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US4958006A Expired / Lapsed US ⏱️ 0.0 years remaining

Fluidized bed product discharge process

Assignee: Union Carbide Corp
•
Filing: 1988-06-28
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Granted: 1990-09-18
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Expires: 2008-06-28
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Abstract

Abstract Method and apparatus for the post reaction treatment of resins produced by fluidized bed polymerization of alpha olefins wherein an extruder is coupled in communication with the reactor and all necessary devolatilization of monomer, deactivation of catalysts and addition of additives are performed in the extruder.

Inventors

  • 👤 Robert J. Bernier
  • 👤 Jorge O. Buhler-Vidal
  • 👤 Urho S. Haapala
  • 👤 Benjamin R. Rozenblat

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 15:53
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/20; C08J3/201; B; B01; B01J; B01J8/00; B01J8/0015; B01J8/18; B01J8/24; B29; B29B; B29B7/00; B29B7/30; B29B7/58; B29B7/60; B29B7/603; B29B7/72; B29B7/728; B29B7/80; B29B7/84; B29B7/845; B29B7/86; B29C; B29C48/00; B29C48/25; B29C48/285; B29C48/29; B29C48/297; B29C48/36; B29C48/395; B29C48/40; B29C48/50; B29C48/76; C08F; C08F6/00; B29C48/03; B29C48/375; B29C48/387; B29K; B29K2105/00; B29K2105/0005; Y; Y10; Y10S; Y10S159/00; Y10S159/16; Y10S526/00; Y10S526/901; Y10S526/92

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 213 words
A process for the post reaction treatment of resins produced by fluidized bed polymerization of alpha olefins in a polymerization reactor which comprises: (a) providing a screw extruder a portion of which is disposed in said reactor in communicating contact with said fluidized bed said screw extruder being adapted to receive polymer particle resins from said fluidized bed, (b) removing polymerized product resin from said fluidized bed by the action of said screw extruder in communication with said fluidized bed, (c) melting said resin in said extruder to form molten polymer, (d) providing valve means for effecting a seal with said molten polymer in said extruder to provide an upstream zone from said seal into said reactor and a downstream zone from said seal in a direction away from said reactor, said seal isolating the pressure in said upstream zone from said downstream zone, (e) devolatilizing monomer residues and volatiles dissolved in said polymer melt by venting said monomer residues and volatiles from said extruder, (f) deactivating catalyst and cocatalyst residues by introducing a deactivating agent to said extruder, (g) adding additives in the absence of oxygen to said extruder containing said polymer melt; steps (e) through (g) being conducted in said downstream zone and (h) discharging treated polymer product from said extruder.
Claim 2
Dependent Claim 213 words
A process for the post reaction treatment of resins produced by fluidized bed polymerization of alpha olefins in a polymerization reactor which comprises: (a) providing a screw extruder a portion of which is disposed in said reactor in communicating contact with said fluidized bed said screw extruder being adapted to receive polymer particle resins from said fluidized bed, (b) removing polymerized product resin from said fluidized bed by the action of said screw extruder in communication with said fluidized bed, (c) melting said resin in said extruder to form molten polymer, (d) providing valve means for effecting a seal with said molten polymer in said extruder to provide an upstream zone from said seal into said reactor and a downstream zone from said seal in a direction away from said reactor, said seal isolating the pressure in said upstream zone from said downstream zone, (e) devolatilizing monomer residues and volatiles dissolved in said polymer melt by venting said monomer residues and volatiles from said extruder, (f) deactivating catalyst and cocatalyst residues by introducing a deactivating agent to said extruder, (g) adding additives in the absence of oxygen to said extruder containing said polymer melt; steps (e) through (g) being conducted in said downstream zone and (h) discharging treated polymer product from said extruder.
Claim 3
Dependent Claim 15 words
A process according to claim 1 wherein said screw extruder is a twin screw extruder.
Claim 4
Dependent Claim 23 words
A process according to claim 1 wherein said polymer particle resin is an ethylene/propylene rubber containing 25 to 50 percent propylene by weight.
Claim 5
Dependent Claim 42 words
A process according to claim 1 wherein said polymer particle resin is an ethylene/butene copolymer produced at reactor temperatures of 50° C. to 80° C. at density levels of 880 to 805 kilograms per cubic meter and which is chlorinated or chlorosulfonated.
Claim 6
Dependent Claim 29 words
A process according to claim 1 wherein in step (d) said seal of molten polymer is obtained by restricting the cross section of said extruder available for polymer flow.
Claim 7
Dependent Claim 27 words
A process according to claim 1 wherein in step (e) said monomer residues and volatiles are vented from said extruder under vacuum in a first vent stage.
Claim 8
Dependent Claim 15 words
A process according to claim 1 wherein in step (f) said deactivating agent is water.
Claim 9
Dependent Claim 24 words
A process according to claim 1 wherein in step (f) said catalyst and cocatalyst residues are deactivated under vacuum in a second vent stage.
Claim 10
Dependent Claim 24 words
A process according to claim 1 wherein said additives added in step (g) are tetrakis [methylene (3,5-di-tert-butyl-4-hydroxy-hydrocinnamate)] methane, tris (2,4-di-tert-butylphenyl) phosphite and zinc oxide.
Claim 11
Dependent Claim 26 words
A process according to claim 1 wherein a screw feeder is provided between said reactor and said extruder, said screw feeder receiving resin from said reactor.
Claim 12
Dependent Claim 33 words
A process according to claim 10 wherein said screw feeder is operated at a rate such that the removal rate of resin from said mixer is substantially equal to the reactor production rate.
Claim 13
Dependent Claim 16 words
A process according to claim 10 wherein said screw feeder is disposed in said upstream zone.

References Cited (Backward Citations)

US23948A Cited
USRE23948E Cited
US3023203A Cited
US3440238A Cited
US3925341A Cited
US4288407A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-09-17 1994-03-19 1994-09-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-09-17 1998-03-19 1998-09-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-09-17 2002-03-19 2002-09-18 $7700.00 Window Closed / Lapsed

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