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US4925916A Expired / Lapsed US ⏱️ 0.0 years remaining

Amide and/or imide containing polymers and monomers for the preparation thereof

Assignee: BP Corp North America Inc
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Filing: 1987-11-18
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Granted: 1990-05-15
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Expires: 2007-11-18
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Abstract

Abstract Described herein are amide and/or imide containing polymers based on novel monomers that contain isoalkylidene bridges. These polymers have excellent toughness combined with high temperature stability, low water absorption, and good melt-fabricability.

Inventors

  • 👤 James E. Harris
  • 👤 Abe Berger
  • 👤 Vilas M. Chopdekar
  • 👤 Markus Matzner
  • 👤 James Spanswick

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 16:43
CPC Classifications
C; C08; C08L; C08L79/00; C08L79/04; C08L79/08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1039; C08G73/1042; C08G73/1046; C08G73/1075; C08G73/1078

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 216 words
Polyimides derived from at least one of the following monomers: ##STR54## wherein R' and R" are independently hydrogen, straight chain or branched C 1 to C 10 alkyl and C 6 to C 20 aryl groups; R' and R" are hydrogens; R 3 is a phenyl, a CF 3 or an alkyl group having from 1 to 10 carbon atoms; R 4 and R 5 are independently hydrogen, halogen, alkyl or alkoxy groups having from 1 to 4 carbon atoms, or aryl and aryloxy groups having from 6 to 20 carbon atoms; R 6 is independently hydrogen or an alkyl having more than one carbon atom, an aryl or aryloxy having from 6 to 20 carbon atoms; and Ar is ##STR55## wherein X can be a chemical bond, O, S, SO, SO 2 --, ##STR56## CH 2 , an alkylene or alkylidene having from 2 to 8 carbon atoms, a cycloalkylene or cycloalkylidene having from 5 to 14 carbon atoms, or a phenylene group which may be substituted by an alkyl or alkoxy group having from 2 to 4 carbon atoms, or by a halogen; the group Ar may also be selected from ##STR57## and wherein the subject monomers are used in an amount of at least 50 mole percent based on the total monomers used.
Claim 2
Dependent Claim 216 words
Polyimides derived from at least one of the following monomers: ##STR54## wherein R' and R" are independently hydrogen, straight chain or branched C 1 to C 10 alkyl and C 6 to C 20 aryl groups; R' and R" are hydrogens; R 3 is a phenyl, a CF 3 or an alkyl group having from 1 to 10 carbon atoms; R 4 and R 5 are independently hydrogen, halogen, alkyl or alkoxy groups having from 1 to 4 carbon atoms, or aryl and aryloxy groups having from 6 to 20 carbon atoms; R 6 is independently hydrogen or an alkyl having more than one carbon atom, an aryl or aryloxy having from 6 to 20 carbon atoms; and Ar is ##STR55## wherein X can be a chemical bond, O, S, SO, SO 2 --, ##STR56## CH 2 , an alkylene or alkylidene having from 2 to 8 carbon atoms, a cycloalkylene or cycloalkylidene having from 5 to 14 carbon atoms, or a phenylene group which may be substituted by an alkyl or alkoxy group having from 2 to 4 carbon atoms, or by a halogen; the group Ar may also be selected from ##STR57## and wherein the subject monomers are used in an amount of at least 50 mole percent based on the total monomers used.
Claim 3
Dependent Claim 10 words
Polyimides according to claim 1 wherein R 3 is methyl.
Claim 4
Dependent Claim 34 words
Polyimides according to claim 1 which contain one or more of the following monomers H.sub.2 N.sub.2 Ar'NH.sub.2' where Ar' is a divalent aromatic radical, and ##STR58## where Ar 3 is a tetravalent aromatic radical.
Claim 5
Dependent Claim 18 words
Polyimides according to claim 3 where Ar 3 is ##STR59## where X is as defined in claim 1.
Claim 6
Dependent Claim 13 words
A polyimide according to claim 1 comprising repeating units of the formula ##STR60##
Claim 7
Dependent Claim 9 words
A polyimide comprising repeating units of the formula ##STR61##
Claim 8
Dependent Claim 9 words
A polyimide comprising repeating units of the formula ##STR61##
Claim 9
Dependent Claim 9 words
A polyimide comprising repeating units of the formula ##STR62##
Claim 10
Dependent Claim 9 words
A polyimide comprising repeating units of the formula ##STR62##
Claim 11
Dependent Claim 13 words
A polyimide according to claim 1 comprising repeating units of the formula ##STR63##

References Cited (Backward Citations)

US4255313A Cited
US4681928A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-05-14 1993-11-13 1994-05-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-05-14 1997-11-13 1998-05-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-05-14 2001-11-13 2002-05-15 $7700.00 Window Closed / Lapsed

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