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US4950405A Expired / Lapsed US ⏱️ 0.0 years remaining

Functional thin organic membrane

Assignee: Fujifilm Corp
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Filing: 1989-10-18
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Granted: 1990-08-21
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Expires: 2009-10-18
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Abstract

Abstract A functional thin organic membrane comprising a monomolecular film which contains at least one organic amphoteric host molecule having a reactive functional group capable of chemically binding with a nucleophilic functional group at room temperature.

Inventors

  • 👤 Tsutomu Miyasaka
  • 👤 Yukio Maekawa
  • 👤 Hisashi Okamura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 16:21
CPC Classifications
B; B05; B05D; B05D1/00; B05D1/18; B05D1/20; B05D1/202; B01; B01D; B01D69/00; B01D69/12; B01D69/122; B82; B82Y; B82Y30/00; B82Y40/00; C; C07; C07K; C07K1/00; C07K1/14; C07K1/16; C07K1/18; C12; C12N; C12N11/00; C12N11/02; G; G01; G01N; G01N33/00; G01N33/48; G01N33/50; G01N33/53; G01N33/543; G01N33/54393; G01N33/544

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 323 words
A functional thin organic membrane comprising a monomolecular film which contains at least one organic amphoteric host molecule having a reactive functional group capable of chemically binding with a nucleophilic functional group at room temperature, wherein said at least one organic amphoteric host molecule is represented by formula (1) (A) .sub.m --L--(B).sub.n ( 1) wherein A represents a functional group capable of binding with a nucleophilic functional group at room temperature; L represents a single bond or a group having a valence of (m+n); B represents an organic residual group which imparts a monomolecular film forming ability to the compound of formula (1); and m and n are each an integer of from 1 to 3, and wherein said functional group represented by A is represented by one of formulae (2) to (6): ##STR9## wherein X 1 represents ##STR10## or --N--; Y 1 represents a hydrogen atom, --O--R 2 or ##STR11## R 1 represents a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, an aryl group having from 6 to 10 carbon atoms, or an aralkyl group having from 7 to 10 carbons atoms; R 2 is either the same as R 1 or represents an alkali metal atom or an ammonium atom; R 3 and R 4 , which may be the same or different, each has the same meaning as defined for R 1 , provided that R 3 and R 4 may combine to form a ring: --X.sup.2 --CH═CH.sub.2 ( 3) wherein X 2 represents --CO--, --SO--, or --SO 2 --; --X.sup.3 --CH.sub.2 CH.sub.2 --Y.sup.2 ( 4) wherein X 3 represents --CO--, --SO--, or --SO 2 --; and Y 2 represents a group capable of being released as a result of a β-elimination reaction upon contact with a base; ##STR12## wherein X 4 represents a group capable of being released as a result of a substitution reaction upon reaction with a primary amino group; and ##STR13##
Claim 2
Dependent Claim 323 words
A functional thin organic membrane comprising a monomolecular film which contains at least one organic amphoteric host molecule having a reactive functional group capable of chemically binding with a nucleophilic functional group at room temperature, wherein said at least one organic amphoteric host molecule is represented by formula (1) (A) .sub.m --L--(B).sub.n ( 1) wherein A represents a functional group capable of binding with a nucleophilic functional group at room temperature; L represents a single bond or a group having a valence of (m+n); B represents an organic residual group which imparts a monomolecular film forming ability to the compound of formula (1); and m and n are each an integer of from 1 to 3, and wherein said functional group represented by A is represented by one of formulae (2) to (6): ##STR9## wherein X 1 represents ##STR10## or --N--; Y 1 represents a hydrogen atom, --O--R 2 or ##STR11## R 1 represents a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, an aryl group having from 6 to 10 carbon atoms, or an aralkyl group having from 7 to 10 carbons atoms; R 2 is either the same as R 1 or represents an alkali metal atom or an ammonium atom; R 3 and R 4 , which may be the same or different, each has the same meaning as defined for R 1 , provided that R 3 and R 4 may combine to form a ring: --X.sup.2 --CH═CH.sub.2 ( 3) wherein X 2 represents --CO--, --SO--, or --SO 2 --; --X.sup.3 --CH.sub.2 CH.sub.2 --Y.sup.2 ( 4) wherein X 3 represents --CO--, --SO--, or --SO 2 --; and Y 2 represents a group capable of being released as a result of a β-elimination reaction upon contact with a base; ##STR12## wherein X 4 represents a group capable of being released as a result of a substitution reaction upon reaction with a primary amino group; and ##STR13##
Claim 3
Dependent Claim 34 words
A functional thin organic film as claimed in claim 1, wherein said reactive functional group represented by (A) is selected from the group consisting of a substituted cyanuric group, and an active vinyl group.
Claim 4
Dependent Claim 101 words
A functional thin organic membrane as in claim 1, wherein L is a divalent group selected from among an alkylene group, an arylene group, an alkenylene group, an alkynylene group, --O--, --S--, --NR 1 --CO--, --SO--, --SO 2 --, and ##STR14## any of which may be present individually or in combination, wherein R 7 and R 8 , which may be the same or different, each represent a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, an aryl group having from 6 to 10 carbon atoms, or an aralkyl group having from 7 to 10 carbon atoms.
Claim 5
Dependent Claim 58 words
A functional thin organic membrane as in claim 1, wherein said organic residual group which imparts a monomolecular film forming ability to said host compound, has from 10 to 30 carbon atoms, and may contain a functional group capable of entering into a polymerization reaction upon exposure to radiation, and may be partially substituted by a hydrophilic group.
Claim 6
Dependent Claim 30 words
A functional thin organic membrane as in claim 1, wherein said membrane comprises a multi-layered film, and said monomolecular film is located on the outermost layer of said multilayered film.
Claim 7
Dependent Claim 59 words
A functional thin organic membrane as in claim 7, wherein said monomolecular film or said multi-layered film is formed on a substrate, said substrate material being selected from the group consisting of electric conductors, glassy inorganic materials, other inorganic insulators, organic crystals, inorganic crystals, organic semi-conductors, inorganic semi-conductors, organic electric conductors, organic polymers, and composites of said substrate materials.
Claim 8
Dependent Claim 46 words
A functional thin organic membrane as in claim 5, wherein the multilayered film contains at least one other monomolecular film which contains at least one organic amphoteric host molecule having a reactive functional group capable of chemically binding with a nucleophilic functional group at room temperature.
Claim 9
Dependent Claim 39 words
A functional thin organic membrane as in claim 1, further comprising at least one water-soluble organic guest compound having a nucleophilic functional group which is chemically bonded to said at least one host molecule having a reactive functional group.
Claim 10
Dependent Claim 23 words
A functional thin organic membrane as in claim 8, wherein said at least one water-soluble organic guest compound is a physiologically active substance.
Claim 11
Dependent Claim 23 words
A functional thin organic membrane as in claim 9, wherein said physiologically active substance is selected from among enzymes, proteins, antigens, and antibodies.
Claim 12
Dependent Claim 22 words
A functional thin organic membrane as in claim 8, wherein said at least one water-soluble organic guest compound is a light-sensitive compound.
Claim 13
Dependent Claim 25 words
A functional thin organic membrane as in claim 8, wherein said nucleophilic functional group is an amino group, a hydroxyl group or a carboxyl group.
Claim 14
Dependent Claim 31 words
A functional thin organic membrane as in claim 1, wherein said reactive functional groups are present on the surface of said membrane at a maximum surface concentration to provide high reactivity.
Claim 15
Dependent Claim 25 words
A functional thin organic membrane as in claim 1, wherein said organic amphoteric host molecule is substantially water-insoluble and contains both hydrophilic and hydrophobic groups.
Claim 16
Dependent Claim 22 words
A functional thin organic membrane as in claim 1, wherein said monomolecular film is formed on the surface of an aqueous medium.
Claim 17
Dependent Claim 46 words
A functional thin organic membrane as in claim 15, wherein a nucleophilic guest compound is added to the aqueous medium whereby a chemical reaction occurs at the interface between the monomolecular film and the aqueous medium, said guest compound being chemically bonded to said host compound.
Claim 18
Dependent Claim 16 words
A functional thin organic membrane as in claim 1, wherein A is represented by formula (2).
Claim 19
Dependent Claim 16 words
A functional thin organic membrane as in claim 1, wherein A is represented by formula (3).

References Cited (Backward Citations)

US4632800A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-08-20 1994-02-19 1994-08-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-08-20 1998-02-19 1998-08-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-08-20 2002-02-19 2002-08-21 $7700.00 Window Closed / Lapsed

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