US4950304A
Expired / Lapsed
US
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Process for quenching or suppressing the fluorescence of substrates treated with fluorescent whitening agents
Assignee: Novartis Corp
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Filing: 1988-09-23
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Granted: 1990-08-21
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Expires: 2008-09-23
Abstract
Abstract There is disclosed a process for quenching or suppressing the fluorescence of natural or synthetic polyamide substrates treated, or to be treated, with fluorescent whitening agents, which process comprises applying to said substrates, before or after the treatment with the fluorescent whitening agent, a sulfonated UV absorber of formula ##STR1## wherein X, R 1 , R 2 and R 3 are as defined in claim 1, and fixing said UV absorber thereon.
Inventors
- 👤 Gerhard Reinert
- 👤 Kurt Burdeska
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 18:53
CPC Classifications
D; D06; D06M; D06M13/00; D06M13/322; D06M13/35; D06M13/355; D06M13/358; D06L; D06L4/00; D06L4/60; D06L4/686; D06M13/352; D06P; D06P1/00; D06P1/44; D06P1/62; D06P1/628; Y; Y10; Y10S; Y10S8/00; Y10S8/916; Y10S8/917; Y10S8/92; Y10S8/924
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
221 words
A process for quenching or suppressing the fluorescence of natural or synthetic polyamide substrates treated, or to be treated, with fluorescent whitening agents, which process comprises applying to said substrates, before or after the treatment with the fluorescent whitening agent, the step of applying a liquor containing at least 1% of ##STR12## wherein R 1 is hydrogen, halogen, C 1 -C 12 -alkyl, C 5 -C 6 -cycloalkyl, C 7 -C 9 -phenylalkyl or sulfo. R 2 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, halogen, hydroxy or sulfo, R 3 is hydrogen, C 1 -C 12 -alkyl, C 1 -C 4 -alkoxy, phenyl, C 1 -C 8 -alkylphenyl, C 5 -C 6 -cycloalkyl, C 2 -C 9 -alkoxycarbonyl, halogen, carboxy-C 1 -C 4 -alkyl, C 2 -C 9 -phenylalkyl or sulfo, and X is a radical of formula ##STR13## wherein R 4 is hydrogen, halogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 2 -C 9 -alkoxycarbonyl, carboxy or sulfo, R 5 is hydrogen or halogen and R 6 and R 7 are each independently of the other C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 5 -C 6 -cycloalkyl, phenyl or phenyl which is substituted by C 1 -C 4 -alkyl and hydroxy, and fixing said UV absorber thereon.
Claim 2
Dependent Claim
221 words
A process for quenching or suppressing the fluorescence of natural or synthetic polyamide substrates treated, or to be treated, with fluorescent whitening agents, which process comprises applying to said substrates, before or after the treatment with the fluorescent whitening agent, the step of applying a liquor containing at least 1% of ##STR12## wherein R 1 is hydrogen, halogen, C 1 -C 12 -alkyl, C 5 -C 6 -cycloalkyl, C 7 -C 9 -phenylalkyl or sulfo. R 2 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, halogen, hydroxy or sulfo, R 3 is hydrogen, C 1 -C 12 -alkyl, C 1 -C 4 -alkoxy, phenyl, C 1 -C 8 -alkylphenyl, C 5 -C 6 -cycloalkyl, C 2 -C 9 -alkoxycarbonyl, halogen, carboxy-C 1 -C 4 -alkyl, C 2 -C 9 -phenylalkyl or sulfo, and X is a radical of formula ##STR13## wherein R 4 is hydrogen, halogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 2 -C 9 -alkoxycarbonyl, carboxy or sulfo, R 5 is hydrogen or halogen and R 6 and R 7 are each independently of the other C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 5 -C 6 -cycloalkyl, phenyl or phenyl which is substituted by C 1 -C 4 -alkyl and hydroxy, and fixing said UV absorber thereon.
Claim 3
Dependent Claim
131 words
A process according to claim 1, which comprises applying a 2-phenylbenzenetriazole, or a salt thereof, of formula ##STR14## as UV absorber, wherein R 1 is hydrogen, C 1 -C 12 -alkyl, chlorine, C 5 -C 6 -cycloalkyl, C 7 -C 9 -phenylalkyl or sulfo. R 2 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, chlorine, hydroxy or sulfo, R 3 is C 1 -C 12 -alkyl, C 1 -C 4 -alkoxy, phenyl, C 1 -C 8 -alkylphenyl, C 5 -C 6 -cycloalkyl, C 2 -C 9 -alkoxycarbonyl, chlorine, carboxyethyl or C 7 -C 9 -phenylalkyl or sulfo, R 4 is hydrogen, chlorine, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 2 -C 9 -alkoxycarbonyl, carboxy or sulfo, and R 5 is hydrogen or chlorine.
Claim 4
Dependent Claim
21 words
A process according to claim 2, which comprises applying the sodium salt of 3-(2'-H-benzotriazol-2'-yl)-5-tert-butyl-4-hydroxybenzenesulfonic acid, 3-(2'H-5'-chlorobenzotriazol-2'-yl)-5-butyl-4-hydroxybenzenesulfonic acid or 3-(2'H-benzotriazol-2'-yl)-5-sec-butyl-4-hydroxy benzenesulfonic acid,
Claim 5
Dependent Claim
97 words
A process according to claim 1, which comprises applying a 2-phenyl-s-triazine, or a salt thereof, of formula ##STR15## as UV absorber, wherein R 1 is hydrogen, halogen, C 1 -C 4 -alkyl or sulfo, R 2 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy or hydroxy, R 3 is hydrogen or sulfo, and R 6 and R 7 are each independently of the other C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, C 5 -C 6 -cycloalkyl, phenyl or phenyl which is substituted by C 1 -C 4 -alkyl and hydroxy.
Claim 6
Dependent Claim
20 words
A process according to claim 4, which comprises applying the sodium salt of 3-(4',6'-diphenyl-s-triazin-2'-yl)-4-hydroxy-6-methoxybenzenesulfonic acid, 3-(4',6'-diphenyl-s-triazin-2'-yl)-4-hydroxy-6-ethoxybenzenesulfonic acid or 3-(4',6'-diphenyl-s-triazin-2'-yl)-4-hydroxy-6-propoxybenzenesulfonic acid.
Claim 7
Dependent Claim
25 words
A process according to claim 1, wherein the UV absorber is applied to the substrate before treatment with the fluorescent whitening agent and fixed thereon.
Claim 8
Dependent Claim
24 words
A process according to claim 1, wherein the UV absorber is applied to the substrate before, during or after dyeing or printing said substrate.
Claim 9
Dependent Claim
15 words
The natural or synthetic polyamide substrate treated by the process as claimed in claim 1.
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| 3.5 Years (Year 4) | 1993-08-20 | 1994-02-19 | 1994-08-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-08-20 | 1998-02-19 | 1998-08-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-08-20 | 2002-02-19 | 2002-08-21 | $7700.00 | Window Closed / Lapsed |