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US4944890A Expired / Lapsed US ⏱️ 0.0 years remaining

Compositions and process of using in refrigeration

Assignee: EIDP Inc
•
Filing: 1989-05-23
•
Granted: 1990-07-31
•
Expires: 2009-05-23
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Abstract

Abstract A blend of refrigerant with at least one fluorinated hydrocarbon, in which the weight ratio of fluorine-to-carbon is from about 0.5 to 5, and which has an SUS viscosity at 100° F. of at least 50 and a pour point of less than about -20° C. is disclosed for use in compression refrigeration.

Inventors

  • 👤 Thomas M. Deeb
  • 👤 George K. Henry
  • 👤 Heather L. Bergmann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 04:34
CPC Classifications
C; C10; C10M; C10M5/00; C10M111/00; C10M111/04; C09; C09K; C09K5/00; C09K5/02; C09K5/04; C09K5/041; C09K5/044; C09K5/045; C10M105/00; C10M105/50; C10M105/52; C10M107/00; C10M107/38; C10M131/00; C10M131/02; C10M131/04; C10M169/00; C10M169/04; C10M171/00; C10M171/008; C09K2205/00; C09K2205/24; C10M2211/00; C10M2211/02; C10M2211/0206; C10M2211/022; C10M2211/0225; C10M2211/024; C10M2211/0245; C10M2211/06; C10M2213/00; C10M2213/02; C10M2213/023; C10M2213/04; C10M2213/043; C10M2213/06; C10M2213/0606; C10M2213/062; C10M2213/0623; C10M2217/00; C10M2217/02; C10M2217/026; C10N; C10N2040/00; C10N2040/06; C10N2040/30; C10N2040/32; C10N2040/34; C10N2040/36; C10N2040/38; C10N2040/40; C10N2040/42; C10N2040/44; C10N2040/50

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 85 words
A composition for use in compression refrigeration comprising: (a) a saturated hydrocarbon having 1-4 carbon atoms that is partially or fully substituted with at least one atom of chlorine or fluorine and having a normal boiling point in the range of -80° C. to +50° C.; and (b) a sufficient amount to provide lubrication of at least one fluorinated hydrocarbon in which the weight ratio of fluorine-to-carbon is from about 0.5 to 5 and having an SUS viscosity at 100° F. of at least 50.
Claim 2
Dependent Claim 85 words
A composition for use in compression refrigeration comprising: (a) a saturated hydrocarbon having 1-4 carbon atoms that is partially or fully substituted with at least one atom of chlorine or fluorine and having a normal boiling point in the range of -80° C. to +50° C.; and (b) a sufficient amount to provide lubrication of at least one fluorinated hydrocarbon in which the weight ratio of fluorine-to-carbon is from about 0.5 to 5 and having an SUS viscosity at 100° F. of at least 50.
Claim 3
Dependent Claim 25 words
The composition of claim 1 wherein component (a) is at least one compound selected from the group consisting of 1,1,1,2-tetrafluoroethane; 1,1,2,2-tetrafluoroethane; pentafluoroethane; dichlorodifluoromethane; and trichlorotrifluoroethane.
Claim 4
Dependent Claim 36 words
The composition of claim 1 wherein component (b) is a polymer of R f (CH 2 ) n CH═CH 2 wherein R f is from CF 3 - to C 20 F 41 - and n=0-2.
Claim 5
Dependent Claim 34 words
The composition of claim 3 wherein R f comprises about 60% C 6 F 13 -, 30% C 8 F 17 - and about 10% C 10 F 21 - and higher; and n=1.
Claim 6
Dependent Claim 46 words
The composition of claim 3 wherein said polymer is a copolymer of R f (CH 2 ) n CH═CH 2 with 1-30% by weight of at least one comonomer selected from the group consisting of a vinyl ether, an acrylate, a methacrylate, acrylonitrile and vinyl ethoxylate.
Claim 7
Dependent Claim 12 words
This composition of claim 5 wherein said comonomer is butyl vinyl ether.
Claim 8
Dependent Claim 28 words
The composition of claim 3 wherein said polymer is a copolymer of R f (CH 2 ) n CH═CH 2 and 1-10% by weight of butyl vinyl ether.
Claim 9
Dependent Claim 10 words
The composition of claim 3 wherein component (a) is 1,1,1,2-tetrafluoroethane.
Claim 10
Dependent Claim 10 words
The composition of claim 7 wherein component (a) is 1,1,1,2-tetrafluoroethane.
Claim 11
Dependent Claim 41 words
The composition of claim 1 wherein component (b) is blended with at least one fluorinated hydrocarbon in which the weight ratio of fluorine-to-carbon is from about 0.5 to 5 and has an SUS viscosity at 100° F. of at least 50.
Claim 12
Dependent Claim 17 words
The composition of claim 3 wherein component (b) also contains up to 20% by weight of 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-7-hexadecene.
Claim 13
Dependent Claim 88 words
A lubricant adapted for use in compression refrigeration with a saturated hydrocarbon refrigerant having 1-4 carbon atoms that is partially or fully substituted with at least one atom of chlorine or fluorine and has a normal boiling point in the range of -80° C. to +50° C., consisting essentially of at least one fluorinated hydrocarbon in which the ratio of fluorine-to-carbon is from about 0.5 to 5, and has an SUS viscosity at 100° F. of at least 50 and a pour point of less than -20° C.
Claim 14
Dependent Claim 88 words
A lubricant adapted for use in compression refrigeration with a saturated hydrocarbon refrigerant having 1-4 carbon atoms that is partially or fully substituted with at least one atom of chlorine or fluorine and has a normal boiling point in the range of -80° C. to +50° C., consisting essentially of at least one fluorinated hydrocarbon in which the ratio of fluorine-to-carbon is from about 0.5 to 5, and has an SUS viscosity at 100° F. of at least 50 and a pour point of less than -20° C.
Claim 15
Independent Claim 101 words
A method for lubricating compression refrigeration equipment using as the refrigerant a saturated hydrocarbon having 1-4 carbon atoms that is partially or fully substituted with at least one atom of fluorine or chlorine and has a normal boiling point in the range of -80° C. to +50° C. consisting essentially of using 10-50% by volume of the combination with said refrigerant of at least one fluorinated hydrocarbon in which the weight ratio of fluorine-to-carbon is from about 0.5 to 5 and has an SUS viscosity at 100° F. of 100 to 1200 and a pour point of less than -20° C.
Claim 16
Independent Claim 101 words
A method for lubricating compression refrigeration equipment using as the refrigerant a saturated hydrocarbon having 1-4 carbon atoms that is partially or fully substituted with at least one atom of fluorine or chlorine and has a normal boiling point in the range of -80° C. to +50° C. consisting essentially of using 10-50% by volume of the combination with said refrigerant of at least one fluorinated hydrocarbon in which the weight ratio of fluorine-to-carbon is from about 0.5 to 5 and has an SUS viscosity at 100° F. of 100 to 1200 and a pour point of less than -20° C.

References Cited (Backward Citations)

US4359394A Cited
US4758366A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-07-30 1994-01-29 1994-07-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-07-30 1998-01-29 1998-07-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-07-30 2002-01-29 2002-07-31 $7700.00 Window Closed / Lapsed

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