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US4929800A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrocarbon conversion and polymerization catalyst and method of making and using same

Assignee: University of Florida
•
Filing: 1988-08-09
•
Granted: 1990-05-29
•
Expires: 2008-08-09
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Abstract

Abstract Hydrocarbon conversion processes are disclosed using a catalyst prepared by a method comprising reacting an adsorbent containing surface hydroxyl groups with a Lewis acid in a halogenated organic solvent.

Inventors

  • 👤 Russell S. Drago
  • 👤 Edward E. Getty

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 14:20
CPC Classifications
B; B01; B01J; B01J27/00; B01J27/06; B01J27/08

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 107 words
In a hydrocarbon conversion process selected from the group consisting of isomerization and alkylation wherein at least one hydrocarbon is contacted with a conversation catalyst under conversion conditions, the improvement comprising contacting aid hydrocarbon with a catalyst prepared by reacting an adsorbent solid containing surface hydroxyl groups with a Lewis acid selected from the group consisting of aluminum halides, antimony halides and mixtures thereof and a halogenated organic solvent selected from the group consisting of CCl 4 , CHCl 3 and mixtures thereof at a temperature and for a time sufficient for said Lewis acid to react with at least a portion of said surface hydroxyl groups.
Claim 2
Dependent Claim 107 words
In a hydrocarbon conversion process selected from the group consisting of isomerization and alkylation wherein at least one hydrocarbon is contacted with a conversation catalyst under conversion conditions, the improvement comprising contacting aid hydrocarbon with a catalyst prepared by reacting an adsorbent solid containing surface hydroxyl groups with a Lewis acid selected from the group consisting of aluminum halides, antimony halides and mixtures thereof and a halogenated organic solvent selected from the group consisting of CCl 4 , CHCl 3 and mixtures thereof at a temperature and for a time sufficient for said Lewis acid to react with at least a portion of said surface hydroxyl groups.
Claim 3
Dependent Claim 11 words
The process of claim 1 wherein said hydrocarbon conversion is isomerization.
Claim 4
Dependent Claim 11 words
The process of claim 1 wherein said hydrocarbon conversion is alkylation.
Claim 5
Dependent Claim 105 words
In a polymerization method wherein a monomer or mixture or monomers is contacted under polymerization conditions with a free radical polymerization catalyst, the improvement comprising contacting said monomer or mixture of monomers with a catalyst prepared by reacting an adsorbent solid containing surface hydroxyl groups with a Lewis acid selected from the group consisting of aluminum halides, antimony halides and mixtures thereof and a halogenated organic solvent selected from the group consisting of CCl 4 , CHCl 3 and mixtures thereof at a temperature and for a time sufficient for said Lewis acid to react with at least a portion of said surface hydroxyl groups.
Claim 6
Dependent Claim 105 words
In a polymerization method wherein a monomer or mixture or monomers is contacted under polymerization conditions with a free radical polymerization catalyst, the improvement comprising contacting said monomer or mixture of monomers with a catalyst prepared by reacting an adsorbent solid containing surface hydroxyl groups with a Lewis acid selected from the group consisting of aluminum halides, antimony halides and mixtures thereof and a halogenated organic solvent selected from the group consisting of CCl 4 , CHCl 3 and mixtures thereof at a temperature and for a time sufficient for said Lewis acid to react with at least a portion of said surface hydroxyl groups.
Claim 7
Dependent Claim 19 words
The polymerization method of claim 3 wherein a mixture of styrene and methyl methacrylate is contacted with said catalyst.

References Cited (Backward Citations)

US3248343A Cited
US3925251A Cited
US3925194A Cited
US3993587A Cited
US3960711A Cited
US4798667A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-05-28 1993-11-27 1994-05-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-05-28 1997-11-27 1998-05-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-05-28 2001-11-27 2002-05-29 $7700.00 Window Closed / Lapsed

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