Laminating varnish composition containing a difunctional epoxy resin, a polyfunctional epoxy resin, a difunctional phenol and a polyfunctional phenol and a solvent

Claim 2

A laminating varnish composition comprising a substantially unreacted mixture of (A) an epoxy-containing composition consisting essentially of (1) from about 5 to about 95 percent by weight of at least one epoxy resin having an average of not more than 2 vicinal epoxide groups per molecules; and (2) from about 95 to about 5 percent by weight of at least one epoxy resin having an average of more than 2 vicinal epoxide groups per molecule, at least one such epoxy resin being represented by the following formulas III; or IV: ##STR5## wherein each A' is independently a divalent hydrocarbyl group having from 1 to about 4 carbon atoms; each R is independently hydrogen or an alkyl group having from 1 to about 3 carbon atoms; each R' is independently hydrogen or a hydrocarbyl group having from 1 to about 5 carbon atoms; each X is independently hydrogen, an alkyl group having from 1 to about 5 carbon atoms or a halogen; m has a value from about 1 to about 4; and m' has a value from zero to about 1; (B) a phenolic hydroxyl-containing composition consisting essentially of (1) from about 10 to about 70 equivalent percent about at least one phenolic hydroxyl-containing compound having an average of not more than 2 phenolic hydroxyl groups per molecules; and (2) from about 90 to about 30 equivalent percent of at least one phenolic hydroxyl-containing compound having an average of more than 2 phenolic hydroxyl groups per molecule; and wherein components (A) and (B) are present in quantities which provide a ratio of phenolic hydroxyl groups for each epoxy group of from about 0.75:1 to about 1.2:1; (C) a catalytic quantity of at least one catalyst for effecting the reaction between components (A) and (B); and (D) one or more solvents in an amount up to about 75 percent by weight of the total composition.

Claim 3

A laminating varnish of claim 1 (a) component (A) comprises from about 5 to about 60 weight percent of component (1) and from about 95 to about 40 weight percent of component (2); (b) component (B) comprises from about 10 to about 50 equivalent percent of component (1) and from about 90 to about 50 equivalent percent of component (2); and (c) components (A) and (B) are present in quantities which provide a ratio of phenolic hydroxyl groups for each epoxy group from about 0.85:1 to about 1.1:1 and (d) component (D) is present in an amount of from zero to about 50 percent by weight of the total composition.

Claim 4

A laminating varnish of claim 2 wherein (a) component (A) comprises from about 5 to about 40 weight percent of component (1) and from about 95 to about 60 weight percent of component (2); (b) component (B) comprises from about 10 to about 35 equivalent percent of component (1) and from about 90 to about 65 equivalent percent of component (2); and (c) components (A) and (B) are present in quantities which provide a ratio of phenolic hydroxyl groups for each epoxy group from about 0.95:1 to about 1:1 and (d) component (D) is present in an amount of from about 0 to about 25 percent by weight of the total composition.

Claim 5

A composition of claim 1, 2 or 3 wherein (a) component (A-1) is an epoxy resin represented by one of the following formulas or a combination of such epoxy resins ##STR6## wherein each is independently a divalent hydrocarbyl group having from 1 to about 5 carbon atoms, --S--, --S--S--, --SO--, --SO 2 --, --CO--, or --O--; each R is independently hydrogen or an alkyl group having from 1 to about 3 carbon atoms; each X is independently hydrogen, an alkyl group having from 1 to about 5 carbon atoms or a halogen; each n independently has a value of zero or 1; and n' has a value from zero to about 2; (b) component (A-2) is an epoxy resin represented by one of the following formulas or a combination of such epoxy resins ##STR7## wherein each A' is independently a divalent hydrocarbyl group having from 1 to about 4 carbon atoms; each R is independently hydrogen or an alkyl group having from 1 to about 3 carbon atoms; each R' is independently hydrogen or a hydrocarbyl group having from 1 to about 5 carbon atoms; each X is independently hydrogen, an alkyl group having from 1 to about 5 carbon atoms or a halogen; m has a value from about 1 to about 4; and m' has a value from zero to about 1; (c) component (B-1) is a phenolic hydroxyl-containing compound represented by one of the following formulas or a combination of such phenolic hydroxyl-containing compounds ##STR8## wherein each A is independently a divalent hydrocarbyl group having from 1 to about 5 carbon atoms, --S--, --S--S--, --SO--, --SO 2 --, --CO--, or --O--; each X is independently hydrogen, an alkyl group having from 1 to about 5 carbon atoms or a halogen; and each n independently has a value of zero or 1; (d) component (B-2) is a phenolic hydroxyl-containing compound represented by one of the following formulas or a combination of such phenolic hydroxyl-containing compounds ##STR9## wherein each A' is independently a divalent hydrocarbyl group having from 1 to about 4 carbon atoms; each R' is independently hydrogen or a hydrocarbyl group having from 1 to about 5 carbon atoms; each X is independently hydrogen, an alkyl group having from 1 to about 5 carbon atoms or a halogen; and m has a value from about 1 to about 4; (e) component (C) is a phosphonium compound, an imidazole or a combination thereof; and (f) component (D) is a ketone, a glycol ether or a combination thereof.

Claim 6

A laminating varnish of claim 4 wherein (a) component (A-1) is a diglycidyl ether represented by formula II wherein n has a value of 1 and n has a value from zero to about 0.5; (b) component (A-2) is a polyglycidyl ether represented by formula III wherein m has a value from about 1 to about 4; (c) component (B-1) is a phenolic hydroxyl-containing compound represented by formula VI wherein n has a value of 1; and (d) component (B-2) is a phenolic hydroxyl-containing compound represented by formula VII wherein m has a value from about 1 to about 4.

Claim 7

A laminating varnish of claim 5 wherein (a) component (A-1) is a diglycidyl ether of bisphenol A; (b) component (A-2) is a polyglycidyl ether of a phenol-formaldehyde novolac epoxy resin; (c) component (B-1) is bisphenol A or tetrabromo bisphenol A; (d) component (B-2) is a phenol-formaldehyde novolac resin; (e) component (C) is the adduct or complex of a quaternary phosphonium acetate.acetic acid complex and fluoric acid in a respective molar ratio of from about 1:0.9 to about 1:1.25, 2-methylimidazole or a combination thereof; and; (f) component (D), when present, is propylene glycoI methyl ether, methyl ethyl ketone, methanol, ethanol, dimethylformamide or a combination thereof.