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US4957593A Expired / Lapsed US ⏱️ 0.0 years remaining

Modified composite electrodes with renewable surface for electrochemical applications and method of making same

Assignee: University of Connecticut
•
Filing: 1989-03-07
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Granted: 1990-09-18
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Expires: 2009-03-07
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Abstract

Abstract Renewable modified composite electrodes for electrochemical applications are provided by homogeneous structures of a conductive filler and a modifier dispersed within a polymer matrix or binder. The modifiers may provide characteristics of electroactivity, inclusion, adsorption or electrocatalysis to the surface of the electrode in a solution. After use, the electrode may be renewed by removing a surface portion and thereby exposing a fresh portion of the homogeneous structure.

Inventors

  • 👤 Brenda R. Shaw
  • 👤 Kenneth E. Creasy

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 19:04
CPC Classifications
C; C25; C25B; C25B11/00; C25B11/04; G; G01; G01N; G01N27/00; G01N27/26; G01N27/28; G01N27/30; H; H01; H01M; H01M4/00; H01M4/86; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 96 words
A self-supporting renewable modified composite electrode for electrochemical applications comprising a substantially homogenous structure of a composition consisting of: (a) 1-98 percent by weight of a non-conductive polymeric matrix; (b) 1-98 percent by weight of a conductive filler dispersed throughout said matrix and sufficient to provide electrical conductivity in the electrode; and (c) 1-98 percent by weight of a modifier dispersed throughout said matrix, said modifier providing to said electrode electroactive properties, said electrode being homogeneous throughout its cross section and thereby renewable by removal of a surface portion thereof to expose a fresh portion thereof.
Claim 2
Dependent Claim 96 words
A self-supporting renewable modified composite electrode for electrochemical applications comprising a substantially homogenous structure of a composition consisting of: (a) 1-98 percent by weight of a non-conductive polymeric matrix; (b) 1-98 percent by weight of a conductive filler dispersed throughout said matrix and sufficient to provide electrical conductivity in the electrode; and (c) 1-98 percent by weight of a modifier dispersed throughout said matrix, said modifier providing to said electrode electroactive properties, said electrode being homogeneous throughout its cross section and thereby renewable by removal of a surface portion thereof to expose a fresh portion thereof.
Claim 3
Dependent Claim 12 words
The electrode in accordance with claim 1 wherein said modifier is non-conductive.
Claim 4
Dependent Claim 15 words
The electrode in accordance with claim 1 wherein said conductive filler comprises a fibrous material.
Claim 5
Dependent Claim 15 words
The electrode in accordance with claim 1 wherein said conductive filler comprises a particulate material.
Claim 6
Dependent Claim 22 words
The electrode in accordance with claim 1 wherein said modifier exhibits such properties only upon application of a potential to said electrode.
Claim 7
Dependent Claim 28 words
The electrode in accordance with claim 1 wherein said modifier exhibits properties which will enable measurement of the potential of a solution in which immersed at zero current.
Claim 8
Dependent Claim 27 words
The electrode in accordance with claim 1 wherein said modifier exhibiting electroactive properties is selected from the group consisting of organic compounds, polymers, metals and metallic compounds.
Claim 9
Dependent Claim 26 words
The electrode in accordance with claim 1 wherein said modifier is non-conductive and enhances electroactivity upon application of a potential to the electrode in a solution.
Claim 10
Dependent Claim 29 words
The electrode in accordance with claim 1 wherein said filler is particulate and comprises 5-15 percent by weight and said modifier comprises 2-20 percent by weight of the composition.
Claim 11
Dependent Claim 96 words
A self-supporting renewable modified composite electrode for electrochemical applications comprising a substantially homogenous structure of a composition consisting of: (a) 1-98 percent by weight of a non-conductive polymer matrix; (b) 1-98 percent by weight of a conductive filler dispersed throughout said matrix and sufficient to provide electrical conductivity in the electrode; and (c) 1-98 percent by weight of a modifier dispersed throughout said matrix, said modifier providing to said electrode adsorption properties, said electrode being homogeneous throughout its cross section and thereby renewable by removal of a surface portion thereof to expose a fresh portion thereof.
Claim 12
Dependent Claim 96 words
A self-supporting renewable modified composite electrode for electrochemical applications comprising a substantially homogenous structure of a composition consisting of: (a) 1-98 percent by weight of a non-conductive polymer matrix; (b) 1-98 percent by weight of a conductive filler dispersed throughout said matrix and sufficient to provide electrical conductivity in the electrode; and (c) 1-98 percent by weight of a modifier dispersed throughout said matrix, said modifier providing to said electrode adsorption properties, said electrode being homogeneous throughout its cross section and thereby renewable by removal of a surface portion thereof to expose a fresh portion thereof.
Claim 13
Dependent Claim 96 words
A self-supporting renewable modified composite electrode for electrochemical applications comprising a substantially homogeneous structure of a composition consisting of: (a) 1-98 percent by weight of a non-conductive polymeric matrix; (b) 1-98 percent by weight of a conductive filler dispersed throughout said matrix and sufficient to provide electrical conductivity in the electrode; and (c) 1-98 percent by weight of a modifier dispersed throughout said matrix, said modifier providing to said electrode electrocatalytic properties, said electrodes being homogeneous throughout its cross section and thereby renewable by removal of a surface portion thereof to expose a fresh portion thereof.
Claim 14
Dependent Claim 96 words
A self-supporting renewable modified composite electrode for electrochemical applications comprising a substantially homogeneous structure of a composition consisting of: (a) 1-98 percent by weight of a non-conductive polymeric matrix; (b) 1-98 percent by weight of a conductive filler dispersed throughout said matrix and sufficient to provide electrical conductivity in the electrode; and (c) 1-98 percent by weight of a modifier dispersed throughout said matrix, said modifier providing to said electrode electrocatalytic properties, said electrodes being homogeneous throughout its cross section and thereby renewable by removal of a surface portion thereof to expose a fresh portion thereof.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-09-17 1994-03-19 1994-09-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-09-17 1998-03-19 1998-09-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-09-17 2002-03-19 2002-09-18 $7700.00 Window Closed / Lapsed

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