Electrophotographic sensitive material with pyrrolopyrrole and benzidine derivatives

Claim 2

An electrophotographic sensitive material having a photosensitive layer formed on an electroconductive substrate, and said photosensitive layer contains a pyrrolopyrrole type compound represented by the following general formula (1) and a benzidine derivative represented by the following general formula (2) ##STR7## (wherein R 1 and R 2 are same or different, selected from the group consisting of aryl group, aryl group which contains a substituent, aralkyl group, aralkyl group which contains a substituent and heterocyclic group, and R 3 and R 4 are same or different, selected from the group consisting of hydrogen atom, alkyl group, aryl group and aryl group which contains a substituent) ##STR8## (wherein R 5 , R 6 , R 7 , R 8 ,R 9 , and R 10 are same or different, selected from the group consisting of hydrogen atom, lower alkyl group, lower alkoxy group and halogen atom, l, m, n and o are integers in the range of 1 to 3, and p and q are 1 or 2).

Claim 3

An electrophotographic sensitive material according to claim 1, wherein said photosensitive layer is a single type photosensitive layer which contains said pyrrolopyrrole type compound and said benzidine derivative.

Claim 4

An electrophotographic sensitive material according to claim 1, wherein said photosensitive layer is a laminate type photosensitive layer superposing an electric charge generating layer which contains said pyrrolopyrrole type compound upon an electric charge transferring layer which contains said benzidine derivative.

Claim 5

An electrophotographic sensitive material according to claim 1, wherein said R 1 and R 2 are aryl group or aralkyl group containing a substituent which is selected from the group consisting of halogen atom, lower alkyl group containing halogen atom, cyano group, alkyl group, alkoxy group and dialkylamino group.

Claim 6

An electrophotographic sensitive material according to claim 1, wherein said R 3 and R 4 are hydrogen atom, alkyl group of 1 to 4 carbon atoms or phenyl group which has a substituent selected from the group consisting of halogen atom, lower alkyl group containing halogen atom, alkyl group, alkoxy group, alkylthio group and nitro group.

Claim 7

An electrophotographic sensitive material according to claim 1, wherein R 5 , R 6 , R 7 , R 8 , R 9 and R 10 are same or different, selected from the group consisting of hydrogen atom, alkyl group of 1 to 4 carbon atoms, alkoxy group of 1 to 4 carbon atoms and halogen atom.

Claim 8

An electrophotographic sensitive material according to claim 1, wherein R 1 and R 2 are each a phenyl group, and R 3 and R 4 are each a hydrogen atom.

Claim 9

An electrophotographic sensitive material according to claim 1, wherein R 5 , R 7 , R 9 and R 10 are each a hydrogen atom, and ##STR9## are each a 2,4-dimethylphenyl group.

Claim 10

An electrophotographic sensitive material according to claim 1, wherein R 1 and R 2 are each a phenyl group, R 3 and R 4 are each a hydrogen atom, R 5 , R 7 , R 9 and R 10 are each a hydrogen atom, and ##STR10## are each a 2,4-dimethylphenyl group.

Claim 11

An electrophotographic sensitive material according to claim 2, wherein the pyrrolopyrrole type compound is in the range of 2 to 20 parts by weight and the benzidine derivative is in the range of 40 to 200 parts by weight based on 100 parts by weight of binder.

Claim 12

An electrophotographic sensitive material according to claim 3, wherein the electric charge generating layer of the laminate contains 5 to 500 parts pyrrolopyrrole type compound in a binder based on 100 parts by weight of binder, and the electric charge transferring layer contains 10 to 500 parts by weight benzidine derivative in a binder, based on 100 parts by weight of binder.

Claim 13

An electrophotographic sensitive material having a photosensitive layer formed on an electroconductive substrate, and said photosensitive layer contains a pyrrolopyrrole type compound represented by the following formula (1) and a benzidine derivative represented by the following general formula (2) ##STR11## wherein R 1 and R 2 are same or different, selected from the group consisting of aryl group, aryl group which contains a substituent, aralkyl group, aralkyl group which contains a substituent and heterocyclic group, and R 3 and R 4 are same or alkyl group, aryl group and aryl group which contains a substituent ##STR12## wherein R 5 , R 6 , R 7 , R 8 , R 9 and R 10 are same or different, selected from the group consisting of hydrogen atom, lower alkyl group, lower alkoxy group and halogen atom, l, m, n and o are integers in the range of 1 to 3, and p and q are 1 or 2, wherein said photosensitive layer is a member selected from the group consisting of a single type photosensitive layer which contains said pyrrolopyrrole type compound and said benzidine derivative and a laminate type photosensitive layer superposing an electric charge generating layer which contains said pyrrolopyrrole type compound upon an electric charge transferring layer which contains said benzidine derivative, and in the single type photosensitive layer the pyrrolopyrrole type compound is in the range of 2 to 20 parts by weight and the benzidine derivative is in the range of 40 to 200 parts by weight based on 100 parts by weight of binder, and wherein the electric charge generating layer of the laminate contains 5 to 500 parts pyrrolopyrrole type compound in a binder based on 100 parts by weight of binder, and the electric charge transferring layer contains 10 to 500 parts by weight benzidine derivative in a binder, based on 100 parts by weight of binder.

Claim 14

An electrophotographic sensitive material having a photosensitive layer formed on an electroconductive substrate, and said photosensitive layer contains a pyrrolopyrrole type compound represented by the following formula (1) and a benzidine derivative represented by the following general formula (2) ##STR11## wherein R 1 and R 2 are same or different, selected from the group consisting of aryl group, aryl group which contains a substituent, aralkyl group, aralkyl group which contains a substituent and heterocyclic group, and R 3 and R 4 are same or alkyl group, aryl group and aryl group which contains a substituent ##STR12## wherein R 5 , R 6 , R 7 , R 8 , R 9 and R 10 are same or different, selected from the group consisting of hydrogen atom, lower alkyl group, lower alkoxy group and halogen atom, l, m, n and o are integers in the range of 1 to 3, and p and q are 1 or 2, wherein said photosensitive layer is a member selected from the group consisting of a single type photosensitive layer which contains said pyrrolopyrrole type compound and said benzidine derivative and a laminate type photosensitive layer superposing an electric charge generating layer which contains said pyrrolopyrrole type compound upon an electric charge transferring layer which contains said benzidine derivative, and in the single type photosensitive layer the pyrrolopyrrole type compound is in the range of 2 to 20 parts by weight and the benzidine derivative is in the range of 40 to 200 parts by weight based on 100 parts by weight of binder, and wherein the electric charge generating layer of the laminate contains 5 to 500 parts pyrrolopyrrole type compound in a binder based on 100 parts by weight of binder, and the electric charge transferring layer contains 10 to 500 parts by weight benzidine derivative in a binder, based on 100 parts by weight of binder.