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US4946896A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic elastomer composition

Assignee: Sumitomo Chemical Co Ltd
•
Filing: 1988-11-01
•
Granted: 1990-08-07
•
Expires: 2008-11-01
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Abstract

Abstract There is provided a thermoplastic elastomer composition having excellent surface processabilities such as adhesion, paintability and printability together with impact resistance. This composition comprises (A) 20-80% by weight of a polypropylene resin, (B) 5-38% by weight of an ethylene copolymer having 82-98.7 mol % of an ethylene unit, 1-15 mol % of an ester unit selected from alkyl acrylate and methacrylate having an alkyl group of 1-8 carbon atoms and 0.3-3 mol % of an unsaturated dicarboxylic acid anhydride unit and (C) 5-70% by weight of ethylene-propylene and/or ethylene-propylene-non-conjugated diene copolymer rubber which contain 50-85 mol % of an ethylene unit and have a Mooney viscosity at 100 DEG C. of 20-100 and an iodine value of 20 or less.

Inventors

  • 👤 Tatsuyuki Mitsuno
  • 👤 Hideo Shinonaga
  • 👤 Akio Daimon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 08:54
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/10; C08L23/16; B; B41; B41M; B41M5/00; B41M5/50; B41M5/52; B41M5/5254; C08L2205/00; C08L2205/03; C08L23/04; C08L23/08; C08L23/0846; C08L23/0869; C08L2312/00

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 115 words
A thermoplastic elastomer composition which comprises (A) 20-80% by weight of a polypropylene resin, (B) 5-38% by weight of an ethylene copolymer having 82-98.7 mol % of an ethylene unit, 1-15 mol % of an ester unit selected from the group consisting of alkyl acrylate and alkyl methacrylate containing an alkyl group of 1-8 carbon atoms and 0.3-3 mol % of an unsaturated dicarboxylic acid anhydride unit and (C) 10-70% by weight of at least one of an ethylenepropylene copolymer rubber and an ethylene-propylene-nonconjugated diene copolymer rubber which contain 50-85 mol % of an ethylene unit and have a Mooney viscosity (ML 1+4 100° C.) of 20-100 and an iodine value of 20 or less.
Claim 2
Dependent Claim 115 words
A thermoplastic elastomer composition which comprises (A) 20-80% by weight of a polypropylene resin, (B) 5-38% by weight of an ethylene copolymer having 82-98.7 mol % of an ethylene unit, 1-15 mol % of an ester unit selected from the group consisting of alkyl acrylate and alkyl methacrylate containing an alkyl group of 1-8 carbon atoms and 0.3-3 mol % of an unsaturated dicarboxylic acid anhydride unit and (C) 10-70% by weight of at least one of an ethylenepropylene copolymer rubber and an ethylene-propylene-nonconjugated diene copolymer rubber which contain 50-85 mol % of an ethylene unit and have a Mooney viscosity (ML 1+4 100° C.) of 20-100 and an iodine value of 20 or less.
Claim 3
Dependent Claim 31 words
A thermoplastic elastomer composition according to claim 1 wherein the polypropylene resin is at least one member selected from crystalline polypropylene, crystalline propylene-ethylene block and random copolymers and crystalline propylene-α-olefin copolymers.
Claim 4
Dependent Claim 20 words
A thermoplastic elastomer composition according to claim 1 wherein the polypropylene resin has a melt index (JIS K6758) of 0.5-100.
Claim 5
Dependent Claim 37 words
A thermoplastic elastomer composition according to claim 1 wherein the ester unit contained in the ethylene copolymer is a monomer selected from methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, 2-ethylhexyl methacrylate and butyl methacrylate.
Claim 6
Dependent Claim 29 words
A thermoplastic elastomer composition according to claim 1 wherein the unsaturated dicarboxylic acid anhydride unit is a monomer selected from maleic anhydride, citraconic anhydride, itaconic anhydride and tetrahydrophthalic anhydride.
Claim 7
Dependent Claim 17 words
A thermoplastic elastomer composition according to claim 5 wherein the unsaturated dicarboxylic acid anhydride is maleic anhydride.
Claim 8
Dependent Claim 20 words
A thermoplastic elastomer composition according to claim 1 wherein the ethylene copolymer has a melt index (JIS K6760) of 0.5-300.
Claim 9
Dependent Claim 24 words
A thermoplastic elastomer composition according to claim 1 wherein the ethylene-propylene copolymer rubber and ethylene-propylene-non-conjugated diene copolymer rubber is crosslinked with an organic peroxide.
Claim 10
Dependent Claim 22 words
A thermoplastic elastomer composition according to claim 1 wherein the non-conjugated diene is selected from methyltetrahydroindene, 5-vinylnorbornene, 5-ethylidene-2-norbornene, dicyclopentadiene, 1,4-hexadiene and 1,6-octadiene.
Claim 11
Dependent Claim 12 words
A molded product prepared from the composition as defined in claim 1.
Claim 12
Dependent Claim 18 words
A molded product comprising a part for an automobile prepared from the composition as defined in claim 1.

References Cited (Backward Citations)

EP0058980A1 Cited
US4387186A Cited
EP0184321A2 Cited
US4619969A Cited
WO1986004912A1 Cited
EP0213720A2 Cited
US4686257A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-08-06 1994-02-05 1994-08-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-08-06 1998-02-05 1998-08-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-08-06 2002-02-05 2002-08-07 $7700.00 Window Closed / Lapsed

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