US4918133A
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Cycloolefin type random copolymer compositions
Assignee: Mitsui Chemicals Inc
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Filing: 1988-10-07
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Granted: 1990-04-17
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Expires: 2008-10-07
Abstract
Abstract PCT No. PCT/JP88/01027 Sec. 371 Date Jun. 7, 1989 Sec. 102(e) Date Jun. 7, 1989 PCT Filed Oct. 7, 1988 PCT Pub. No. WO89/03413 PCT Pub. Date Apr. 20, 1989.In accordance with the present invention, there are provided cycloolefin type random copolymer compositions excellent in heat resistance, chemical resistance, rigidity, impact resistance, etc., which comprise (A) a cycloolefin type random copolymer containing an ethylene component and a cycloolefin component and having an intrinsic viscosity [ eta ] of 0.05-10 dl/g as measured at 135 DEG C. in decalin and a softening temperature (TMA) of not lower than 70 DEG C., and (B) one or more non-rigid copolymers selected from the group consisting of: (i) a cycloolefin type random copolymer containing an ethylene component, at least one other alpha -olefin component and a cycloolefin component and having an intrinsic viscosity [ eta ] of 0.01-10 dl/g as measured at 135 DEG C. in decalin and a softening temperature (TMA) of below 70 DEG C., (ii) a non-crystalline to low crystalline alpha -olefin type elastomeric copolymer formed from at least two alpha -olefins, (iii) an alpha -olefin-diene type elastomeric copolymer formed from at least two alpha -olefins and at least one non-conjugated diene, and (iv) an aromatic vinyl type hydrocarbon-conjugated diene copolymer or a hydrogenated product thereof, and optionally (c) an inorganic filler or organic filler.
Inventors
- 👤 Satoru Moriya
- 👤 Akio Ishimoto
- 👤 Yoshinori Akana
- 👤 Yozo Yamamoto
- 👤 Kotaro Kishimura
- 👤 Fumitoshi Ikejiri
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 21:11
CPC Classifications
C; C08; C08L; C08L23/00; C08L23/02; C08L23/16; C08K; C08K5/00; C08K5/04; C08K5/10; C08L23/04; C08L23/08; C08L23/0807; C08L23/0823; C08L45/00; C08L65/00; C08L2205/00; C08L2205/02; C08L2205/025; C08L2312/00
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
238 words
A cycloolefin type random copolymer composition characterized by comprising (A) a cycloolefin type random copolymer containing an ethylene component and a cycloolefin component represented by the following general formula [I] or [II] and having an intrinsic viscosity [η] of 0.05-10 dl/g as measured at 135° C. in decalin and a softening temperature (TMA) of not lower than 70° C., and (B) one or more non-rigid copolymers selected from the group consisting of: (i) a cycloolefin type random copolymer containing an ethylene component, at least one other α-olefin component and a cycloolefin component represented by the following general formula [I] or [II] and having an intrinsic viscosity [η] of 0.01-10 dl/g as measured at 135° C. in decalin and a softening temperature (TMA) of below 70° C., (ii) a non-crystalline to low crystalline α-olefin type elastomeric copolymer formed from at least two α-olefins, (iii) an α-olefin-diene type elastomeric copolymer formed from at least two α-olefins and at least one non-conjugated diene, and (iv) an aromatic vinyl type hydrocarbon-conjugated diene copolymer or a hydrogenated product thereof, in such a proportion that the total amount of the component (B) is 5 to 100 parts by weight based on 100 parts by weight of the component (A). ##STR108## wherein n and m are each 0 or a positive integer, l is an integer of at least 3, and R 1 to R 10 each represents hydrogen atom, halogen atom or hydrocarbon group.
Claim 2
Dependent Claim
238 words
A cycloolefin type random copolymer composition characterized by comprising (A) a cycloolefin type random copolymer containing an ethylene component and a cycloolefin component represented by the following general formula [I] or [II] and having an intrinsic viscosity [η] of 0.05-10 dl/g as measured at 135° C. in decalin and a softening temperature (TMA) of not lower than 70° C., and (B) one or more non-rigid copolymers selected from the group consisting of: (i) a cycloolefin type random copolymer containing an ethylene component, at least one other α-olefin component and a cycloolefin component represented by the following general formula [I] or [II] and having an intrinsic viscosity [η] of 0.01-10 dl/g as measured at 135° C. in decalin and a softening temperature (TMA) of below 70° C., (ii) a non-crystalline to low crystalline α-olefin type elastomeric copolymer formed from at least two α-olefins, (iii) an α-olefin-diene type elastomeric copolymer formed from at least two α-olefins and at least one non-conjugated diene, and (iv) an aromatic vinyl type hydrocarbon-conjugated diene copolymer or a hydrogenated product thereof, in such a proportion that the total amount of the component (B) is 5 to 100 parts by weight based on 100 parts by weight of the component (A). ##STR108## wherein n and m are each 0 or a positive integer, l is an integer of at least 3, and R 1 to R 10 each represents hydrogen atom, halogen atom or hydrocarbon group.
Claim 3
Dependent Claim
88 words
The composition as claimed in claim 1, wherein the cycloolefin type random copolymer containing an ethylene component, at least one other α-olefin component and a cycloolefin component represented by the following formula [I] or [II] is a cycloolefin type random copolymer containing an ethylene component, a propylene component and a cycloolefin component represented by the following general formula [I] or [II], or a cycloolefin type random copolymer containing an ethylene component, a butene component and a cycloolefin component represented by the following general formula [I] or [II]. ##STR109##
Claim 4
Dependent Claim
24 words
The composition as claimed in claim 1, wherein the α-olefin type elastomeric copolymer is ethylene-propylene copolymer rubber, ethylene-butene copolymer rubber or propylene-butene copolymer rubber.
Claim 5
Dependent Claim
19 words
The compositions as claimed in claim 1, wherein the α-olefin-diene type elastomeric copolymer is an ethylene-propylene-diene type elastomeric copolymer.
Claim 6
Dependent Claim
46 words
The composition as claimed in claim 1, wherein the aromatic vinyl type hydrocarbon-conjuated diene copolymer or a hydrogenated product thereof is styrene-butadiene copolymer rubber, styrene-butadiene-styrene block copolymer rubber, styrene-isoprene copolymer rubber, styrene-isoprene-styrene block copolymer rubber, hydrogenated styrene-butadiene-styrene block copolymer rubber or hydrogenated styrene-isoprene-styrene block copolymer rubber.
Claim 7
Dependent Claim
269 words
A cycloolefin type random copolymer composition characterized by comprising (A) a cycloolefin type random copolymer containing an ethylene component and a cycloolefin component represented by the following general formula [I] or [II] and having an intrinsic viscosity [η] of 0.05-10 dl/g as measured at 135° C. in decalin and a softening temperature (TMA) of not lower than 70° C., (B) at least two non-rigid copolymers selected from the group consisting of: (i) a cycloolefin type random copolymer containing an ethylene component, at least one other α-olefin component and a cycloolefin component represented by the following general formula [I] or [II] and having an intrinsic viscosity [η] of 0.01-10 dl/g as measured at 135° C. in decalin and a softening temperature (TMA) of below 70° C., (ii) a non-crystalline to low crystalline α-olefin type elastomeric copolymer formed from at least two α-olefins, (iii) an α-olefin-diene type elastomeric copolymer formed from at least two α-olefins and at least one non-conjugated diene, and (iv) an aromatic vinyl type hydrocarbon-conjugated diene copolymer or a hydrogenated product thereof, and (C) an inorganic filler or organic filler, in such a proportion that the total amount of the component (B) is 1 to 100 parts by weight based on 100 parts by weight of the component (A) and the amount of the component (C) is 1 to 100 parts by weight based on 100 parts by weight of the component (A). ##STR110## wherein n and m are each 0 or a positive integer, l is an integer of at least 3, and R 1 to R 10 each represents hydrogen atom, halogen atom or hydrocarbon group.
Claim 8
Dependent Claim
269 words
A cycloolefin type random copolymer composition characterized by comprising (A) a cycloolefin type random copolymer containing an ethylene component and a cycloolefin component represented by the following general formula [I] or [II] and having an intrinsic viscosity [η] of 0.05-10 dl/g as measured at 135° C. in decalin and a softening temperature (TMA) of not lower than 70° C., (B) at least two non-rigid copolymers selected from the group consisting of: (i) a cycloolefin type random copolymer containing an ethylene component, at least one other α-olefin component and a cycloolefin component represented by the following general formula [I] or [II] and having an intrinsic viscosity [η] of 0.01-10 dl/g as measured at 135° C. in decalin and a softening temperature (TMA) of below 70° C., (ii) a non-crystalline to low crystalline α-olefin type elastomeric copolymer formed from at least two α-olefins, (iii) an α-olefin-diene type elastomeric copolymer formed from at least two α-olefins and at least one non-conjugated diene, and (iv) an aromatic vinyl type hydrocarbon-conjugated diene copolymer or a hydrogenated product thereof, and (C) an inorganic filler or organic filler, in such a proportion that the total amount of the component (B) is 1 to 100 parts by weight based on 100 parts by weight of the component (A) and the amount of the component (C) is 1 to 100 parts by weight based on 100 parts by weight of the component (A). ##STR110## wherein n and m are each 0 or a positive integer, l is an integer of at least 3, and R 1 to R 10 each represents hydrogen atom, halogen atom or hydrocarbon group.
Claim 9
Dependent Claim
89 words
The composition as claimed in claim 6, wherein the cycloolefin type random copolymer containing an ethylene component, at least one other α-olefin component and a cycloolefin component represented by the following general formula [I] or [II] is a cycloolefin type random copolymer containing an ethylene component, a propylene component and a cycloolefin component represented by the following general formula [I] or [II], or a cycloolefin type random copolymer containing an ethylene component, a butene component and a cycloolefin component represented by the following general formula [I] or [II]. ##STR111##
Claim 10
Dependent Claim
24 words
The composition as claimed in claim 6, wherein the α-olefin type elastomeric copolymer is ethylene-propylene copolymer rubber, ethylene-butene copolymer rubber or propylene-butene copolymer rubber.
Claim 11
Dependent Claim
19 words
The composition as claimed in claim 6, wherein the α-olefin-diene type elastomeric copolymer is an ethylenepropylene-diene type elastomeric copolymer.
Claim 12
Dependent Claim
47 words
The composition as claimed in claim 6, wherein the aromatic vinyl type hydrocarbon-conjugated diene copolymer or a hydrogenated product thereof is styrene-butadiene copolymer rubber, styrene-butadiene-styrene block copolymer rubber, styrene-isoprene block copolymer rubber, styrene-isoprene-styrene block copolymer rubber, hydrogenated styrene-butadiene-styrene block copolymer rubber or hydrogenated styrene-isoprene-styrene block copolymer rubber.
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| 3.5 Years (Year 4) | 1993-04-16 | 1993-10-16 | 1994-04-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-04-16 | 1997-10-16 | 1998-04-17 | $3760.00 | Window Closed / Lapsed |
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