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US4925780A Expired / Lapsed US ⏱️ 0.0 years remaining

Direct positive silver halide light-sensitive color photographic material

Assignee: Konica Minolta Inc
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Filing: 1988-08-18
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Granted: 1990-05-15
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Expires: 2008-08-18
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Abstract

Abstract A direct positive silver halide light-sensitive color photographic material comprising, on a support, (1) at least three light-sensitive silver halide emulsion layers containing internal latent image-type light-sensitive silver halide grains, (2) specific sensitizing dyes having formulas [I], [II] and [III], respectively defined in the specification, and (3) at least one anti-irradiation compound selected from the group consisting of those compounds having formulas [IV], [V] and [VI], respectively defined in the specification, is disclosed.

Inventors

  • 👤 Tomimi Yoshizawa
  • 👤 Keiji Ogi
  • 👤 Atushi Kamitakahara

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 21:50
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/28; G03C1/29; G03C1/485; G03C1/48538; G03C7/00; G03C7/30; G03C7/3003; G03C1/10; G03C1/12

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 620 words
A direct positive silver halide light-sensitive color photographic material which comprises at least three light-sensitive silver halide emulsion layers containing internal latent image-type light-sensitive silver halide grains and sensitizing dyes having the following Formulas [I], [II] and [III], respectively, and at least one compound selected from the group consisting of those compounds having the following Formulas [IV], [V] and [VI]; Formula [I] ##STR24## wherein Z 1 and Z 2 each is a group of atoms necessary to form a benzothiazole ring, naphthothiazole ring, benzoselenazole ring or naphthoselenazole ring: R 1 and R 2 each is a substituted or unsubstituted alkyl group, provided that at least one of the R 1 and R 2 is a sulfo or carboxyl group-substituted alkyl group; X 1 - is an anion; and l is an integer of 1 or 2; Formula [II] ##STR25## wherein Z 3 and Z 4 each is a group of atoms necessary to form a benzoxazole ring or naphthoxazole ring: R 3 and R 4 each is a substituted or unsubstituted alkyl group, and R 5 is an lower alkyl group, provided that at least one of the R 3 and R 4 is a sulfo or carboxyl group-substituted alkyl group; X 2 - is an anion; and m is an integer of 1 or 2; Formula [III] ##STR26## wherein Z 5 and Z 6 each is a group of atoms necessary to form a benzothiazole ring, naphthothiazole ring, benzoselenazole ring or naphthoselenazole ring: R 6 and R 7 each is a substituted or unsubstituted alkyl group, and R 8 is an alkyl or aryl group, provided that at least one of the R 6 and R 7 is a sulfo or carboxyl group-substituted alkyl group; X 3 - is an anion; and n is an integer of 1 or 2; Formula [IV] ##STR27## wherein Y is an oxygen atom, ═NR 2 , ═C(CH 3 ) or a sulfur atom; Q 1 is a group of atoms necessary to form a pyrazolone ring, isooxazolone ring, barbituric acid ring, thiobarbituric acid ring, tetrahydropyridine-2,6-dione ring or pyrazolo[3,4-b]pyridine-3,6-dione ring: R 1 and R 2 each is an alkyl group; M is a hydrogen atom or a cation; L 1 , L 2 , L 3 , L 4 , L 5 and L 6 each is a methine group: l' is an integer of 1 or 2; and m 1 , m 2 and m 3 each is zero or 1; Formula [V] ##STR28## wherein Q 2 and Q 3 each is a group of atoms necessary to form an isooxazolone ring, barbituric acid ring, thiobarbituric acid ring, tetrahydropyridine-2,6-dione ring, pyrazolo[3,4-b]pyridine-3,6-dione ring or ##STR29## or a tautomer of each of these keto rings; R 3 is an aryl group; R 4 is a carbamoyl group, alkoxycarbonyl group, aryloxycarbonyl group, perfluoroalkyl group or cyano group; provided that at least one of the Q 2 and Q 3 has a sulfo or carboxyl group-substituted alkyl, aryl or heterocyclic group; L 7 , L 8 , L 9 , L 10 and L 11 each is a methine group; and n 1 and n 2 each is an integer of zero or 1; Formula [VI] ##STR30## wherein Q 4 is a group of atoms necessary to form an isooxazolone ring, barbituric acid ring, thiobarbituric acid ring, pyrazolo[3,4-b]pyridine-3,6-dione ring or ##STR31## R 7 and R 8 represent the same groups as defined in the R 3 and R 4 , respectively, of Formula [V]; R 5 is an alkoxy group or amino group: R 6 is a hydrogen atom, halogen atom, alkyl or alkoxy group; L 12 , L 13 and L 14 each is a methine group; and q is an integer of zero or 1.
Claim 2
Dependent Claim 620 words
A direct positive silver halide light-sensitive color photographic material which comprises at least three light-sensitive silver halide emulsion layers containing internal latent image-type light-sensitive silver halide grains and sensitizing dyes having the following Formulas [I], [II] and [III], respectively, and at least one compound selected from the group consisting of those compounds having the following Formulas [IV], [V] and [VI]; Formula [I] ##STR24## wherein Z 1 and Z 2 each is a group of atoms necessary to form a benzothiazole ring, naphthothiazole ring, benzoselenazole ring or naphthoselenazole ring: R 1 and R 2 each is a substituted or unsubstituted alkyl group, provided that at least one of the R 1 and R 2 is a sulfo or carboxyl group-substituted alkyl group; X 1 - is an anion; and l is an integer of 1 or 2; Formula [II] ##STR25## wherein Z 3 and Z 4 each is a group of atoms necessary to form a benzoxazole ring or naphthoxazole ring: R 3 and R 4 each is a substituted or unsubstituted alkyl group, and R 5 is an lower alkyl group, provided that at least one of the R 3 and R 4 is a sulfo or carboxyl group-substituted alkyl group; X 2 - is an anion; and m is an integer of 1 or 2; Formula [III] ##STR26## wherein Z 5 and Z 6 each is a group of atoms necessary to form a benzothiazole ring, naphthothiazole ring, benzoselenazole ring or naphthoselenazole ring: R 6 and R 7 each is a substituted or unsubstituted alkyl group, and R 8 is an alkyl or aryl group, provided that at least one of the R 6 and R 7 is a sulfo or carboxyl group-substituted alkyl group; X 3 - is an anion; and n is an integer of 1 or 2; Formula [IV] ##STR27## wherein Y is an oxygen atom, ═NR 2 , ═C(CH 3 ) or a sulfur atom; Q 1 is a group of atoms necessary to form a pyrazolone ring, isooxazolone ring, barbituric acid ring, thiobarbituric acid ring, tetrahydropyridine-2,6-dione ring or pyrazolo[3,4-b]pyridine-3,6-dione ring: R 1 and R 2 each is an alkyl group; M is a hydrogen atom or a cation; L 1 , L 2 , L 3 , L 4 , L 5 and L 6 each is a methine group: l' is an integer of 1 or 2; and m 1 , m 2 and m 3 each is zero or 1; Formula [V] ##STR28## wherein Q 2 and Q 3 each is a group of atoms necessary to form an isooxazolone ring, barbituric acid ring, thiobarbituric acid ring, tetrahydropyridine-2,6-dione ring, pyrazolo[3,4-b]pyridine-3,6-dione ring or ##STR29## or a tautomer of each of these keto rings; R 3 is an aryl group; R 4 is a carbamoyl group, alkoxycarbonyl group, aryloxycarbonyl group, perfluoroalkyl group or cyano group; provided that at least one of the Q 2 and Q 3 has a sulfo or carboxyl group-substituted alkyl, aryl or heterocyclic group; L 7 , L 8 , L 9 , L 10 and L 11 each is a methine group; and n 1 and n 2 each is an integer of zero or 1; Formula [VI] ##STR30## wherein Q 4 is a group of atoms necessary to form an isooxazolone ring, barbituric acid ring, thiobarbituric acid ring, pyrazolo[3,4-b]pyridine-3,6-dione ring or ##STR31## R 7 and R 8 represent the same groups as defined in the R 3 and R 4 , respectively, of Formula [V]; R 5 is an alkoxy group or amino group: R 6 is a hydrogen atom, halogen atom, alkyl or alkoxy group; L 12 , L 13 and L 14 each is a methine group; and q is an integer of zero or 1.
Claim 3
Dependent Claim 33 words
The direct positive silver halide light-sensitive color photographic material of claim 1, wherein Z 1 and Z 2 in formula [I] respectively represent a group of atoms necessary to complete a benzothiazole ring.
Claim 4
Dependent Claim 81 words
The direct positive silver halide light-sensitive color photographic material of claim 1, wherein at least one of R 1 and R 2 in formula [I], at least one of R 3 and R 4 in formula [II], and at least one of R 6 and R 7 in formula [III] respectively represent an alkyl group of which one hydrogen atom has been substituted by a sulfo group or a carboxyl group, said alkyl group having not more than five carbon atoms.
Claim 5
Dependent Claim 29 words
The direct positive silver halide light-sensitive color photographic material of claim 1, wherein R 5 in formula [II] is an alkyl group having not more than 4 carbon atoms.
Claim 6
Dependent Claim 49 words
The direct positive silver halide light-sensitive color photographic material of claim 1, wherein the sensitizing dye of Formula [I] is incorporated in a blue-sensitive emulsion layer, the sensitizing dye of Formula [II] in a green-sensitive emulsion layer, and the sensitizing dye of Formula [III] in a red-sensitive emulsion layer.
Claim 7
Dependent Claim 36 words
The direct positive silver halide light-sensitive color photographic material of claim 1, wherein the compounds represented by the formulas [IV], [V] and/or [VI] are incorporated into at least one of the light-sensitive silver halide emulsion layer.
Claim 8
Dependent Claim 61 words
The direct positive silver halide light-sensitive color photographic material of claim 1, wherein the compound is selected from ones having a spectral absorption in the region of 500 nm to 600 nm and incorporated in a green-sensitive emulsion layer or ones having spectral absorption in the region of 500 nm to 600 nm and is incorporated in a red-sensitive emulsion layer.

References Cited (Backward Citations)

US4147547A Cited
US4102688A Cited
US4444874A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-05-14 1993-11-13 1994-05-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-05-14 1997-11-13 1998-05-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-05-14 2001-11-13 2002-05-15 $7700.00 Window Closed / Lapsed

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