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US4973702A Expired / Lapsed US ⏱️ 0.0 years remaining

2-(2-hydroxyphenyl)-benztriazoles

Assignee: BASF Corp
•
Filing: 1989-02-13
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Granted: 1990-11-27
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Expires: 2009-02-13
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Abstract

Abstract The novel UV-absorbers are compounds of the formula I ##STR1## in which R 1 is, for example, hydrogen, n is one of the numbers 1 or 2 and R 2 is an appropriate monovalent or divalent radical, for example --OH or --O--CH 2 CH 2 --O--. The UV-absorbers are used in particular for stabilising and improving lacquers and photographic material.

Inventors

  • 👤 Jean Rody
  • 👤 Mario Slongo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 19:55
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/815; G03C1/8155; C; C07; C07D; C07D249/00; C07D249/16; C07D249/18; C07D249/20; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3467; C08K5/3472; C08K5/3475; C09; C09D; C09D7/00; C09D7/40; C09D7/48; Y; Y10; Y10S; Y10S430/00; Y10S430/132

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 218 words
A compound of the formula I ##STR41## in which R 1 is H, Cl, straight-chain or branched C 1 -C 4 alkyl or straight-chain or branched C 1 -C 4 alkoxy and n is one of the numbers 1 or 2, and in which, (a) when n=1, R 2 is ##STR42## and (b) when n=2, R 2 is ##STR43## R 4 and R 5 independently of one another are H, straight-chain or branched C 1 -C 18 alkyl, straight-chain or branched C 3 -C 18 alkyl which is interrupted by O, S or --NR 6 --, C 5 -C 12 cycloalkyl, straight-chain or branched C 3 -C 8 alkenyl, C 7 -C 15 aralkyl, C 6 -C 14 aryl or C 1 -C 3 hydroxyalkyl, or R 4 and R 5 , together with the nitrogen atom, are a pyrrolidine, piperidine, piperazine or morpholine ring, R 6 is H, straight-chain or branched C 1 -C 18 alkyl, C 5 -C 12 cycloalkyl, straight-chain or branched C 3 -C 8 alkenyl, C 6 -C 14 aryl or C 7 -C 18 aralkyl, and R 10 is straight-chain or branched C 2 -C 12 alkylene which may be interrupted by --O--, cyclohexylene, ##STR44## or R 10 and R 6 , together with the two nitrogen atoms, are a piperazine ring.
Claim 2
Dependent Claim 218 words
A compound of the formula I ##STR41## in which R 1 is H, Cl, straight-chain or branched C 1 -C 4 alkyl or straight-chain or branched C 1 -C 4 alkoxy and n is one of the numbers 1 or 2, and in which, (a) when n=1, R 2 is ##STR42## and (b) when n=2, R 2 is ##STR43## R 4 and R 5 independently of one another are H, straight-chain or branched C 1 -C 18 alkyl, straight-chain or branched C 3 -C 18 alkyl which is interrupted by O, S or --NR 6 --, C 5 -C 12 cycloalkyl, straight-chain or branched C 3 -C 8 alkenyl, C 7 -C 15 aralkyl, C 6 -C 14 aryl or C 1 -C 3 hydroxyalkyl, or R 4 and R 5 , together with the nitrogen atom, are a pyrrolidine, piperidine, piperazine or morpholine ring, R 6 is H, straight-chain or branched C 1 -C 18 alkyl, C 5 -C 12 cycloalkyl, straight-chain or branched C 3 -C 8 alkenyl, C 6 -C 14 aryl or C 7 -C 18 aralkyl, and R 10 is straight-chain or branched C 2 -C 12 alkylene which may be interrupted by --O--, cyclohexylene, ##STR44## or R 10 and R 6 , together with the two nitrogen atoms, are a piperazine ring.
Claim 3
Dependent Claim 61 words
The compound according to claim 1 of the formula I in which R 1 is H or Cl, n is the number 1, R 2 is ##STR45## and R 4 and R 5 independently of one another are straight-chain or branched C 4 -C 12 alkyl, straight-chain or branched C 3 -C 10 alkyl which is interrupted by O, or cyclohexyl.
Claim 4
Dependent Claim 49 words
The compound according to claim 1 of the formula I in which R 1 is H or Cl, n is the number 2, R 2 is ##STR46## R 6 is H or C 1 -C 8 alkyl, and R 10 is straight-chain or branched C 2 -C 12 alkylene.
Claim 5
Dependent Claim 269 words
A compound of the formula I ##STR47## in which R 1 is H, Cl, straight-chain or branched C 1 -C 4 alkyl or straight-chain or branched C 1 -C 4 alkoxy and n is one of the numbers 1 or 2, and in which, (a) when n=1, R 2 is Cl or --OR 3 , and (b) when n=2, R 2 is --O--R 9 --O--, R 3 is straight-chain or branched C 1 -C 18 alkyl which is substituted by ##STR48## or --O--Si(R 6 ) 3 or --O--CO(R 6 ), straight-chain or branched C 3 -C 18 alkyl which is interrupted by --NR 6 -- and which can be unsubstituted or substituted by OH or --O--CO(R 6 ), or ##STR49## R 6 is H, straight-chain or branched C 1 -C 18 alkyl, C 5 -C 12 cycloalkyl, straight-chain or branched C 3 -C 8 alkenyl, C 6 -C 14 aryl or C 7 -C 18 aralkyl, R 7 is H, straight-chain or branched C 1 -C 18 alkyl which is unsubstituted or substituted by --PO(OR 8 ) 2 , phenyl which is unsubstituted or substituted by OH, C 7 -C 18 aralkyl or --CH 2 OR 8 , R 8 is straight-chain or branched C 1 -C 18 alkyl, straight-chain or branched C 3 -C 18 alkenyl, C 5 -C 10 cycloalkyl, C 6 -C 16 aryl or C 7 -C 15 aralkyl, R 9 is C 4 alkinylene, or ##STR50## and R 11 is straight-chain or branched C 2 -C 8 alkylene, straight-chain or branched C 4 -C 10 alkylene which is interrupted by --O--, cycloalkylene, arylene, ##STR51##
Claim 6
Dependent Claim 269 words
A compound of the formula I ##STR47## in which R 1 is H, Cl, straight-chain or branched C 1 -C 4 alkyl or straight-chain or branched C 1 -C 4 alkoxy and n is one of the numbers 1 or 2, and in which, (a) when n=1, R 2 is Cl or --OR 3 , and (b) when n=2, R 2 is --O--R 9 --O--, R 3 is straight-chain or branched C 1 -C 18 alkyl which is substituted by ##STR48## or --O--Si(R 6 ) 3 or --O--CO(R 6 ), straight-chain or branched C 3 -C 18 alkyl which is interrupted by --NR 6 -- and which can be unsubstituted or substituted by OH or --O--CO(R 6 ), or ##STR49## R 6 is H, straight-chain or branched C 1 -C 18 alkyl, C 5 -C 12 cycloalkyl, straight-chain or branched C 3 -C 8 alkenyl, C 6 -C 14 aryl or C 7 -C 18 aralkyl, R 7 is H, straight-chain or branched C 1 -C 18 alkyl which is unsubstituted or substituted by --PO(OR 8 ) 2 , phenyl which is unsubstituted or substituted by OH, C 7 -C 18 aralkyl or --CH 2 OR 8 , R 8 is straight-chain or branched C 1 -C 18 alkyl, straight-chain or branched C 3 -C 18 alkenyl, C 5 -C 10 cycloalkyl, C 6 -C 16 aryl or C 7 -C 15 aralkyl, R 9 is C 4 alkinylene, or ##STR50## and R 11 is straight-chain or branched C 2 -C 8 alkylene, straight-chain or branched C 4 -C 10 alkylene which is interrupted by --O--, cycloalkylene, arylene, ##STR51##
Claim 7
Dependent Claim 78 words
The compound according to claim 4 of the formula I in which R 1 is H or Cl, n is the number 1, R 2 is --OR 3 , R 3 is ##STR52## which is unsubstituted or substituted by OH, R 7 is straight-chain or branched C 1 -C 12 alkyl which is unsubstituted or substituted by ##STR53## or --CH 2 OR 8 , and R 8 is straight-chain or branched C 1 -C 12 alkyl or cyclohexyl.
Claim 8
Dependent Claim 56 words
The compound according to claim 4 of the formula I in which R 1 is H or Cl, n is the number 2, R 2 is --O--R 9 --O--, R 9 is ##STR54## and R 11 is C 2 -C 6 alkylene or straight-chain or branched C 4 -C 10 alkylene which is interrupted by --O--.

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-11-26 1994-05-28 1994-11-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-11-26 1998-05-28 1998-11-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-11-26 2002-05-28 2002-11-27 $7700.00 Window Closed / Lapsed

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