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US4935476A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of amine-modified ethylene/carboxylic acid copolymers, such copolymers, and use thereof as adhesion promoters and cable sheathing

Assignee: BASF SE
•
Filing: 1989-08-30
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Granted: 1990-06-19
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Expires: 2009-08-30
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Abstract

Abstract A high molecular weight ethylene copolymer is prepared by high-pressure copolymerization of ethylene with an α,β-ethylenically unsaturated carboxylic acid, carboxylic anhydride or a derivative thereof in the presence of a tertiary organic monoamine, preferably from 10 to 100 mol % thereof, based on the unsaturated carboxylic acid used, and can be used for preparing adhesion promoters and cable sheathing.

Inventors

  • 👤 Norbert Hasenbein
  • 👤 Thomas Muehlenbernd
  • 👤 Gernot Koehler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 08:50
CPC Classifications
C; C08; C08F; C08F210/00; C08F210/02; C08F8/00; C08F8/30; C08F8/32

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 88 words
A process for preparing a high molecular weight ethylene copolymer having a melt flow index to less than 40 g/10 min by copolymerization of ethylene with an α,β-ethylenically unsaturated acrylic acid, carboxylic anhydride or a derivative thereof in a polymerization system at pressures of from 500 to 5,000 bar and temperatures of from 40° to 350° C. in the presence of a free-radical polymerization initiator and in the presence or absence of a molecular weight regulator, which comprises copolymerizing in the additional presence of a tertiary organic monoamine.
Claim 2
Dependent Claim 88 words
A process for preparing a high molecular weight ethylene copolymer having a melt flow index to less than 40 g/10 min by copolymerization of ethylene with an α,β-ethylenically unsaturated acrylic acid, carboxylic anhydride or a derivative thereof in a polymerization system at pressures of from 500 to 5,000 bar and temperatures of from 40° to 350° C. in the presence of a free-radical polymerization initiator and in the presence or absence of a molecular weight regulator, which comprises copolymerizing in the additional presence of a tertiary organic monoamine.
Claim 3
Dependent Claim 36 words
A process as claimed in claim 1, wherein the copolymerization is carried out in the presence of from 10 to about 100 mol%, based on the unsaturated carboxylic acid compound used, of the tertiary organic amine.
Claim 4
Dependent Claim 22 words
A process as claimed in claim 1, wherein the copolymerization is carried out in the presence of an aliphatic tertiary organic amine.
Claim 5
Dependent Claim 29 words
A process as claimed in claim 3, wherein the copolymerization is carried out in the presence of a trialkylamine which contains alkyls of from 1 to 18 carbon atoms.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-06-18 1993-12-18 1994-06-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-06-18 1997-12-18 1998-06-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-06-18 2001-12-18 2002-06-19 $7700.00 Window Closed / Lapsed

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