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US4942200A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyamide-polyarylate composition containing elastomeric modifier and epoxy-functional copolymer

Assignee: EIDP Inc
•
Filing: 1988-03-09
•
Granted: 1990-07-17
•
Expires: 2008-03-09
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Abstract

Abstract Thermoplastic compositions consisting essentially of 25-80 weight percent polyamide, 10-70 weight percent polyarylate, 0.5-30 weight percent elastomeric modifier, and 0.5-7 weight percent epoxy functional polymer, where the epoxy functional polymer and the polyarylate are preblended with each other, show unexpectedly superior resistance to high speed puncture, even as compared with the same formulation absent preblending.

Inventors

  • 👤 Edmund A. Flexman
  • 👤 James J. Sosnowski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 20:58
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; C08L67/03; C08L77/00

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 164 words
A polyamide/polyarylate composition consisting essentially of: (a) 25-80 weight percent of at least one polyamide resin, (b) 10-70 weight percent of at least one polyarylate resin, (c) 0.5-30 weight percent of at least one elastomeric modifier which is a graft polymer consisting essentially of at least one monomer containing a functional acid group and at least one substantially saturated copolymer of ethylene and C 3 -C 8 alpha-olefins, and (d) 0.5-7 weight percent of at least one epoxy functional polymer which is a copolymer comprised of at least two of the following monomers: ##STR4## where the monomers of formula (a) comprise 50-99 weight percent of the copolymer, the monomers of formula (b) comprise 0-40 weight percent of the copolymer, and the monomer of formula (c) comprise 1-10 weight percent of the copolymer, wherein the epoxy functional polymer and the polyarylate are blended with each other before either the epoxy functional polymer of the polyarylate are blended with either the polyamide or the elastomeric modifier.
Claim 2
Dependent Claim 164 words
A polyamide/polyarylate composition consisting essentially of: (a) 25-80 weight percent of at least one polyamide resin, (b) 10-70 weight percent of at least one polyarylate resin, (c) 0.5-30 weight percent of at least one elastomeric modifier which is a graft polymer consisting essentially of at least one monomer containing a functional acid group and at least one substantially saturated copolymer of ethylene and C 3 -C 8 alpha-olefins, and (d) 0.5-7 weight percent of at least one epoxy functional polymer which is a copolymer comprised of at least two of the following monomers: ##STR4## where the monomers of formula (a) comprise 50-99 weight percent of the copolymer, the monomers of formula (b) comprise 0-40 weight percent of the copolymer, and the monomer of formula (c) comprise 1-10 weight percent of the copolymer, wherein the epoxy functional polymer and the polyarylate are blended with each other before either the epoxy functional polymer of the polyarylate are blended with either the polyamide or the elastomeric modifier.
Claim 3
Dependent Claim 14 words
The composition of claim 1 wherein the weight percent of component (a) is 30-75.
Claim 4
Dependent Claim 14 words
The composition of claim 1 wherein the weight percent of component (a) is 40-75.
Claim 5
Dependent Claim 14 words
The composition of claim 1 wherein the weight percent of component (b) is 15-60.
Claim 6
Dependent Claim 14 words
The composition of claim 1 wherein the weight percent of component (b) is 20-50.
Claim 7
Dependent Claim 14 words
The composition of claim 1 wherein the weight percent of component (c) is 1-25.
Claim 8
Dependent Claim 14 words
The composition of claim 1 wherein the weight percent of component (c) is 2-20.
Claim 9
Dependent Claim 14 words
The composition of claim 1 wherein the weight percent of component (d) is 1-6.
Claim 10
Dependent Claim 14 words
The composition of claim 1 wherein the weight percent of component (d) is 1.5-5.
Claim 11
Dependent Claim 28 words
The composition of claim 1 wherein component (a) is selected from 66 nylon, 69 nylon, 610 nylon,612 nylon, polyamides produced by ring opening of lactams, and copolymers thereof.
Claim 12
Dependent Claim 18 words
The composition of claim 10 wherein the polyamide produced by ring opening of a lactam is 6 nylon.
Claim 13
Dependent Claim 13 words
The composition of claim 1 wherein component (a) is selected from 66 nylons.
Claim 14
Dependent Claim 36 words
The composition of claim 1 wherein component (b) is the reaction product of at least one compound selected from dihydric phenols and derivatives thereof, and at least one compound selected from dicarboxylic acids and derivatives thereof.
Claim 15
Dependent Claim 29 words
The composition of claim 1 wherein component (b) is the reaction product of 2,2,-bis(4-hydroxy-phenyl) propane and at least one compound selected from terephthalic acid, isophthalic acid, and derivatives thereof.
Claim 16
Dependent Claim 22 words
The composition of claim 14 wherein the ratio of isophthalic acid and derivatives thereof to terephthalic acid and derivatives thereof is 100:0-50:50.
Claim 17
Dependent Claim 46 words
The composition of claim 1 wherein component (c) is characterized by having adherent sites, having a tensile modulus in the range of 1-20,000 p.s.i., and having a ratio of tensile modulus of the polyamide to tensile modulus of the modifier of greater than 10 to 1.
Claim 18
Dependent Claim 29 words
The composition of claim 1 wherein the at least one monomer containing a functional acid group is selected from unsaturated carboxylic acids, diacids, monoesters of such diacids, and anhydrides.
Claim 19
Dependent Claim 15 words
The composition of claim 17 wherein the monomer is fumaric acid, maleic anhydride, maleic acid.
Claim 20
Dependent Claim 26 words
The composition of claim 18 wherein the copolymer is derived from ethylene, propylene, and 1,4-hexadiene or the copolymer is derived from ethylene, propylene, 1,4-hexadiene and norbornadiene.
Claim 21
Dependent Claim 29 words
The composition of claim 1 wherein the epoxy functional polymer is a copolymer of 65-84 weight percent ethylene, 20-30 weight percent n-butyl acrylate, and 1-5 weight percent glycidyl methacrylate.
Claim 22
Dependent Claim 24 words
The composition of claim 19 wherein the epoxy functional polymer is a copolymer of 95-99 weight percent ethylene and 1-5 weight percent glycidyl methacrylate.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-07-16 1994-01-15 1994-07-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-07-16 1998-01-15 1998-07-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-07-16 2002-01-15 2002-07-17 $7700.00 Window Closed / Lapsed

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