Infrared absorbing oxyindolizine dyes for dye-donor element used in laser-induced thermal dye transfer

Claim 2

In a dye-donor element for laser-induced thermal dye transfer comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in said dye layer, the improvement wherein said infrared-absorbing material is an oxyindolizine dye having the following formula: ##STR8## wherein: R 1 and R 2 each independently represents a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms or an aryl, cycloalkyl or hetaryl group having from about 5 to about 10 atoms; R 3 , R 4 , R 5 , R 6 and R 7 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R 3 , R 4 , R 5 , R 6 and R 7 groups may be combined with each other to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; Y represents oxygen, sulfur, selenium, tellurium, nitrogen or phosphorus; A and Z each independently represents hydrogen or the atoms necessary to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring, with the proviso that Z may be a ring only when Y is nitrogen or phosphorus; n is 0 to 2, with the proviso that n is 1 or 2 when Y is oxygen, sulfur, selenium or tellurium; and X is a monovalent anion.

Claim 3

The element of claim 1 wherein R 1 and R 2 are each methyl or phenyl.

Claim 4

The element of claim 1 wherein Y is oxygen or nitrogen.

Claim 5

The element of claim 1 wherein A represents the atoms necessary to complete a 6-membered heterocyclic ring.

Claim 6

The element of claim 1 wherein R 3 , R 4 , R 5 , R 6 , and R 7 each represent hydrogen or phenyl.

Claim 7

The element of claim 1 wherein said dye layer comprises sequential repeating areas of cyan, magenta and yellow dye.

Claim 8

In a process of forming a laser-induced thermal dye transfer image comprising (a) imagewise-heating by means of a laser a dye-donor element comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in said dye layer, and (b) transferring a dye image to a dye-receiving element to form said laser-induced thermal dye transfer image, the improvement wherein said infrared-absorbing material is an oxyindolizine dye having the following formula: ##STR9## wherein: R 1 and R 2 each independently represents a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms or an aryl, cycloalkyl or hetaryl group having from about 5 to about 10 atoms; R 3 , R 4 , R 5 , R 6 and R 7 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R 3 , R 4 , R 5 , R 6 and R 7 groups may be combined with each other to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; Y represents oxygen, sulfur, selenium, tellurium, nitrogen or phosphorus; A and Z each independently represents hydrogen or the atoms necessary to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring, with the proviso that Z may be a ring only when Y is nitrogen or phosphorus; n is 0 to 2, with the proviso that n is 1 or 2 when Y is oxygen, sulfur, selenium or tellurium; and X is a monovalent anion.

Claim 9

In a process of forming a laser-induced thermal dye transfer image comprising (a) imagewise-heating by means of a laser a dye-donor element comprising a support having thereon a dye layer and an infrared-absorbing material which is different from the dye in said dye layer, and (b) transferring a dye image to a dye-receiving element to form said laser-induced thermal dye transfer image, the improvement wherein said infrared-absorbing material is an oxyindolizine dye having the following formula: ##STR9## wherein: R 1 and R 2 each independently represents a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms or an aryl, cycloalkyl or hetaryl group having from about 5 to about 10 atoms; R 3 , R 4 , R 5 , R 6 and R 7 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R 3 , R 4 , R 5 , R 6 and R 7 groups may be combined with each other to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; Y represents oxygen, sulfur, selenium, tellurium, nitrogen or phosphorus; A and Z each independently represents hydrogen or the atoms necessary to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring, with the proviso that Z may be a ring only when Y is nitrogen or phosphorus; n is 0 to 2, with the proviso that n is 1 or 2 when Y is oxygen, sulfur, selenium or tellurium; and X is a monovalent anion.

Claim 10

The process of claim 7 wherein R 1 and R 2 are each methyl or phenyl.

Claim 11

The process of claim 7 wherein Y is oxygen or nitrogen.

Claim 12

The process of claim 7 wherein A represents the atoms necessary to complete a 6-membered heterocyclic ring.

Claim 13

The process of claim 7 wherein said support is poly(ethylene terephthalate) which is coated with sequential repeating areas of cyan, magenta and yellow dye, and said process steps are sequentially performed for each color to obtain a three-color dye transfer image.

Claim 14

In a thermal dye transfer assemblage comprising: (a) a dye-donor element comprising a support having a dye layer and an infrared absorbing material which is different from the dye in said dye layer, and (b) a dye-receiving element comprising a support having thereon a dye image-receiving layer, said dye-receiving element being in a superposed relationship with said dye-donor element so that said dye layer is adjacent to said dye image-receiving layer, the improvement wherein said infrared-absorbing material is an oxyindolizine dye having the following formula: ##STR10## wherein: R 1 and R 2 each independently represents a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms or an aryl, cycloalkyl or hetaryl group having from about 5 to about 10 atoms; R 3 , R 4 , R 5 , R 6 and R 7 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R 3 , R 4 , R 5 , R 6 and R 7 groups may be combined with each other to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; Y represents oxygen, sulfur, selenium, tellurium, nitrogen or phosphorus; A and Z each independently represents hydrogen or the atoms necessary to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring, with the proviso that Z may be a ring only when Y is nitrogen or phosphorus; n is 0 to 2, with the proviso that n is 1 or 2 when Y is oxygen, sulfur, selenium or tellurium; and X is a monovalent anion.

Claim 15

In a thermal dye transfer assemblage comprising: (a) a dye-donor element comprising a support having a dye layer and an infrared absorbing material which is different from the dye in said dye layer, and (b) a dye-receiving element comprising a support having thereon a dye image-receiving layer, said dye-receiving element being in a superposed relationship with said dye-donor element so that said dye layer is adjacent to said dye image-receiving layer, the improvement wherein said infrared-absorbing material is an oxyindolizine dye having the following formula: ##STR10## wherein: R 1 and R 2 each independently represents a substituted or unsubstituted alkyl group having from 1 to about 6 carbon atoms or an aryl, cycloalkyl or hetaryl group having from about 5 to about 10 atoms; R 3 , R 4 , R 5 , R 6 and R 7 each independently represents hydrogen, halogen, cyano, alkoxy, aryloxy, acyloxy, aryloxycarbonyl, alkoxycarbonyl, sulfonyl, carbamoyl, acyl, acylamido, alkylamino, arylamino or a substituted or unsubstituted alkyl, aryl or hetaryl group; or any two of said R 3 , R 4 , R 5 , R 6 and R 7 groups may be combined with each other to form a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring; Y represents oxygen, sulfur, selenium, tellurium, nitrogen or phosphorus; A and Z each independently represents hydrogen or the atoms necessary to complete a 5- to 7-membered substituted or unsubstituted carbocyclic or heterocyclic ring, with the proviso that Z may be a ring only when Y is nitrogen or phosphorus; n is 0 to 2, with the proviso that n is 1 or 2 when Y is oxygen, sulfur, selenium or tellurium; and X is a monovalent anion.

Claim 16

The assemblage of claim 12 wherein R 1 and R 2 are each methyl or phenyl

Claim 17

The assemblage of claim 12 wherein Y is oxygen or nitrogen.

Claim 18

The assemblage of claim 12 wherein A represents the atoms necessary to complete a 6-membered heterocyclic ring.

Claim 19

The assemblage of claim 12 wherein R 3 , R 4 , R 5 , R 6 , and R 7 each represent hydrogen or phenyl.

Claim 20

The assemblage of claim 12 wherein said support of the dye-donor element comprises poly(ethylene terephthalate) and said dye layer comprises sequential repeating areas of cyan, magenta and yellow dye.