Polymeric compounds and radiation-sensitive mixture containing them

Claim 2

A polymer comprising repeat units X, wherein X is represented by the formula ##STR5## where R is a hydrogen or a halogen atom, a cyanide group or an aliphatic hydrocarbon group of 1-4 carbon atoms, R 1 , R 2 , R 3 are identical or different, and each denotes a hydrogen or a halogen atom, an alkoxycarbonyl group, or a hydrocarbon group selected from branched and unbranched, saturated and unsaturated groups with cyclic and open chains which can be substituted by halogen atoms or hydroxyl groups, or which contain ether or keto groups, R 4 is a hydrogen atom or a divalent organic group which is linked intermolecularly or intramolecularly to another unit represented by formula (I), on average at least one R 4 of each polymer unit being hydrogen, A denotes the atoms required for completing a mononuclear or dinuclear carbocyclic or heterocyclic aromatic ring system and m is 2 or 3, and said polymer being a homopolymer of units X or a copolymer of units X and units Y, wherein Y is represented by the formula ##STR6## where R 5 is H, alkyl or alkenyl, R 6 is alkyl, carboxyl, alkoxycarbonyl or alkylcarbonyloxy, and R 7 is H or carboxyl, or R 6 and R 7 together are an acid anhydride group.

Claim 3

The polymer as claimed in claim 1, wherein A denotes the carbon atoms required for completing a benzene ring.

Claim 4

The polymer as claimed in claim 1, wherein said polymer has a molecular weight MHD n of between about 1000 to 200,000.

Claim 5

The polymer as claimed in claim 1, wherein m is 2.

Claim 6

The polymer as claimed in claim 1, wherein said polymer comprises 20 to 100 mol-% of units of formula (I).

Claim 7

A radiation-sensitive mixture comprising: (A) a water-insoluble polymeric binder which is soluble in aqueous alkaline solutions and has phenolic hydroxyl side groups and (B) (1) a 1,2-quinonediazide or (2) a combination of (a) a compound which forms a strong acid under the action of actinic radiation and (b) a compound which has at least one acid cleavable C-O-C bond and the solubility of which in a developer is increased by the action of acid, wherein said binder comprises a polymer comprised of repeat units X, wherein X is represented by the formula ##STR7## where R is a hydrogen or a halogen atom, a cyanide group or an aliphatic hydrocarbon group of 1-4 carbon atoms, R 1 ,R 2 ,R 3 are identical or different, and each denotes a hydrogen or a halogen atom, an alkoxycarbonyl group, or a hydrocarbon group selected from branched and unbranched, saturated and unsaturated groups with cyclic and open chains which can be substituted by halogen atoms or hydroxy groups, or which contain ether or keto groups, R 4 is a hydrogen atom o a divalent organic group which is linked inter-molecularly or intramolecularly to another unit represented by formula (I), on average at least one R 4 of each polymer unit being hydrogen, A denotes the atoms required for completing a monomuclear or dinuclear carbocyclic or heterocyclic aromatic ring system and m is 2 or 3, and said polymer being a homopolymer of units X or a copolymer of units X add units Y, wherein Y is represented by the formula ##STR8## where R 5 is H, alkyl or alkenyl, R 6 is alkyl, carboxyl, alkoxycarbonyl or alkylcarbonyloxy, and R 7 is H or carboxy,, or R 6 and R 7 together are an acid anhydride group.

Claim 8

A radiation-sensitive mixture comprising: (A) a water-insoluble polymeric binder which is soluble in aqueous alkaline solutions and has phenolic hydroxyl side groups and (B) (1) a 1,2-quinonediazide or (2) a combination of (a) a compound which forms a strong acid under the action of actinic radiation and (b) a compound which has at least one acid cleavable C-O-C bond and the solubility of which in a developer is increased by the action of acid, wherein said binder comprises a polymer comprised of repeat units X, wherein X is represented by the formula ##STR7## where R is a hydrogen or a halogen atom, a cyanide group or an aliphatic hydrocarbon group of 1-4 carbon atoms, R 1 ,R 2 ,R 3 are identical or different, and each denotes a hydrogen or a halogen atom, an alkoxycarbonyl group, or a hydrocarbon group selected from branched and unbranched, saturated and unsaturated groups with cyclic and open chains which can be substituted by halogen atoms or hydroxy groups, or which contain ether or keto groups, R 4 is a hydrogen atom o a divalent organic group which is linked inter-molecularly or intramolecularly to another unit represented by formula (I), on average at least one R 4 of each polymer unit being hydrogen, A denotes the atoms required for completing a monomuclear or dinuclear carbocyclic or heterocyclic aromatic ring system and m is 2 or 3, and said polymer being a homopolymer of units X or a copolymer of units X add units Y, wherein Y is represented by the formula ##STR8## where R 5 is H, alkyl or alkenyl, R 6 is alkyl, carboxyl, alkoxycarbonyl or alkylcarbonyloxy, and R 7 is H or carboxy,, or R 6 and R 7 together are an acid anhydride group.

Claim 9

A radiation-sensitive recording material comprising a base material and a radiation-sensitive recording layer provided on said base material, said recording layer comprising (A) a water-insoluble polymeric binder which is soluble in aqueous alkaline solutions and has phenolic hydroxyl side groups and (B) (1) a 1,2-quinonediazide or (2) a combination of (a) a compound which forms a strong acid under the action of actinic radiation and (b) a compound which has at least one acid cleavable C-O-C bond and the solubility of which in a developer is increased by the action of acid, wherein said binder comprises a polymer comprising repeat units X, wherein X is represented by the formula ##STR9## where R is a hydrogen or a halogen atom, a cyanide group of an aliphatic hydrocarbon group of 1-4 carbon atoms, R 1 ,R 2 , R 3 are identical or different, and each denotes a hydrogen or a halogen atom, an alkoxycarbonyl group, or a hydrocarbon group selected from branched and unbranched, saturated and unsaturated groups with cyclic and open chains which can be substituted by halogen atoms or hydroxyl groups, or which contain ether or keto groups, R 4 is a hydrogen atom or a divalent organic group which is linked intermolecularly or intramoleularly to another unit represented by formula (I), on average at least one R 4 of each polymer unit being hydrogen, A denotes the atoms required for completing a mononuclear or dinuclear carbocyclic or heterocyclic aromatic ring system and m is 2 or 3, and said polymer being a homopolymer of units X or a copolymer of units X and units Y, wherein Y is represented by the formula ##STR10## where R 5 is H, alkyl or alkenyl, R 6 is alkyl, carboxyl, alkoxycarbonyl or alkylcarbonylosy, and R 7 is H or carbonyl, or R 6 and R 7 together are an acid anhydride group.

Claim 10

A radiation-sensitive recording material comprising a base material and a radiation-sensitive recording layer provided on said base material, said recording layer comprising (A) a water-insoluble polymeric binder which is soluble in aqueous alkaline solutions and has phenolic hydroxyl side groups and (B) (1) a 1,2-quinonediazide or (2) a combination of (a) a compound which forms a strong acid under the action of actinic radiation and (b) a compound which has at least one acid cleavable C-O-C bond and the solubility of which in a developer is increased by the action of acid, wherein said binder comprises a polymer comprising repeat units X, wherein X is represented by the formula ##STR9## where R is a hydrogen or a halogen atom, a cyanide group of an aliphatic hydrocarbon group of 1-4 carbon atoms, R 1 ,R 2 , R 3 are identical or different, and each denotes a hydrogen or a halogen atom, an alkoxycarbonyl group, or a hydrocarbon group selected from branched and unbranched, saturated and unsaturated groups with cyclic and open chains which can be substituted by halogen atoms or hydroxyl groups, or which contain ether or keto groups, R 4 is a hydrogen atom or a divalent organic group which is linked intermolecularly or intramoleularly to another unit represented by formula (I), on average at least one R 4 of each polymer unit being hydrogen, A denotes the atoms required for completing a mononuclear or dinuclear carbocyclic or heterocyclic aromatic ring system and m is 2 or 3, and said polymer being a homopolymer of units X or a copolymer of units X and units Y, wherein Y is represented by the formula ##STR10## where R 5 is H, alkyl or alkenyl, R 6 is alkyl, carboxyl, alkoxycarbonyl or alkylcarbonylosy, and R 7 is H or carbonyl, or R 6 and R 7 together are an acid anhydride group.

Claim 11

A process for preparing relief images, comprising the steps of (1) imagewise irradiating a radiation-sensitive recording material as claimed in claim 7 with actinic radiation such that the solubility of the recording layer in an aqueous alkaline developer solution increases and (2) removing irradiated portions of the recording layer by means of an aquious alkaline developer solution.