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US4960901A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermal imaging method

Assignee: YAMA CAPITAL LLC
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Filing: 1987-10-29
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Granted: 1990-10-02
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Expires: 2007-10-29
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Abstract

Abstract A thermal imaging method is provided which comprises heating imagewise a di- or triarylmethane compound possessing within its di- or triarylmethane structure an aryl group substituted in the ortho position to the meso carbon atom with a moiety ring-closed on the meso carbon atom directly through a nitrogen atom, which nitrogen atom is also bound to a group with a masked acyl substituent that undergoes fragmentation upon heating to liberate the acyl group for effecting intramolecular acylation of said nitrogen atom to form a new group in the ortho position whereby the di- or triarylmethane compound is rendered colored in an imagewise pattern corresponding to said imagewise heating.

Inventors

  • 👤 Alan L. Borror
  • 👤 Ernest W. Ellis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 08:15
CPC Classifications
C; C07; C07D; C07D491/00; C07D491/02; C07D491/10; B; B41; B41M; B41M5/00; B41M5/26; B41M5/30; B41M5/323; C07D417/00; C07D417/14; C07D513/00; C07D513/02; C07D513/10

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 202 words
A substantially colorless di- or triarylmethane compound of the formula ##STR54## wherein ring B represents a carbocyclic aryl ring or a heterocyclic aryl ring; C 1 represents the meso carbon atom of said di- or triarylmethane compound; X represents ##STR55## or --CH 2 -- and completes a moiety ring-closed on said meso carbon, said moiety including the nitrogen atom bonded directly to said meso carbon; Y represents ##STR56## wherein L is a leaving group that departs upon thermal fragmentation to unmask --N=C=O for effecting intramolecular acylation of said nitrogen atom to open the N-containing ring and form a new group in the ortho position of ring B that cannot bond to said meso carbon atom; E is hydrogen, an electron-donating group, an electron-withdrawing group or a group, either an electron-donating group or an electron-neutral group, that undergoes fragmentation upon heating to liberate an electron-withdrawing group; s is 0 or 1 and Z and Z' taken individually represent the moieties to complete the auxochromophoric system of a diarylmethane or triarylmethane dye when said N-containing ring is open and Z and Z' taken together represent the bridged moieties to complete the auxochromophoric system of a bridged triarylmethane dye when said N-containing ring is open.
Claim 2
Dependent Claim 202 words
A substantially colorless di- or triarylmethane compound of the formula ##STR54## wherein ring B represents a carbocyclic aryl ring or a heterocyclic aryl ring; C 1 represents the meso carbon atom of said di- or triarylmethane compound; X represents ##STR55## or --CH 2 -- and completes a moiety ring-closed on said meso carbon, said moiety including the nitrogen atom bonded directly to said meso carbon; Y represents ##STR56## wherein L is a leaving group that departs upon thermal fragmentation to unmask --N=C=O for effecting intramolecular acylation of said nitrogen atom to open the N-containing ring and form a new group in the ortho position of ring B that cannot bond to said meso carbon atom; E is hydrogen, an electron-donating group, an electron-withdrawing group or a group, either an electron-donating group or an electron-neutral group, that undergoes fragmentation upon heating to liberate an electron-withdrawing group; s is 0 or 1 and Z and Z' taken individually represent the moieties to complete the auxochromophoric system of a diarylmethane or triarylmethane dye when said N-containing ring is open and Z and Z' taken together represent the bridged moieties to complete the auxochromophoric system of a bridged triarylmethane dye when said N-containing ring is open.
Claim 3
Dependent Claim 13 words
A substantially colorless compound as defined in claim 1 wherein s is 0.
Claim 4
Dependent Claim 12 words
A substantially colorless compound as defined in claim 1 wherein X is
Claim 5
Dependent Claim 41 words
A substantially colorless compound a defined in claim 1 wherein Z and Z' taken individually or taken together represent the moieties to complete the auxochromophoric system of a triarylmethane dye or a bridge triarylmethane dye when said N-containing ring is open.
Claim 6
Dependent Claim 18 words
A substantially colorless compound as defined in claim 1 wherein said ring B is a carbocyclic aryl ring.
Claim 7
Dependent Claim 8 words
A substantially colorless compound of the formula ##STR57##
Claim 8
Dependent Claim 8 words
A substantially colorless compound of the formula ##STR57##
Claim 9
Dependent Claim 15 words
A substantially colorless compound as defined in claim 1 wherein X is --CH 2 --.

References Cited (Backward Citations)

US4228075A Cited
US4290951A Cited
US4663518A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-10-01 1994-04-02 1994-10-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-10-01 1998-04-02 1998-10-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-10-01 2002-04-02 2002-10-02 $7700.00 Window Closed / Lapsed

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