising blending an effective amount of a taurine with said anionic surfactant prior to said use, said taurine having the formula ##STR6## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 8
Independent Claim 101 words
A method for increasing the divalent ion tolerance of an anionic surfactant for use in enhanced oil recovery operations, said method comprising blending an effective amount of a taurine with said anionic surfactant prior to said use, said taurine having the formula ##STR6## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 9
Dependent Claim 33 words
The method of claim 1, wherein said method comprises adding a taurine to said anionic surfactant in an amount greater than about 0.05% by weight but less than the amount of anionic surfactant.
Claim 10
Independent Claim 145 words
A method for recovering petroleum from a subterranean petroleum-bearing formation, penetrated by at least one injection well and at least one production well, said method comprising: injecting into said formation via said injection well an aqueous fluid comprising an effective amount of a taurine blended with an amount of an anionic surfactant system greater than the amount of taurine; said taurine having the formula ##STR7## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + , driving said aqueous fluid through said formation toward said production well; and recovering displaced oil from said formation via said production well.
Claim 11
Independent Claim 145 words
A method for recovering petroleum from a subterranean petroleum-bearing formation, penetrated by at least one injection well and at least one production well, said method comprising: injecting into said formation via said injection well an aqueous fluid comprising an effective amount of a taurine blended with an amount of an anionic surfactant system greater than the amount of taurine; said taurine having the formula ##STR7## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + , driving said aqueous fluid through said formation toward said production well; and recovering displaced oil from said formation via said production well.
Claim 12
Dependent Claim 37 words
The method of claim 1 wherein the concentration in said aqueous fluid of said taurine is less than about 2% by weight and the concentration of said anionic surfactant system is about 5% by weight or less.
Claim 13
Dependent Claim 14 words
The method of claim 1 wherein said drive fluid comprises a mobility control fluid.
Claim 14
Dependent Claim 143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR8## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 15
Dependent Claim 143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR8## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 16
Dependent Claim 143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR9## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .
Claim 17
Dependent Claim 143 words
In a method for recovering petroleum from a subterranean, petroleum-bearing formation penetrated by at least one injection well and at least one production well, said recovery method being of the type wherein an aqueous fluid comprising anionic surfactant is injected into the formation via the injection well, and oil displaced by the injected fluid is recovered from the formation via the production well, wherein the improvement comprises adding a taurine to said aqueous fluid comprising an anionic surfactant, said taurine having the following formula: ##STR9## wherein R 1 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, R 2 is selected from the group comprising hydrogen, a phenyl group, and alkyl groups having from about 1-4 carbon atoms, and X is selected from the group comprising NH 2 and NH 3 + .

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