US4911238A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Gas flooding with surfactants enriched in olefin disulfonate
Assignee: Shell USA Inc
•
Filing: 1988-12-19
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Granted: 1990-03-27
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Expires: 2008-12-19
Abstract
Abstract An improved process for recovering oil by injecting a mixture of noncondensible gas and gas foam surfactant into an oil-containing subterranean reservoir, the improvement provided by using a surfactant enriched in olefin disulfonate. The sulfactant may be used in either a gas drive or a gas soak process. Disulfonate-enriched gas foam surfactants and mixtures are also described.
Inventors
- 👤 Hon Chung Lau
- 👤 John K. Borchardt
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 22:31
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/60; C09K8/92; C09K8/94; C09K8/58; C09K8/594; Y; Y10; Y10S; Y10S507/00; Y10S507/935; Y10S507/936
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
67 words
A process for recovering oil from a reservoir penetrated by at least one injection well and at least one production well, comprising: displacing within the reservoir a gas foam mixture of noncondensible gas and aqueous surfactant solution, said surfactant containing at least about 25 wt % olefin disulfonate, said olefin disulfonate derived from olefins with carbon numbers in the range of from about 16 to about 40.
Claim 2
Dependent Claim
67 words
A process for recovering oil from a reservoir penetrated by at least one injection well and at least one production well, comprising: displacing within the reservoir a gas foam mixture of noncondensible gas and aqueous surfactant solution, said surfactant containing at least about 25 wt % olefin disulfonate, said olefin disulfonate derived from olefins with carbon numbers in the range of from about 16 to about 40.
Claim 3
Dependent Claim
86 words
A process for recovering oil from a reservoir penetrated by at least one injection well and at least one production well, comprising: injecting into the reservoir a gas foam mixture of noncondensible gas and aqueous surfactant solution, said surfactant containing at least about 25 wt % olefin disulfonate, said olefin disulfonate derived from olefins with carbon numbers in the range of from about 16 to about 40; and displacing the gas foam mixture within the reservoir to assist in recovery of hydrocarbons at the production well.
Claim 4
Dependent Claim
86 words
A process for recovering oil from a reservoir penetrated by at least one injection well and at least one production well, comprising: injecting into the reservoir a gas foam mixture of noncondensible gas and aqueous surfactant solution, said surfactant containing at least about 25 wt % olefin disulfonate, said olefin disulfonate derived from olefins with carbon numbers in the range of from about 16 to about 40; and displacing the gas foam mixture within the reservoir to assist in recovery of hydrocarbons at the production well.
Claim 5
Dependent Claim
17 words
The process of claim 2 wherein the surfactant contains at least about 30 wt % olefin disulfonate.
Claim 6
Dependent Claim
17 words
The process of claim 2 wherein the surfactant contains at least about 40 wt % olefin disulfonate.
Claim 7
Dependent Claim
17 words
The process of claim 4 wherein the surfactant contains at least about 50 wt % olefin disulfonate.
Claim 8
Dependent Claim
39 words
The process of any one of claims 2, 3, 4, or 5 wherein an electrolyte is injected in a concentration from about 0.01 wt % to about 15.0 wt % of the aqueous phase of the gas foam mixture.
Claim 9
Dependent Claim
77 words
A process for recovering oil from a reservoir through the use of a single well, comprising: injecting into the reservoir a gas foam mixture of noncondensible gas and aqueous surfactant solution, said surfactant containing at least about 25 wt % olefin disulfonate, said olefin disulfonate derived from olefins with carbon numbers in the range of from about 16 to about 40; allowing the gas foam mixture to soak in the reservoir; and producing oil from the reservoir.
Claim 10
Dependent Claim
77 words
A process for recovering oil from a reservoir through the use of a single well, comprising: injecting into the reservoir a gas foam mixture of noncondensible gas and aqueous surfactant solution, said surfactant containing at least about 25 wt % olefin disulfonate, said olefin disulfonate derived from olefins with carbon numbers in the range of from about 16 to about 40; allowing the gas foam mixture to soak in the reservoir; and producing oil from the reservoir.
Claim 11
Dependent Claim
17 words
The process of claim 7 wherein the surfactant contains at least about 30 wt % olefin disulfonate.
Claim 12
Dependent Claim
17 words
The process of claim 7 wherein the surfactant contains at least about 40 wt % olefin disulfonate.
Claim 13
Dependent Claim
17 words
The process of claim 7 wherein the surfactant contains at least about 50 wt % olefin disulfonate.
Claim 14
Dependent Claim
39 words
The process of any one of claims 7, 8, 9, or 10 wherein an electrolyte is injected in a concentration from about 0.01 wt % to about 15.0 wt % of the aqueous phase of the gas foam mixture.
Claim 15
Dependent Claim
97 words
A process for recovering oil from a reservoir penetrated by at least one injection well and at least one production well, comprising: injecting into the reservoir an aqueous surfactant solution wherein the surfactant contains at least about 25 wt % olefin disulfonate, said olefin disulfonate derived from olefins with carbon numbers in the range of from about 16 to about 40; injecting into the reservoir a noncondensible gas; forming a gas foam mixture; and displacing the gas foam mixture within the reservoir by injecting additional noncondensible gas to assist in recovery of hydrocarbons at the production well.
Claim 16
Dependent Claim
97 words
A process for recovering oil from a reservoir penetrated by at least one injection well and at least one production well, comprising: injecting into the reservoir an aqueous surfactant solution wherein the surfactant contains at least about 25 wt % olefin disulfonate, said olefin disulfonate derived from olefins with carbon numbers in the range of from about 16 to about 40; injecting into the reservoir a noncondensible gas; forming a gas foam mixture; and displacing the gas foam mixture within the reservoir by injecting additional noncondensible gas to assist in recovery of hydrocarbons at the production well.
Claim 17
Dependent Claim
17 words
The process of claim 12 wherein the surfactant contains at least about 30 wt % olefin disulfonate.
Claim 18
Dependent Claim
17 words
The process of claim 12 wherein the surfactant contains at least about 40 wt % olefin disulfonate.
Claim 19
Dependent Claim
17 words
The process of claim 12 wherein the surfactant contains at least about 50 wt % olefin disulfonate.
Claim 20
Dependent Claim
39 words
The process of any one of claims 12, 13, 14, or 15 wherein an electrolyte is injected in a concentration from about 0.01 wt % to about 15.0 wt % of the aqueous phase of the gas foam mixture.
Claim 21
Dependent Claim
166 words
A process for recovering oil from a reservoir penetrated by at least one injection well and at least one production well, comprising: injecting into the reservoir a gas foam mixture, comprising: (a) aqueous surfactant solution, wherein the surfactant is present in a concentration of from about 0.05 wt % to about 5.0 wt % in the aqueous phase of the gas foam mixture, and wherein the surfactant contains at least about 40 wt % olefin disulfonate, said olefin disulfonate derived from olefins with carbon numbers in the range of from about 16 to about 40; (b) noncondensible gas, in an amount of from about 1 mol % to about 100 mol % of the gaseous phase of the gas foam mixture; and (c) electrolyte, in a concentration of from about 0.01 wt % to about 15.0 wt % of the aqueous phase of the gas foam mixture; and displacing the gas foam mixture within the reservoir to assist in recovery of oil at the production well.
Claim 22
Dependent Claim
166 words
A process for recovering oil from a reservoir penetrated by at least one injection well and at least one production well, comprising: injecting into the reservoir a gas foam mixture, comprising: (a) aqueous surfactant solution, wherein the surfactant is present in a concentration of from about 0.05 wt % to about 5.0 wt % in the aqueous phase of the gas foam mixture, and wherein the surfactant contains at least about 40 wt % olefin disulfonate, said olefin disulfonate derived from olefins with carbon numbers in the range of from about 16 to about 40; (b) noncondensible gas, in an amount of from about 1 mol % to about 100 mol % of the gaseous phase of the gas foam mixture; and (c) electrolyte, in a concentration of from about 0.01 wt % to about 15.0 wt % of the aqueous phase of the gas foam mixture; and displacing the gas foam mixture within the reservoir to assist in recovery of oil at the production well.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1993-03-26 | 1993-09-25 | 1994-03-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-03-26 | 1997-09-25 | 1998-03-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-03-26 | 2001-09-25 | 2002-03-27 | $7700.00 | Window Closed / Lapsed |