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US4948718A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic silver halide elements containing solid particle dispersions of dyes

Assignee: Eastman Kodak Co
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Filing: 1989-06-27
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Granted: 1990-08-14
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Expires: 2009-06-27
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Abstract

Abstract Solid particle dispersions of dyes according to the formula: ##STR1## are useful as filter dyes in photographic elements. In this formula, R 1 and R 2 are each independently substituted or unsubstituted alkyl or substituted or unsubstituted aryl, or together represent the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered ring. R 3 and R 4 each independently represents H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, CO 2 H, or NHSO 2 R 6 . R 5 is H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, carboxylate, or substituted or unsubstituted acyl, R 6 and R 7 are each independently substituted or unsubstituted alkyl or substituted or unsubstituted aryl, and n is 1 or 2. R 8 is either substituted or unsubstituted alkyl, or is part of a double bond between the ring carbon atoms to which R 1 and R 2 are attached. At least one of the aryl rings of the dye molecule must have at least one substituent that is CO 2 H or NHSO 2 R 6 .

Inventors

  • 👤 Ronda E. Factor
  • 👤 Donald R. Diehl

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 22:18
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/825; G03C1/83; G03C1/832; C; C09; C09B; C09B23/00; C09B23/10; C09B23/105; C09B23/107

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 234 words
A photographic element comprising a support having thereon a radiation-sensitive silver halide emulsion layer and a layer, which is the same as or different from the silver halide layer, comprising a hydrophilic binder, and an amount effective as a photographic filter dye of a dispersion of solid particles, said dispersion consisting essentially of a compound having the formula: ##STR5## wherein R 1 and R 2 are each independently substituted or unsubstituted alkyl or aryl, or together represent the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered ring, R 3 and R 4 each independently represents H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, CO 2 H, or NHSO 2 R 6 , R 5 is H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, substituted or unsubstituted carboxylate, or substituted or unsubstituted acyl, R 6 and R 7 are each independently substituted or unsubstituted alkyl or substituted or unsubstituted aryl, R 8 is substituted or unsubstituted alkyl, or is part of a double bond between the ring carbon atoms to which R 1 and R 2 are attached, and n is 1 or 2, with the proviso that at least one of the aryl rings of the dye molecule has at least one substituent that is CO 2 H or NHSO 2 R 6 , the particles of said dispersion having a mean diameter of about 0.01 to 10 μm.
Claim 2
Dependent Claim 234 words
A photographic element comprising a support having thereon a radiation-sensitive silver halide emulsion layer and a layer, which is the same as or different from the silver halide layer, comprising a hydrophilic binder, and an amount effective as a photographic filter dye of a dispersion of solid particles, said dispersion consisting essentially of a compound having the formula: ##STR5## wherein R 1 and R 2 are each independently substituted or unsubstituted alkyl or aryl, or together represent the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered ring, R 3 and R 4 each independently represents H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, CO 2 H, or NHSO 2 R 6 , R 5 is H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, substituted or unsubstituted carboxylate, or substituted or unsubstituted acyl, R 6 and R 7 are each independently substituted or unsubstituted alkyl or substituted or unsubstituted aryl, R 8 is substituted or unsubstituted alkyl, or is part of a double bond between the ring carbon atoms to which R 1 and R 2 are attached, and n is 1 or 2, with the proviso that at least one of the aryl rings of the dye molecule has at least one substituent that is CO 2 H or NHSO 2 R 6 , the particles of said dispersion having a mean diameter of about 0.01 to 10 μm.
Claim 3
Dependent Claim 102 words
A photographic element according to claim 1 wherein R 1 and R 2 are each independently substituted or unsubstituted alkyl of from 1 to 6 carbon atoms, or together form a substituted or unsubstituted phenyl ring, R 3 is CO 2 H or NHSO 2 R 6 , R 4 is H, CO 2 H, or NHSO 2 R 6 , R 5 is substituted or unsubstituted alkyl of from 1 to 4 carbon atoms, R 6 is substituted or unsubstituted aryl of from 6 to 12 carbon atoms, R 7 is substituted or unsubstituted alkyl from 1 to 8 carbon atoms.
Claim 4
Dependent Claim 54 words
A photographic element according to claim 1 wherein R 1 and R 2 are each methyl or together with the carbon atoms to which they are attached, form a phenyl ring, R 3 is CO 2 H, R 4 is H or CO 2 H, R 5 is methyl, and R 7 is ethyl.
Claim 5
Dependent Claim 30 words
A photographic element according to claim 1 wherein R 8 is part of a double bond between the ring carbon atoms to which R 1 and R 2 are attached.
Claim 6
Dependent Claim 25 words
A photographic element according to any of claims 1-4 wherein the particles of said dispersion have a means diameter of about 0.01 to 1 μm.

References Cited (Backward Citations)

US2527583A Cited
US3282699A Cited
US4092168A Cited
US4110115A Cited
US4294917A Cited
US4294916A Cited
JPS59113434A Cited
US4542091A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-08-13 1994-02-12 1994-08-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-08-13 1998-02-12 1998-08-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-08-13 2002-02-12 2002-08-14 $7700.00 Window Closed / Lapsed

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