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US4950304A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for quenching or suppressing the fluorescence of substrates treated with fluorescent whitening agents

Assignee: Novartis Corp
•
Filing: 1988-09-23
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Granted: 1990-08-21
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Expires: 2008-09-23
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Abstract

Abstract There is disclosed a process for quenching or suppressing the fluorescence of natural or synthetic polyamide substrates treated, or to be treated, with fluorescent whitening agents, which process comprises applying to said substrates, before or after the treatment with the fluorescent whitening agent, a sulfonated UV absorber of formula ##STR1## wherein X, R 1 , R 2 and R 3 are as defined in claim 1, and fixing said UV absorber thereon.

Inventors

  • 👤 Gerhard Reinert
  • 👤 Kurt Burdeska

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 18:53
CPC Classifications
D; D06; D06M; D06M13/00; D06M13/322; D06M13/35; D06M13/355; D06M13/358; D06L; D06L4/00; D06L4/60; D06L4/686; D06M13/352; D06P; D06P1/00; D06P1/44; D06P1/62; D06P1/628; Y; Y10; Y10S; Y10S8/00; Y10S8/916; Y10S8/917; Y10S8/92; Y10S8/924

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 221 words
A process for quenching or suppressing the fluorescence of natural or synthetic polyamide substrates treated, or to be treated, with fluorescent whitening agents, which process comprises applying to said substrates, before or after the treatment with the fluorescent whitening agent, the step of applying a liquor containing at least 1% of ##STR12## wherein R 1 is hydrogen, halogen, C 1 -C 12 -alkyl, C 5 -C 6 -cycloalkyl, C 7 -C 9 -phenylalkyl or sulfo. R 2 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, halogen, hydroxy or sulfo, R 3 is hydrogen, C 1 -C 12 -alkyl, C 1 -C 4 -alkoxy, phenyl, C 1 -C 8 -alkylphenyl, C 5 -C 6 -cycloalkyl, C 2 -C 9 -alkoxycarbonyl, halogen, carboxy-C 1 -C 4 -alkyl, C 2 -C 9 -phenylalkyl or sulfo, and X is a radical of formula ##STR13## wherein R 4 is hydrogen, halogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 2 -C 9 -alkoxycarbonyl, carboxy or sulfo, R 5 is hydrogen or halogen and R 6 and R 7 are each independently of the other C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 5 -C 6 -cycloalkyl, phenyl or phenyl which is substituted by C 1 -C 4 -alkyl and hydroxy, and fixing said UV absorber thereon.
Claim 2
Dependent Claim 221 words
A process for quenching or suppressing the fluorescence of natural or synthetic polyamide substrates treated, or to be treated, with fluorescent whitening agents, which process comprises applying to said substrates, before or after the treatment with the fluorescent whitening agent, the step of applying a liquor containing at least 1% of ##STR12## wherein R 1 is hydrogen, halogen, C 1 -C 12 -alkyl, C 5 -C 6 -cycloalkyl, C 7 -C 9 -phenylalkyl or sulfo. R 2 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, halogen, hydroxy or sulfo, R 3 is hydrogen, C 1 -C 12 -alkyl, C 1 -C 4 -alkoxy, phenyl, C 1 -C 8 -alkylphenyl, C 5 -C 6 -cycloalkyl, C 2 -C 9 -alkoxycarbonyl, halogen, carboxy-C 1 -C 4 -alkyl, C 2 -C 9 -phenylalkyl or sulfo, and X is a radical of formula ##STR13## wherein R 4 is hydrogen, halogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 2 -C 9 -alkoxycarbonyl, carboxy or sulfo, R 5 is hydrogen or halogen and R 6 and R 7 are each independently of the other C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 5 -C 6 -cycloalkyl, phenyl or phenyl which is substituted by C 1 -C 4 -alkyl and hydroxy, and fixing said UV absorber thereon.
Claim 3
Dependent Claim 131 words
A process according to claim 1, which comprises applying a 2-phenylbenzenetriazole, or a salt thereof, of formula ##STR14## as UV absorber, wherein R 1 is hydrogen, C 1 -C 12 -alkyl, chlorine, C 5 -C 6 -cycloalkyl, C 7 -C 9 -phenylalkyl or sulfo. R 2 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, chlorine, hydroxy or sulfo, R 3 is C 1 -C 12 -alkyl, C 1 -C 4 -alkoxy, phenyl, C 1 -C 8 -alkylphenyl, C 5 -C 6 -cycloalkyl, C 2 -C 9 -alkoxycarbonyl, chlorine, carboxyethyl or C 7 -C 9 -phenylalkyl or sulfo, R 4 is hydrogen, chlorine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 2 -C 9 -alkoxycarbonyl, carboxy or sulfo, and R 5 is hydrogen or chlorine.
Claim 4
Dependent Claim 21 words
A process according to claim 2, which comprises applying the sodium salt of 3-(2'-H-benzotriazol-2'-yl)-5-tert-butyl-4-hydroxybenzenesulfonic acid, 3-(2'H-5'-chlorobenzotriazol-2'-yl)-5-butyl-4-hydroxybenzenesulfonic acid or 3-(2'H-benzotriazol-2'-yl)-5-sec-butyl-4-hydroxy benzenesulfonic acid,
Claim 5
Dependent Claim 97 words
A process according to claim 1, which comprises applying a 2-phenyl-s-triazine, or a salt thereof, of formula ##STR15## as UV absorber, wherein R 1 is hydrogen, halogen, C 1 -C 4 -alkyl or sulfo, R 2 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or hydroxy, R 3 is hydrogen or sulfo, and R 6 and R 7 are each independently of the other C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 5 -C 6 -cycloalkyl, phenyl or phenyl which is substituted by C 1 -C 4 -alkyl and hydroxy.
Claim 6
Dependent Claim 20 words
A process according to claim 4, which comprises applying the sodium salt of 3-(4',6'-diphenyl-s-triazin-2'-yl)-4-hydroxy-6-methoxybenzenesulfonic acid, 3-(4',6'-diphenyl-s-triazin-2'-yl)-4-hydroxy-6-ethoxybenzenesulfonic acid or 3-(4',6'-diphenyl-s-triazin-2'-yl)-4-hydroxy-6-propoxybenzenesulfonic acid.
Claim 7
Dependent Claim 25 words
A process according to claim 1, wherein the UV absorber is applied to the substrate before treatment with the fluorescent whitening agent and fixed thereon.
Claim 8
Dependent Claim 24 words
A process according to claim 1, wherein the UV absorber is applied to the substrate before, during or after dyeing or printing said substrate.
Claim 9
Dependent Claim 15 words
The natural or synthetic polyamide substrate treated by the process as claimed in claim 1.

References Cited (Backward Citations)

US4313732A Cited
WO1984002365A1 Cited
US4668235A Cited
US4770667A Cited
WO1986003528A1 Cited
US4698064A Cited
GB2174731A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-08-20 1994-02-19 1994-08-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-08-20 1998-02-19 1998-08-21 $3760.00 Window Closed / Lapsed
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