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US4966435A Expired / Lapsed US ⏱️ 0.0 years remaining

Plastic optical fiber

Assignee: Mitsubishi Chemical Corp
•
Filing: 1989-11-29
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Granted: 1990-10-30
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Expires: 2009-11-29
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Abstract

Abstract A plastic core-plastic cladding optical fiber is described wherein the core is composed of a copolymer of a perfluorodioxole represented by the following formula: ##STR1## wherein R and R' independently represent F or CF 3 , with at least one other ethylenically unsaturated monomer substantially free of CH bonds and the copolymer has no first order transition temperature as determined by the differential scanning colorimetry (DSC) and has a second order transition temperature not lower than 100° C. as determined by DSC.

Inventors

  • 👤 Tsuruyoshi Matsumoto
  • 👤 Takashi Yamamoto
  • 👤 Teruhiko Sugimori
  • 👤 Katsuhiko Shimada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 19:03
CPC Classifications
G; G02; G02B; G02B6/00; G02B6/02; G02B6/02033; G02B1/00; G02B1/04; G02B1/045; G02B1/046

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 82 words
A plastic optical fiber having a core-sheath structure, wherein the core component is composed of a copolymer of a perfluorodioxole represented by the following formula: ##STR3## wherein R and R' independently represent F or CF 3 , with at least one other ethylenically unsaturated monomer substantially free of CH bonds, and said copolymer has no first order transition temperature as determined by the differential scanning colorimetry (DSC}and has a second order transition temperature not lower than 100° C. as determined by DSC.
Claim 2
Dependent Claim 82 words
A plastic optical fiber having a core-sheath structure, wherein the core component is composed of a copolymer of a perfluorodioxole represented by the following formula: ##STR3## wherein R and R' independently represent F or CF 3 , with at least one other ethylenically unsaturated monomer substantially free of CH bonds, and said copolymer has no first order transition temperature as determined by the differential scanning colorimetry (DSC}and has a second order transition temperature not lower than 100° C. as determined by DSC.
Claim 3
Dependent Claim 33 words
A plastic optical fiber as set forth in claim 1, wherein the unstable end group content, as determined by the Fourier transform infrared spectroscopy (FTIR), in the perfluorodioxole copolymer is below 5 meq/kg.
Claim 4
Dependent Claim 29 words
A plastic optical fiber as set forth in claim 1, wherein the other ethylenically unsaturated monomer is selected from the group consisting of tetrafluoroethylene, chlorotrifluoroethylene and perfluoro(methyl vinyl ether).

References Cited (Backward Citations)

US4431786A Cited
US4535175A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-10-29 1994-04-30 1994-10-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-10-29 1998-04-30 1998-10-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-10-29 2002-04-30 2002-10-30 $7700.00 Window Closed / Lapsed

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