US4950461A
Expired / Lapsed
US
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Process for catalytic reduction of nitrogen oxides
Assignee: Kali Chemie AG
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Filing: 1989-02-21
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Granted: 1990-08-21
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Expires: 2009-02-21
Abstract
Abstract A process for catalytically reducing nitrogen oxides in an exhaust gas such as a combustion gas and a catalyst suitable for use therein. The catalyst comprises a zeolite Y which has been ion exchanged with lithium ions and/or rare earth metal ions, and may be dispersed in an amorphous oxide gel matrix.
Inventors
- 👤 Norbert Schwetje
- 👤 Dieter Kipping
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 12:31
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/08; B01J29/10; B01J29/12; B01J29/126; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8621; B01D53/8625; B01D53/8628
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
79 words
A process for catalytic reduction of nitrogen oxides (NO x ) in exhaust gases comprising treating the exhaust gas in the presence of a hydrogen donor with a catalyst comprising a zeolite Y dispersed in an amorphous matrix of oxide gel, said zeolite Y having been subjected to ion exchange to replace from 40 to 90 mole-% of its exchangeable ions with at least one ion selected from the group consisting of lithium ion and rare earth metal ions.
Claim 2
Dependent Claim
79 words
A process for catalytic reduction of nitrogen oxides (NO x ) in exhaust gases comprising treating the exhaust gas in the presence of a hydrogen donor with a catalyst comprising a zeolite Y dispersed in an amorphous matrix of oxide gel, said zeolite Y having been subjected to ion exchange to replace from 40 to 90 mole-% of its exchangeable ions with at least one ion selected from the group consisting of lithium ion and rare earth metal ions.
Claim 3
Dependent Claim
15 words
A process as recited in claim 1, wherein said exhaust gas is a combustion gas.
Claim 4
Dependent Claim
30 words
A process as recited in claim 1, wherein said catalyst comprises a mixture comprising at least 10% by weight zeolite Y and a maximum of 90% by weight oxide gel.
Claim 5
Dependent Claim
28 words
A process as recited in claim 3, wherein said mixture comprises from 15 to 40% by weight zeolite Y and from 60 to 85% by weight oxide gel.
Claim 6
Dependent Claim
36 words
A process as recited in claim 1, wherein said oxide gel is formed of at least one oxide selected from the group consisting of SiO 2 and the oxides of aluminum, magnesium, calcium, titanium and zirconium.
Claim 7
Dependent Claim
45 words
A process as recited in claim 5, wherein said oxide gel is selected from the group consisting of binary and ternary gels of SiO 2 and at least one oxide of a metal selected from the group consisting of aluminum, magnesium, calcium, titanium and zirconium.
Claim 8
Dependent Claim
28 words
A process as recited in claim 6, wherein said oxide gel comprises from 75 to 100% by weight SiO 2 and 0 to 25% by weight metal oxide.
Claim 9
Dependent Claim
29 words
A process as recited in claim 7, wherein said oxide gel comprises from 90 to 100% by weight SiO 2 and from 0 to 10% by weight metal oxide.
Claim 10
Dependent Claim
23 words
A process as recited in claim 1, wherein said catalyst additionally contains a metal or metal compound phase having a hydrogen binding capability.
Claim 11
Dependent Claim
20 words
A process as recited in claim 9, wherein said phase having hydrogen binding capability comprises at least one transition metal.
Claim 12
Dependent Claim
41 words
A process as recited in claim 10, wherein said transition metal is selected from the group consisting of metals having the atomic numbers 22 to 28, 40 to 46, 57 to 71 and 72 to 78 and compounds of such metals.
Claim 13
Dependent Claim
35 words
A process as recited in claim 11, wherein said transition metal is selected from the group consisting of metals having the atomic numbers 26 to 28 and 57 to 71 and compounds of such metals.
Claim 14
Dependent Claim
18 words
A process as recited in claim 9, wherein said phase having hydrogen binding capability comprises a chalcogen compound.
Claim 15
Dependent Claim
15 words
A process as recited in claim 13, wherein said chalcogen compound is an oxygen compound.
Claim 16
Dependent Claim
18 words
A process as recited in claim 9, wherein said phase having hydrogen binding capability comprises a metallic material.
Claim 17
Dependent Claim
28 words
A process as recited in claim 9, wherein said phase having hydrogen binding capability comprises from 0.05 to 15% by weight of the total mass of the catalyst.
Claim 18
Dependent Claim
28 words
A process as recited in claim 16, wherein said phase having hydrogen binding capability comprises from 0.1 to 5% by weight of the total mass of the catalyst.
Claim 19
Dependent Claim
24 words
A process as recited in claim 1, wherein said hydrogen donor is selected from the group consisting of hydrogen, ammonia, or a lower hydrocarbon.
Claim 20
Dependent Claim
13 words
A process as recited in claim 18, wherein said hydrogen donor is ammonia.
Claim 21
Dependent Claim
28 words
A process as recited in claim 1, wherein said exhaust gas is contacted with said catalyst at a temperature in the range from 150° C. to 350° C.
Claim 22
Dependent Claim
28 words
A process as recited in claim 20, wherein said exhaust gas is contacted with said catalyst at a temperature in the range from 150° C. to 280° C.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-08-20 | 1994-02-19 | 1994-08-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-08-20 | 1998-02-19 | 1998-08-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-08-20 | 2002-02-19 | 2002-08-21 | $7700.00 | Window Closed / Lapsed |