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US4960664A Expired / Lapsed US ⏱️ 0.0 years remaining

Developer composition for developing electrostatic image and toner image forming process

Assignee: Konica Minolta Inc
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Filing: 1989-09-25
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Granted: 1990-10-02
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Expires: 2009-09-25
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Abstract

Abstract A toner for developing an electrostatic latent image containing a polyester resin binder obtained by condensation polymerization of a diol component and a mixture of acid components. The acid components are an aliphatic unsaturated dicarboxylic acid or an acid anhydride thereof and a polybasic carboxylic acid having not less than three carboxylic acid groups or an acid anhydride thereof. A ratio of the polybasic carboxylic acid having not less than three carboxylic acid groups or the acid anhydride thereof to the total acid components is in the range of from 5 mol % to less than 30 mol %.

Inventors

  • 👤 Hiroyuki Yamada
  • 👤 Hiroyuki Takagiwa
  • 👤 Hiroya Masaki
  • 👤 Takahira Kasuya
  • 👤 Jiro Takahashi
  • 👤 Masafumi Uchida
  • 👤 Satoru Ikeuchi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 14:50
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/10; G03G9/113; G03G9/1132; G03G9/1133; G03G9/1134; G03G9/087; G03G9/08742; G03G9/08755; Y; Y10; Y10S; Y10S524/00; Y10S524/901; Y10S525/00; Y10S525/934; Y10S526/00; Y10S526/934

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 227 words
A developer composition for developing an electrostatic latent image comprising: (1) a color toner comprising (i) a polyester resin obtained by polymerizing by condensation polymerization: (a) a mixture of diol components comprising diols represented by the formula (1): ##STR12## wherein R is an ethylene group or a propylene group, x and y represent integers and the average of the total sum of x and y is from 2 to 7, and (b) a mixture of acid components comprising an aliphatic unsaturated dicarboxylic acid, an acid anhydride thereof or a derivative thereof and a polybasic carboxylic acid having not less than three carboxylic acid groups or an acid anhydride thereof, the proportion of the content of said polybasic carboxylic acid having not less than three carboxylic acid groups or the acid anhydride thereof to the total acid components being from 5 mol % to less than 30 mol %, and (ii) a chromatic coloring agent; and (2) a resin coated carrier comprising a core material and a resin layer coated thereon, said resin layer containing a vinylidene fluoride/ethylene tetrafluoride copolymer and a polymer having at least one of monomer components represented by the following formulas I and II: ##STR13## wherein R 3 and R 4 each represent a hydrogen atom or a methyl group, r represents 1 or 2, and s represents an integer of 2 to 4.
Claim 2
Dependent Claim 227 words
A developer composition for developing an electrostatic latent image comprising: (1) a color toner comprising (i) a polyester resin obtained by polymerizing by condensation polymerization: (a) a mixture of diol components comprising diols represented by the formula (1): ##STR12## wherein R is an ethylene group or a propylene group, x and y represent integers and the average of the total sum of x and y is from 2 to 7, and (b) a mixture of acid components comprising an aliphatic unsaturated dicarboxylic acid, an acid anhydride thereof or a derivative thereof and a polybasic carboxylic acid having not less than three carboxylic acid groups or an acid anhydride thereof, the proportion of the content of said polybasic carboxylic acid having not less than three carboxylic acid groups or the acid anhydride thereof to the total acid components being from 5 mol % to less than 30 mol %, and (ii) a chromatic coloring agent; and (2) a resin coated carrier comprising a core material and a resin layer coated thereon, said resin layer containing a vinylidene fluoride/ethylene tetrafluoride copolymer and a polymer having at least one of monomer components represented by the following formulas I and II: ##STR13## wherein R 3 and R 4 each represent a hydrogen atom or a methyl group, r represents 1 or 2, and s represents an integer of 2 to 4.
Claim 3
Dependent Claim 35 words
The developer of claim 1, wherein said aliphatic unsaturated dicarboxylic acid is at least one member selected from the group consisting of fumaric acid, maleic acid, citraconic acid, mesaconic acid, itaconic acid and gulutaconic acid.
Claim 4
Dependent Claim 13 words
The developer of claim 1, wherein said polybasic carboxylic acid is 1,2,4-benzenetricarboxylic acid.
Claim 5
Dependent Claim 42 words
The developer of claim 1, wherein the amount of said chromatic coloring agent to be contained in said color toner is from 3 to 20 parts by weight based on 100 parts by weight of the polyester resin of said color toner.
Claim 6
Dependent Claim 20 words
The developer of claim 1, wherein the copolymerization molar ratio of said vinylidene fluoride/ethylene tetrafluoride is between 75:25 and 95:5.
Claim 7
Dependent Claim 20 words
The developer of claim 1, wherein the polymerization molar ratio of said vinylidene fluoride/ethylene tetrafluoride is between 75:25 and 87.5:12.5.
Claim 8
Dependent Claim 22 words
The developer of claim 1, wherein the weight average particle size of said resin coated carrier is from 10 to 1000 μm.
Claim 9
Dependent Claim 22 words
The developer of claim 1, wherein the weight average particle size of said resin coated carrier is from 20 to 300 μm.
Claim 10
Dependent Claim 18 words
The developer of claim 1, wherein the thickness of said resin layer is from 0.01 to 20 μm.
Claim 11
Dependent Claim 18 words
The developer of claim 1, wherein the thickness of said resin layer is from 0.1 to 3 μm.

References Cited (Backward Citations)

US4657837A Cited
JPS60339A Cited
JPH01240251A Cited
JPH044956A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-10-01 1994-04-02 1994-10-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-10-01 1998-04-02 1998-10-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-10-01 2002-04-02 2002-10-02 $7700.00 Window Closed / Lapsed

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