US4943681A
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Optical recording medium and process for the production thereof
Assignee: Artience Co Ltd
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Filing: 1989-12-22
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Granted: 1990-07-24
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Expires: 2009-12-22
Abstract
Abstract An optical recording medium which comprises an organic thin film layer containing at least one of phthalocyanine compounds, due to which high light absorptivity to laser beams and high recording sensitivity can be obtained. The optical recording medium provided by the present invention has high chemical and physical stability. There is also disclosed a process for the production of the optical recording medium.
Inventors
- 👤 Takeshi Sato
- 👤 Shuji Miyazaki
- 👤 Makoto Sakamoto
- 👤 Motonori Ando
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 10:03
CPC Classifications
G; G11; G11B; G11B7/00; G11B7/24; G11B7/241; G11B7/242; G11B7/244; G11B7/246; G11B7/248; Y; Y10; Y10S; Y10S430/00; Y10S430/146
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
515 words
An optical recording medium which comprises an organic thin film layer containing at least one of phthalocyanine compounds represented by the following general formula (I) ##STR13## wherein rings A 1 to A 4 each independently represent a benzene ring, naphthalene ring or anthracene ring, M represents Al, Ga, In, Si, Ge or Sn, X's may be identical or different, and each represents an alkyl group which may have a substituent, an aryl group which may have a substituent, a heteroring moiety which may have a substituent, a phthalimidomethyl group which may have a substituent, a halogen atom, a nitro group, a cyano group, a sulfonic acid group, --OR 1 , --SR 2 , --COOR 3 , ##STR14## ##STR15## in which R 1 to R 11 may be identical or different, and each represents a hydrogen atom, an alkyl group which may have a substituent, an aryl group which may have a substituent, an acyl group which may have a substituent, a cycloalkyl group which may have a substituent, or a polyether group which may have a substituent, or R 6 and R 7 , R 8 and R 9 or R 10 and R 11 may form a four to seven-membered heteroring, and these four to seven-membered ring may further contain a nitrogen atom, oxygen atom or sulfur atom, and R 12 , R 13 and R 14 may be identical or different, and each represents an alkyl group which may have a substituent, a cylcoalky group which may have a substituent, or an aryl group which may have a substituent, ##STR16## or --O--Se--R 23 , and Z represents hydrogen, a halogen atom, a hydroxyl group, an alkyl group which may have a substitutent, ##STR17## in which R 15 , R 16 , R 21 , R 22 , R 23 , R 24 , R 25 , R 26 , R 27 and R 32 may be identical or different, and each represents an alkyl group which may have a substituent, an aryl group which may have a substituent, an acyl group which may have a substituent, a cycloalkyl group which may have a substituent, an alkoxy group which may have a substituent, an aryloxy group which may have a substituent, a polyether group which may have a substituent, a hydroxyl group, or a halogen atom, and in which R 17 , R 18 , R 19 , R 20 , R 28 , R 29 , R 30 and R 31 may be identical or different, and each represents an alkyl group which may have a substituent, an aryl group which may have a substituent, an acyl group which may have a substituent, a cycloalkyl group which may have a substituent, an alkoxy group which may have a substituent, an aryloxy group which may have a substituent, a polyether group which may have a substituent, a hydroxyl group, a halogen atom or a hydrogen atom, and W represents O, S, Se or Te, k, l, m and n each independently represent an integer of 0 to 8, and p represents 0 or 1.
Claim 2
Dependent Claim
515 words
An optical recording medium which comprises an organic thin film layer containing at least one of phthalocyanine compounds represented by the following general formula (I) ##STR13## wherein rings A 1 to A 4 each independently represent a benzene ring, naphthalene ring or anthracene ring, M represents Al, Ga, In, Si, Ge or Sn, X's may be identical or different, and each represents an alkyl group which may have a substituent, an aryl group which may have a substituent, a heteroring moiety which may have a substituent, a phthalimidomethyl group which may have a substituent, a halogen atom, a nitro group, a cyano group, a sulfonic acid group, --OR 1 , --SR 2 , --COOR 3 , ##STR14## ##STR15## in which R 1 to R 11 may be identical or different, and each represents a hydrogen atom, an alkyl group which may have a substituent, an aryl group which may have a substituent, an acyl group which may have a substituent, a cycloalkyl group which may have a substituent, or a polyether group which may have a substituent, or R 6 and R 7 , R 8 and R 9 or R 10 and R 11 may form a four to seven-membered heteroring, and these four to seven-membered ring may further contain a nitrogen atom, oxygen atom or sulfur atom, and R 12 , R 13 and R 14 may be identical or different, and each represents an alkyl group which may have a substituent, a cylcoalky group which may have a substituent, or an aryl group which may have a substituent, ##STR16## or --O--Se--R 23 , and Z represents hydrogen, a halogen atom, a hydroxyl group, an alkyl group which may have a substitutent, ##STR17## in which R 15 , R 16 , R 21 , R 22 , R 23 , R 24 , R 25 , R 26 , R 27 and R 32 may be identical or different, and each represents an alkyl group which may have a substituent, an aryl group which may have a substituent, an acyl group which may have a substituent, a cycloalkyl group which may have a substituent, an alkoxy group which may have a substituent, an aryloxy group which may have a substituent, a polyether group which may have a substituent, a hydroxyl group, or a halogen atom, and in which R 17 , R 18 , R 19 , R 20 , R 28 , R 29 , R 30 and R 31 may be identical or different, and each represents an alkyl group which may have a substituent, an aryl group which may have a substituent, an acyl group which may have a substituent, a cycloalkyl group which may have a substituent, an alkoxy group which may have a substituent, an aryloxy group which may have a substituent, a polyether group which may have a substituent, a hydroxyl group, a halogen atom or a hydrogen atom, and W represents O, S, Se or Te, k, l, m and n each independently represent an integer of 0 to 8, and p represents 0 or 1.
Claim 3
Dependent Claim
19 words
An optical recording medium according to claim 1 wherein all of the rings A' to A' are naphthalene rings.
Claim 4
Dependent Claim
14 words
An optical recording medium according to claim 1 wherein M is Si or Ge.
Claim 5
Dependent Claim
23 words
An optical recording medium according to claim 1 wherein X is a linear or branched alkyl group having 1 to 18 carbon atoms.
Claim 6
Dependent Claim
14 words
An optical recording medium according to claim 1 wherein X is a phthalimidomethyl group.
Claim 7
Dependent Claim
21 words
An optical recording medium according to claim 1 wherein k, l, m and n amount to 4 to 6 in total.
Claim 8
Dependent Claim
34 words
An optical recording medium according to claim 1 wherein each of Y and Z is a diphenylphosphinoxy group represented by the formula ##STR18## wherein R 21 and R 22 each represent a phenyl group.
Claim 9
Dependent Claim
34 words
An optical recording medium according to claim 3 wherein each of Y and Z is a diphenylphosphinoxy group represented by the formula ##STR19## wherein R 21 and R 22 each represent a phenyl group.
Claim 10
Dependent Claim
17 words
An optical recording medium according to claim 7 wherein A 1 to A 4 each are naphthalene.
Claim 11
Dependent Claim
23 words
An optical recording medium according to claim 9 wherein X is a linear or branched alkyl group having 1 to 18 carbon atoms.
Claim 12
Dependent Claim
14 words
An optical recording medium according to claim 9 wherein X is a phthalimidomethyl group.
Claim 13
Dependent Claim
27 words
An optical recording medium according to claim 10 wherein the phthalocyanine compound is a siliconnaphthalocyanine compound in which each of K, l, m and n is 1.
Claim 14
Dependent Claim
18 words
An optical recording medium according to claim 12 wherein the siliconnaphthaocyanine compound has 1 to 2 halogen atoms.
Claim 15
Dependent Claim
50 words
A process for the production of an optical recording medium, which comprises dissolving at least one phathalocyanine compound recited in claim 1 in an aliphatic hydrocarbon having at least one unsaturated bond, coating the resultant solution on a transparent substrate, and drying the resultant coating to form a recording film.
Claim 16
Dependent Claim
35 words
A process according to claim 14 wherein the aliphatic hydrocarbon is at least one aliphatic hydrocarbon selected from a group consisting of alkenes, cycloalkenes, alkynes, cycloalkynes and these with a hydroxyl group in their skeleton.
Claim 17
Dependent Claim
52 words
A process according to claim 14 wherein the phthalocyanine compound is that in which each of rings A 1 to A 4 is a naphthalene ring and each of Y and Z is a diphenylphosphinoxy group represented by the formula ##STR20## wherein R 21 and R 22 each represent a phenyl group.
Claim 18
Dependent Claim
52 words
A process according to claim 15 wherein the phthalocyanine compound is that in which each of rings A 1 to A 4 is a naphthalene ring and each of Y and Z is a diphenylphosphinoxy group represented by the formula ##STR21## wherein R 21 and R 22 each represent a phenyl group.
Claim 19
Dependent Claim
16 words
A process according to claim 14 wherein the transparent substrate is formed of a polycarbonate resin.
References Cited (Backward Citations)
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| 3.5 Years (Year 4) | 1993-07-23 | 1994-01-22 | 1994-07-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-07-23 | 1998-01-22 | 1998-07-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-07-23 | 2002-01-22 | 2002-07-24 | $7700.00 | Window Closed / Lapsed |