US4968500A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Continuous method for preparation of granulated sodium perborate
Assignee: Evonik Operations GmbH
•
Filing: 1989-05-17
•
Granted: 1990-11-06
•
Expires: 2009-05-17
Abstract
Abstract The spray drying of a solution containing hydrogen peroxide and sodium metaborate to obtain primary particles which are immediately conveyed after leaving the drying zone to a granulating device and are then granulated in the presence of free and/or perborate water of crystallization. The granulated materials are dried, if necessary. The generally amorphous primary particles are converted into granulated materials with at least partially crystalline structure and significantly improved shelf life. The work is performed with advantage in a spray dryer with integrated fluid bed or in a compressing granulating device. The method is suitable for preparing perborate granulated materials with over 10% by wt., especially perborate monohydrate granular materials with 14-16% by wt. active oxygen.
Inventors
- 👤 Birgit Bertsch-Frank
- 👤 Klaus Mueller
- 👤 Thomas Lieser
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 13:22
CPC Classifications
C; C01; C01B; C01B15/00; C01B15/055; C01B15/12; B; B01; B01J; B01J2/00; C01B15/126
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
138 words
A continuous method for the preparation of granulated perborate with an Oa-content of 14 to 16% by weight comprising the steps of: spraying an aqueous solution comprising hydrogen peroxide and sodium metaborate in a molar ratio of 0.9 to 1.1 into a drying zone to form droplets, wherein no nuclei of perborate are introduced into said drying zone, drying said droplets by means of a heated gas in said drying zone to thereby form powdery, essentially amorphous sodium perborate, conveying said powdery perborate after leaving said drying zone to a separate granulating zone, separated from said drying zone, adding water in sprayed form, vapor form, in the form of perborate containing water of crystallization or in the form of sodium perborate tetrahydrate to said powdery perborate and granulating by intimately bringing into contact said water and powdery perborate.
Claim 2
Dependent Claim
138 words
A continuous method for the preparation of granulated perborate with an Oa-content of 14 to 16% by weight comprising the steps of: spraying an aqueous solution comprising hydrogen peroxide and sodium metaborate in a molar ratio of 0.9 to 1.1 into a drying zone to form droplets, wherein no nuclei of perborate are introduced into said drying zone, drying said droplets by means of a heated gas in said drying zone to thereby form powdery, essentially amorphous sodium perborate, conveying said powdery perborate after leaving said drying zone to a separate granulating zone, separated from said drying zone, adding water in sprayed form, vapor form, in the form of perborate containing water of crystallization or in the form of sodium perborate tetrahydrate to said powdery perborate and granulating by intimately bringing into contact said water and powdery perborate.
Claim 3
Dependent Claim
25 words
The method of claim 1 wherein sodium perborate tetrahydrate is used as auxiliary granulating agent and the granulation is performed at 60° to 75° C.
Claim 4
Dependent Claim
16 words
The method according to claim 1 wherein the granulation is performed by compression of the perborate.
Claim 5
Dependent Claim
29 words
The method according to claim 3 wherein granulation in a fluidized bed is used to obtain a product with bulk density in the range of 0.3 to 0.6 g/ml.
Claim 6
Dependent Claim
26 words
The method according to claim 3 wherein granulation of sufficient compression is used to obtain a product with a bulk density of 0.4 to 1.0 g/ml.
Claim 7
Dependent Claim
15 words
The method according to claim 1 wherein the water is introduced into said granulating zone.
Claim 8
Dependent Claim
20 words
The method according to claim 1 wherein the water is introduced to said perborate immediately after leaving the drying zone.
Claim 9
Dependent Claim
20 words
The method according to claim 1 wherein an auxiliary granulating agent is present in the water used in sprayed form.
Claim 10
Dependent Claim
25 words
The method according to claim 1 wherein the water further contains an active oxygen stabilizer or surface active agent, or bleaching activator or mixture thereof.
Claim 11
Dependent Claim
18 words
The method according to claim 1, wherein the droplets and the heated gas are in a concurrent flow.
Claim 12
Dependent Claim
113 words
A continuous method for the preparation of granulated perborate with an Oa-content of 14 to 16% by weight, comprising the steps of: spraying an aqueous solution comprising hydrogen peroxide and sodium metaborate in a molar ratio of 0.9 to 1.1 into a drying zone to form droplets, wherein no nuclei of perborate are introduced into said drying zone, drying said droplets by means of a heated gas in said drying zone to thereby form powdery, essentially amorphous sodium perborate, conveying said powdery perborate after leaving said drying zone to a granulating zone, adding water in sprayed from to said powdery perborate and granulating by intimately bringing into contact said water and powdery perborate.
Claim 13
Dependent Claim
113 words
A continuous method for the preparation of granulated perborate with an Oa-content of 14 to 16% by weight, comprising the steps of: spraying an aqueous solution comprising hydrogen peroxide and sodium metaborate in a molar ratio of 0.9 to 1.1 into a drying zone to form droplets, wherein no nuclei of perborate are introduced into said drying zone, drying said droplets by means of a heated gas in said drying zone to thereby form powdery, essentially amorphous sodium perborate, conveying said powdery perborate after leaving said drying zone to a granulating zone, adding water in sprayed from to said powdery perborate and granulating by intimately bringing into contact said water and powdery perborate.
Claim 14
Dependent Claim
29 words
The method according to claim 11 wherein granulation in a fluidized bed is used to obtain a product with bulk density in the range of 0.3 to 0.6 g/ml.
Claim 15
Dependent Claim
26 words
The method according to claim 11 wherein granulation of sufficient compression is used to obtain a product with a bulk density of 0.4 to 1.0 g/ml.
Claim 16
Dependent Claim
15 words
The method according to claim 11 wherein the water is introduced into said granulating zone.
Claim 17
Dependent Claim
20 words
The method according to claim 11 wherein the water is introduced to said perborate immediately after leaving the drying zone.
References Cited (Backward Citations)
US3555696A
Cited
US4002434A
Cited
US4115519A
Cited
US4185960A
Cited
US4215097A
Cited
US4681748A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-11-05 | 1994-05-07 | 1994-11-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-11-05 | 1998-05-07 | 1998-11-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-11-05 | 2002-05-07 | 2002-11-06 | $7700.00 | Window Closed / Lapsed |