US4916216A
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Process for granulating azobisamidine salts using an aqueous binder
Assignee: Fujifilm Wako Pure Chemical Corp
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Filing: 1987-05-11
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Granted: 1990-04-10
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Expires: 2007-05-11
Abstract
Abstract Granules of azobisamidine salt can be produced by granulating a powder of azobisamidine salt using a limited amount of water or a mixture of water and a water-soluble organic solvent such as methanol are convenient in handling without deteriorating the quality and can be used as a water-soluble polymerization initiator.
Inventors
- 👤 Motoaki Tanaka
- 👤 Takanori Toyama
- 👤 Hiroki Sugioka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 11:17
CPC Classifications
C; C08; C08F; C08F4/00; C08F4/04
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
236 words
A process for producing granules of an azobisamidine salt of the formula: ##STR5## wherein R 1 and R 2 are independently selected from the group consisting of C 1-6 alkyl, C 3-6 cycloalkyl and an aliphatic ring wherein R 1 and R 2 , together with the carbon to which they are attached, are bonded together to form a ring containing 4 to 8 carbon atoms; G is a guanyl group of the formula ##STR6## wherein R 3 and R 4 are independently selected from the group consisting of hydrogen, C 1-10 alkyl, C 1-10 alkyl substituted with a substituent selected from the group consisting of hydroxy, chloro, bromo, and phenyl, C 3-6 cycloalkyl, allyl, phenyl, phenyl substituted with a substituent selected from the group consisting of methyl, ethyl, methoxy, ethoxy, hydroxy, nitro, amino, acetyl and acetylamino; R 5 is a lower alkylene or lower alkylene having one or more substituents selected from the group consisting of C 1-4 alkyl and hydroxy; R 6 is hydrogen or a hydroxyalkyl; and X is selected from the group consisting of Cl, Br and CH 3 COO--, which comprises granulating a powder of azobisamidine salt using a mixture of water and a water-soluble organic solvent as a binder, wherein the mixture of water and a water-soluble organic solvent is adjusted to make the amount of water 5 to 18% by weight, based on the weight of the azobisamidine salt.
Claim 2
Dependent Claim
236 words
A process for producing granules of an azobisamidine salt of the formula: ##STR5## wherein R 1 and R 2 are independently selected from the group consisting of C 1-6 alkyl, C 3-6 cycloalkyl and an aliphatic ring wherein R 1 and R 2 , together with the carbon to which they are attached, are bonded together to form a ring containing 4 to 8 carbon atoms; G is a guanyl group of the formula ##STR6## wherein R 3 and R 4 are independently selected from the group consisting of hydrogen, C 1-10 alkyl, C 1-10 alkyl substituted with a substituent selected from the group consisting of hydroxy, chloro, bromo, and phenyl, C 3-6 cycloalkyl, allyl, phenyl, phenyl substituted with a substituent selected from the group consisting of methyl, ethyl, methoxy, ethoxy, hydroxy, nitro, amino, acetyl and acetylamino; R 5 is a lower alkylene or lower alkylene having one or more substituents selected from the group consisting of C 1-4 alkyl and hydroxy; R 6 is hydrogen or a hydroxyalkyl; and X is selected from the group consisting of Cl, Br and CH 3 COO--, which comprises granulating a powder of azobisamidine salt using a mixture of water and a water-soluble organic solvent as a binder, wherein the mixture of water and a water-soluble organic solvent is adjusted to make the amount of water 5 to 18% by weight, based on the weight of the azobisamidine salt.
Claim 3
Dependent Claim
29 words
A process according to claim 1, wherein the water-soluble organic solvent is used in an amount of 1.5 parts by weight or less per part by weight of water.
Claim 4
Dependent Claim
13 words
A process according to claim 2, wherein the water-soluble organic solvent is methanol.
Claim 5
Dependent Claim
219 words
A process for producing granules of an azobisamidine salt of the formula: ##STR7## wherein R 1 and R 2 are independently selected from the group consisting of C 1-6 alkyl, C 3-6 cycloalkyl and an aliphatic ring wherein R 1 and R 2 together with the carbon to which they are attached are bonded together to form a ring containing 4 to 8 carbon atoms; G is a guanyl group of the formula: ##STR8## wherein R 3 and R 4 are independently selected from the group consisting of hydrogen, C 1-10 alkyl, C 1-10 alkyl substituted with a substituent selected from the group consisting of hydroxy, chloro, bromo, and phenyl, C 3-6 cycloalkyl, allyl, phenyl, phenyl substituted with a substituent selected from the group consisting of methyl, ethyl, methoxy, ethoxy, hydroxy, nitro, amino, acetyl and acetylamino; R 5 is a lower alkylene group or lower alkylene having one or more substituents selected from the group consisting of C 1-4 alkyl and hydroxy; R 6 is hydrogen or a hydroxyalkyl; and X is selected from the group consisting of Cl, Br and CH 3 COO--, which comprises granulating a powder of azobisamidine salt using water as a binder, wherein the water is used in the amount of 10 to 22% by weight, based on the weight of the azobisamidine salt.
Claim 6
Dependent Claim
219 words
A process for producing granules of an azobisamidine salt of the formula: ##STR7## wherein R 1 and R 2 are independently selected from the group consisting of C 1-6 alkyl, C 3-6 cycloalkyl and an aliphatic ring wherein R 1 and R 2 together with the carbon to which they are attached are bonded together to form a ring containing 4 to 8 carbon atoms; G is a guanyl group of the formula: ##STR8## wherein R 3 and R 4 are independently selected from the group consisting of hydrogen, C 1-10 alkyl, C 1-10 alkyl substituted with a substituent selected from the group consisting of hydroxy, chloro, bromo, and phenyl, C 3-6 cycloalkyl, allyl, phenyl, phenyl substituted with a substituent selected from the group consisting of methyl, ethyl, methoxy, ethoxy, hydroxy, nitro, amino, acetyl and acetylamino; R 5 is a lower alkylene group or lower alkylene having one or more substituents selected from the group consisting of C 1-4 alkyl and hydroxy; R 6 is hydrogen or a hydroxyalkyl; and X is selected from the group consisting of Cl, Br and CH 3 COO--, which comprises granulating a powder of azobisamidine salt using water as a binder, wherein the water is used in the amount of 10 to 22% by weight, based on the weight of the azobisamidine salt.
References Cited (Backward Citations)
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