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US4912161A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic moulding compounds of great toughness and good processability in the molten state

Assignee: Bayer AG
•
Filing: 1989-03-06
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Granted: 1990-03-27
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Expires: 2009-03-06
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Abstract

Abstract Thermoplastic moulding compounds containing (A) from 5-90 parts by weight of one or more thermoplastic polymers, (B) from 5-90 parts by weight of one or more graft polymers and (C) from 0.25-40 parts by weight of a blocked copolymer corresponding to the idealized formula (I) A - B - A; B - A - B or (A - B).sub.x (I) wherein A denotes the residue of a homopolymer, e.g. of styrene, and B denotes the residue of a homopolymer of a cyclic carbonate or lactone.

Inventors

  • 👤 Herbert Eichenauer
  • 👤 Edgar Leitz
  • 👤 Karl-Heinz Ott
  • 👤 Alfred Pischtschan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 13:54
CPC Classifications
C; C08; C08L; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08L25/12; C08L51/00; C08L51/04; C08L87/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 229 words
Thermoplastic moulding compositions comprising (A) from 5-90 parts by weight of one or more thermoplastic polymers of styrene, α-methylstyrene, styrene substituted in the nucleus, methyl methacrylate, acrylonitrile, methacrylonitrile, maleic acid anhydride, N-substituted maleimide, vinyl acetate, and mixtures thereof (B) from 5-90 parts by weight of one or more graft polymers of (B1) from 5-90 parts by weight of styrene, α-methylstyrene, styrene substituted in the nucleus, methylmethacrylate, acrylonitrile, methacrylonitrile, maleic acid anhydride, N-substituted maleimide, vinyl acetate or mixtures thereof on (B2) from 95-10 parts by weight of a rubber having a glass temperature ≧10° C. and (C) from 0.25-40 parts by weight of a block copolymer corresponding to the idealized formula (I) A-B-A; B-A-B or (A-B).sub.x (I) wherein x=1 to 40 and A denotes the residue of a homopolymer of styrene, vinyl naphthalene, butadiene or isoprene, and B denotes the residue of a homopolymer of a cyclic carbonate or lactone corresponding to the general formulae (II) to (IV): ##STR13## wherein R 1 , R 2 , R 3 and R 4 =H, C 1 -C 6 -alkyl, C 3 -C 6 -alkenyl, C 1 -C 6 -alkoxy or C 1 -C 6 -alkenoxy-C 1 -C 6 -alkyl, and m and n denote, independently of one another, 0, 1, 2, 3, 4, 5 or 6, ##STR14## wherein ##STR15## wherein ##STR16## the average molecular weights of blocks A and B being ≧800.
Claim 2
Dependent Claim 229 words
Thermoplastic moulding compositions comprising (A) from 5-90 parts by weight of one or more thermoplastic polymers of styrene, α-methylstyrene, styrene substituted in the nucleus, methyl methacrylate, acrylonitrile, methacrylonitrile, maleic acid anhydride, N-substituted maleimide, vinyl acetate, and mixtures thereof (B) from 5-90 parts by weight of one or more graft polymers of (B1) from 5-90 parts by weight of styrene, α-methylstyrene, styrene substituted in the nucleus, methylmethacrylate, acrylonitrile, methacrylonitrile, maleic acid anhydride, N-substituted maleimide, vinyl acetate or mixtures thereof on (B2) from 95-10 parts by weight of a rubber having a glass temperature ≧10° C. and (C) from 0.25-40 parts by weight of a block copolymer corresponding to the idealized formula (I) A-B-A; B-A-B or (A-B).sub.x (I) wherein x=1 to 40 and A denotes the residue of a homopolymer of styrene, vinyl naphthalene, butadiene or isoprene, and B denotes the residue of a homopolymer of a cyclic carbonate or lactone corresponding to the general formulae (II) to (IV): ##STR13## wherein R 1 , R 2 , R 3 and R 4 =H, C 1 -C 6 -alkyl, C 3 -C 6 -alkenyl, C 1 -C 6 -alkoxy or C 1 -C 6 -alkenoxy-C 1 -C 6 -alkyl, and m and n denote, independently of one another, 0, 1, 2, 3, 4, 5 or 6, ##STR14## wherein ##STR15## wherein ##STR16## the average molecular weights of blocks A and B being ≧800.
Claim 3
Dependent Claim 33 words
Moulding compositions according to claim 1, containing in addition to components (A)+(B)+(C), from 1 to 40 parts by weight (based on 100 parts by weight of (A)+(B)+(C) of a linear aliphatic polycarbonate (D).
Claim 4
Dependent Claim 15 words
Moulding compositions according to claim 1 containing as (C) a polymer prepared by anionic polymerization.
Claim 5
Dependent Claim 17 words
Moulding compositions according to claim 2 containing as (D) a polymer prepared by anionic ring opening polymerization.
Claim 6
Dependent Claim 31 words
Moulding compositions according to claim 1 containing as (C) a copolymer of from 5 to 95% by weight of styrene and from 95 to 5% by weight of neopentyl glycol carbonate.
Claim 7
Dependent Claim 12 words
Moulding compositions according to claim 2 containing as (D) polyneopentyl glycol carbonate.
Claim 8
Dependent Claim 33 words
Moulding compositions according to claim 1 wherein A denotes styrene or butadiene and R 1 , R 2 , R 3 and R 4 =H, CH 3 or C 2 H 5 .

References Cited (Backward Citations)

US3639503A Cited
US4360643A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-03-26 1993-09-25 1994-03-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-03-26 1997-09-25 1998-03-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-03-26 2001-09-25 2002-03-27 $7700.00 Window Closed / Lapsed

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