Patent US2544738A successfully refreshed from Google Patents.
US4960901A
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Thermal imaging method
Assignee: YAMA CAPITAL LLC
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Filing: 1987-10-29
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Granted: 1990-10-02
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Expires: 2007-10-29
Abstract
Abstract A thermal imaging method is provided which comprises heating imagewise a di- or triarylmethane compound possessing within its di- or triarylmethane structure an aryl group substituted in the ortho position to the meso carbon atom with a moiety ring-closed on the meso carbon atom directly through a nitrogen atom, which nitrogen atom is also bound to a group with a masked acyl substituent that undergoes fragmentation upon heating to liberate the acyl group for effecting intramolecular acylation of said nitrogen atom to form a new group in the ortho position whereby the di- or triarylmethane compound is rendered colored in an imagewise pattern corresponding to said imagewise heating.
Inventors
- 👤 Alan L. Borror
- 👤 Ernest W. Ellis
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 08:15
CPC Classifications
C; C07; C07D; C07D491/00; C07D491/02; C07D491/10; B; B41; B41M; B41M5/00; B41M5/26; B41M5/30; B41M5/323; C07D417/00; C07D417/14; C07D513/00; C07D513/02; C07D513/10
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
202 words
A substantially colorless di- or triarylmethane compound of the formula ##STR54## wherein ring B represents a carbocyclic aryl ring or a heterocyclic aryl ring; C 1 represents the meso carbon atom of said di- or triarylmethane compound; X represents ##STR55## or --CH 2 -- and completes a moiety ring-closed on said meso carbon, said moiety including the nitrogen atom bonded directly to said meso carbon; Y represents ##STR56## wherein L is a leaving group that departs upon thermal fragmentation to unmask --N=C=O for effecting intramolecular acylation of said nitrogen atom to open the N-containing ring and form a new group in the ortho position of ring B that cannot bond to said meso carbon atom; E is hydrogen, an electron-donating group, an electron-withdrawing group or a group, either an electron-donating group or an electron-neutral group, that undergoes fragmentation upon heating to liberate an electron-withdrawing group; s is 0 or 1 and Z and Z' taken individually represent the moieties to complete the auxochromophoric system of a diarylmethane or triarylmethane dye when said N-containing ring is open and Z and Z' taken together represent the bridged moieties to complete the auxochromophoric system of a bridged triarylmethane dye when said N-containing ring is open.
Claim 2
Dependent Claim
202 words
A substantially colorless di- or triarylmethane compound of the formula ##STR54## wherein ring B represents a carbocyclic aryl ring or a heterocyclic aryl ring; C 1 represents the meso carbon atom of said di- or triarylmethane compound; X represents ##STR55## or --CH 2 -- and completes a moiety ring-closed on said meso carbon, said moiety including the nitrogen atom bonded directly to said meso carbon; Y represents ##STR56## wherein L is a leaving group that departs upon thermal fragmentation to unmask --N=C=O for effecting intramolecular acylation of said nitrogen atom to open the N-containing ring and form a new group in the ortho position of ring B that cannot bond to said meso carbon atom; E is hydrogen, an electron-donating group, an electron-withdrawing group or a group, either an electron-donating group or an electron-neutral group, that undergoes fragmentation upon heating to liberate an electron-withdrawing group; s is 0 or 1 and Z and Z' taken individually represent the moieties to complete the auxochromophoric system of a diarylmethane or triarylmethane dye when said N-containing ring is open and Z and Z' taken together represent the bridged moieties to complete the auxochromophoric system of a bridged triarylmethane dye when said N-containing ring is open.
Claim 3
Dependent Claim
13 words
A substantially colorless compound as defined in claim 1 wherein s is 0.
Claim 4
Dependent Claim
12 words
A substantially colorless compound as defined in claim 1 wherein X is
Claim 5
Dependent Claim
41 words
A substantially colorless compound a defined in claim 1 wherein Z and Z' taken individually or taken together represent the moieties to complete the auxochromophoric system of a triarylmethane dye or a bridge triarylmethane dye when said N-containing ring is open.
Claim 6
Dependent Claim
18 words
A substantially colorless compound as defined in claim 1 wherein said ring B is a carbocyclic aryl ring.
Claim 7
Dependent Claim
8 words
A substantially colorless compound of the formula ##STR57##
Claim 8
Dependent Claim
8 words
A substantially colorless compound of the formula ##STR57##
Claim 9
Dependent Claim
15 words
A substantially colorless compound as defined in claim 1 wherein X is --CH 2 --.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-10-01 | 1994-04-02 | 1994-10-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-10-01 | 1998-04-02 | 1998-10-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-10-01 | 2002-04-02 | 2002-10-02 | $7700.00 | Window Closed / Lapsed |