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US4927949A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of preparing an aminoalkylalkoxysilane

Assignee: Momentive Performance Materials Japan LLC
•
Filing: 1989-09-13
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Granted: 1990-05-22
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Expires: 2009-09-13
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Abstract

Abstract An improved method of preparing an aminoalkylalkoxy silane of the formula: ##STR1## in which R 1 and R 2 independently are alkyl groups having 1-8 carbon atoms, R 3 is a hydrogen atom or an alkyl group having 1-6 carbon atoms, R 4 and R 5 independently are a member selected from the group consisting of a hydrogen atom, an alkyl group having 1-10 carbon atoms, --CH 2 CH 2 NH 2 , --CH 2 CH 2 NHCH 2 CH 2 NH 2 , an allyl group, a substituted phenyl group and a nonsubstituted phenyl group and a is an integer from 0-2, comprises the step of reacting a silane compound with an allylamine in the presence of a catalyst composition selected from the group consisting of (1) a rhodium complex catalyst and a heterocyclic compound containing nitrogen and/or sulfur atoms and (2) a rhodium complex catalyst having a heterocyclic compound containing nitrogen and/or sulfur atoms as a ligand.

Inventors

  • 👤 Keiji Kabeta
  • 👤 Michio Zenbayashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 21:52
CPC Classifications
C; C07; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/18; C07F7/1804; C07F7/1872; C07F7/1876

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 189 words
A method of preparing an aminoalkylalkoxysilane of the formula: ##STR4## in which R 1 and R 2 independently are alkyl groups having 1-8 carbon atoms, R 3 is a hydrogen atom or an alkyl group having 1-6 carbon atoms, R 4 and R 5 independently are a member selected from the group consisting of a hydrogen atom, an alkyl group having 1-10 carbon atoms, --CH 2 CH 2 NH 2 , --CH 2 CH 2 NHCH 2 CH 2 NH 2 , an allyl group, a substituted phenyl group and a nonsubstituted phenyl group and a is an integer from 0-2, comprising the step of reacting an alkoxysilane of the formula: R.sub.a.sup.1 HSi(OR.sup.2).sub.3-a, where R 1 , R 2 and a are described above, with an allylamine of the formula: ##STR5## where R 3 , R 4 and R 5 are as described above, in the presence of a catalyst composition selected from the group consisting of (1) a rhodium complex catalyst and a heterocyclic compound containing nitrogen and/or sulfur atoms and (2) a rhodium complex catalyst having a heterocyclic compound containing nitrogen and/or sulfur atoms as a ligand.
Claim 2
Independent Claim 189 words
A method of preparing an aminoalkylalkoxysilane of the formula: ##STR4## in which R 1 and R 2 independently are alkyl groups having 1-8 carbon atoms, R 3 is a hydrogen atom or an alkyl group having 1-6 carbon atoms, R 4 and R 5 independently are a member selected from the group consisting of a hydrogen atom, an alkyl group having 1-10 carbon atoms, --CH 2 CH 2 NH 2 , --CH 2 CH 2 NHCH 2 CH 2 NH 2 , an allyl group, a substituted phenyl group and a nonsubstituted phenyl group and a is an integer from 0-2, comprising the step of reacting an alkoxysilane of the formula: R.sub.a.sup.1 HSi(OR.sup.2).sub.3-a, where R 1 , R 2 and a are described above, with an allylamine of the formula: ##STR5## where R 3 , R 4 and R 5 are as described above, in the presence of a catalyst composition selected from the group consisting of (1) a rhodium complex catalyst and a heterocyclic compound containing nitrogen and/or sulfur atoms and (2) a rhodium complex catalyst having a heterocyclic compound containing nitrogen and/or sulfur atoms as a ligand.
Claim 3
Dependent Claim 26 words
The method of claim 1, wherein said catalyst composition is a rhodium complex catalyst having a heterocyclic compound containing nitrogen and/or sulfur atoms as a ligand.
Claim 4
Dependent Claim 18 words
The method of claim 2, wherein said catalyst composition is formed in-situ, during the preparation of the aminoalkylalkoxysilane.
Claim 5
Dependent Claim 23 words
The method of claim 1, wherein said catalyst composition is a rhodium complex catalyst and a heterocyclic compound containing nitrogen and/or sulfur atoms.

References Cited (Backward Citations)

US3470225A Cited
US3864373A Cited
US4481364A Cited
US4556722A Cited
EP0284447A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-05-21 1993-11-20 1994-05-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-05-21 1997-11-20 1998-05-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-05-21 2001-11-20 2002-05-22 $7700.00 Window Closed / Lapsed

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