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US4927612A Expired / Lapsed US ⏱️ 0.0 years remaining

Reduction of nitrogen- and carbon-based pollutants

Assignee: Fuel Tech Inc
•
Filing: 1988-06-02
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Granted: 1990-05-22
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Expires: 2008-06-02
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Abstract

Abstract Disclosed is a process for reducing nitrogen oxides in an efflucent from the combustion of a carbonaceous fuel under oxygen-rich conditions which minimize the production of carbon-based pollutants. A dispersion of a solution comprising at least one additive compound selected from the group consisting of guanidine, guanidine carbonate, biguanide, guanylurea sulfate, melamine, dicyandiamide, calcium cyanamide, biuret, 1,1'-azobisformamide, methylol urea, methylol urea-urea condensation product, dimethylol urea, methyl urea, dimethyl urea, and hexamethylenetetramine is injected into an effluent at a temperature above 1300° F., and preferably above 1500° F. The concentration of the additive compound in solution, the temperature of the effluent at the point of injection, and the size of the droplets in the dispersion, are selected to provide a reduction in nitrogen oxides. When urea is employed in combination with hexamethylenetetramine, the effectiveness of the urea is enhanced, particularly at temperatures 1800° F., and below.

Inventors

  • 👤 Wayne E. Bowers

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 08:08
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/54; B01D53/56

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 78 words
A process for reducing the concentration of nitrogen oxides in an oxygen-rich effluent from the combustion of a carbonaceous fuel, which process comprises injecting a solution comprising at least one additive compound selected from the group consisting of guanidine, guanidine carbonate, biguanide, guanylurea sulfate, melamine, dicyandiamide, biuret, 1,1'-azobisformamide, methylol urea, methylol urea-urea condensation product, dimethylol urea, methyl urea, and dimethyl urea, at a concentration and a temperature effective to achieve reduction in nitrogen oxide levels in the effluent.
Claim 2
Dependent Claim 78 words
A process for reducing the concentration of nitrogen oxides in an oxygen-rich effluent from the combustion of a carbonaceous fuel, which process comprises injecting a solution comprising at least one additive compound selected from the group consisting of guanidine, guanidine carbonate, biguanide, guanylurea sulfate, melamine, dicyandiamide, biuret, 1,1'-azobisformamide, methylol urea, methylol urea-urea condensation product, dimethylol urea, methyl urea, and dimethyl urea, at a concentration and a temperature effective to achieve reduction in nitrogen oxide levels in the effluent.
Claim 3
Dependent Claim 22 words
A process according to claim 1 wherein the temperature of the effluent is greater than 1300° F. at the point of injection.
Claim 4
Dependent Claim 11 words
A process according to claim 1 wherein the solution comprises water.
Claim 5
Dependent Claim 39 words
A process according to claim 1 wherein the solution is injected as a dispersion at a number of points, the droplets within the dispersion being within the range of from about 10 to about 10,000 microns Sauter mean diameter.
Claim 6
Dependent Claim 15 words
A process according to claim 4 wherein the droplets are greater than about 50 microns.
Claim 7
Dependent Claim 24 words
A process according to claim 1 wherein the dispersion is injected into the effluent at a temperature of from 2000° F. to 2500° F.
Claim 8
Dependent Claim 21 words
A process according to claim 6 wherein the solution comprises at least 80% solvent, based on the weight of the solution.
Claim 9
Dependent Claim 21 words
A process according to claim 7 wherein the solution comprises at least 90% solvent, based on the weight of the solution.

References Cited (Backward Citations)

US4719092A Cited
US4751065A Cited
US4770863A Cited
US4777024A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-05-21 1993-11-20 1994-05-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-05-21 1997-11-20 1998-05-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-05-21 2001-11-20 2002-05-22 $7700.00 Window Closed / Lapsed

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