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US4918138A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing a colored molded article of metathesis polymerized polymer

Assignee: Metton America Inc
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Filing: 1989-02-15
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Granted: 1990-04-17
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Expires: 2009-02-15
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Abstract

Abstract A process for producing a colored cross-linked molded article by metathesis polymerizing in a mold a mixture comprising metathesis polymerizable monomers such as dicyclopentadiene and a metathesis polymerizable multi-part composition therefor.

Inventors

  • 👤 Shigeyoshi Hara
  • 👤 Zen-ichiro Endo
  • 👤 Umewaka Nakatani

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 23:31
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/01; B; B29; B29C; B29C67/00; B29C67/24; B29C67/246; C08G; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 202 words
A process for producing a molded article comprising the steps of: preparing a first reactive solution containing at least one metathesis polymerizable cycloolefin and a catalyst component of a metathesis polymerization catalyst system comprising a halide of tungsten, molybdenum, rhenium or tantalum; preparing a second reactive solution containing at least one metathesis polymerizable cycloolefin ana an activator component for said metathesis polymerization catalyst system, wherein said activator component is selected from the group consisting of tetraalkyl tins, trialkyl tin hydrides, alkylaluminum compounds and alkylaluminum halide compounds; adding at least one pigment selected from the group consisting of (a) a carbon black prepared by the incomplete combustion process, (b) a titanium oxide, (c) an iron oxide, and (d) a cobalt oxide to said second reactive solution; adding, subsequent to the addition of said pigment, a supplementary amount of said activator component to said second reactive solution to compensate for said activator component consumed when said pigment is added to said second reactive solution; combining a plurality of reactive solutions comprising at least said first reactive solution and said second reactive solution; and introducing said combined reactive solutions into a mold and metathesis polymerizing in bulk in said mold to produce said molded article.
Claim 2
Dependent Claim 202 words
A process for producing a molded article comprising the steps of: preparing a first reactive solution containing at least one metathesis polymerizable cycloolefin and a catalyst component of a metathesis polymerization catalyst system comprising a halide of tungsten, molybdenum, rhenium or tantalum; preparing a second reactive solution containing at least one metathesis polymerizable cycloolefin ana an activator component for said metathesis polymerization catalyst system, wherein said activator component is selected from the group consisting of tetraalkyl tins, trialkyl tin hydrides, alkylaluminum compounds and alkylaluminum halide compounds; adding at least one pigment selected from the group consisting of (a) a carbon black prepared by the incomplete combustion process, (b) a titanium oxide, (c) an iron oxide, and (d) a cobalt oxide to said second reactive solution; adding, subsequent to the addition of said pigment, a supplementary amount of said activator component to said second reactive solution to compensate for said activator component consumed when said pigment is added to said second reactive solution; combining a plurality of reactive solutions comprising at least said first reactive solution and said second reactive solution; and introducing said combined reactive solutions into a mold and metathesis polymerizing in bulk in said mold to produce said molded article.
Claim 3
Dependent Claim 40 words
A process according to claim 1, where said at least one pigment is incorporated into said second reactive solution containing the activator component in the amount of 0.05-20 weight % based on the total weight of said combined reactive solutions.
Claim 4
Dependent Claim 25 words
A process according to claim 1, where said carbon black prepared by the incomplete combustion process is an oil furnace carbon black or lamp black.
Claim 5
Dependent Claim 28 words
A process according to claim 1, where said titanium oxide is white titanium oxide, black nitrogen-doped titanium monooxide, or titanium yellow TiO 2 --NiOSb 2 O 3 .
Claim 6
Dependent Claim 29 words
A process according to claim 1, where said iron oxide is black iron oxide Fe 3 O 4 , red iron oxide Fe 2 O 3 , or ochre.
Claim 7
Dependent Claim 13 words
A process according to claim 1, where said cobalt oxide is cobalt blue.
Claim 8
Dependent Claim 17 words
A process according to claim 1, where said at least one metathesis polymerizable cycloolefin is predominantly dicyclopentadiene.
Claim 9
Dependent Claim 24 words
A process according to claim 1, where said at least one metathesis polymerizable cycloolefin is a mixture of dicyclopentadiene and other metathesis polymerizable monomers.

References Cited (Backward Citations)

US4400340A Cited
US4598102A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-04-16 1993-10-16 1994-04-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-04-16 1997-10-16 1998-04-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-04-16 2001-10-16 2002-04-17 $7700.00 Window Closed / Lapsed

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