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Multi-component coating composition comprising an anhydride containing polymer, a glycidyl component and a self-stabilized dispersion resin

Assignee: EIDP Inc
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Filing: 1988-06-27
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Granted: 1990-03-13
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Expires: 2008-06-27
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Abstract

Abstract A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about (a) 25-94% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000; (b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups; (c) 1-40% by weight, based on the weight of the binder, of a self-stabilized dispersed resin; and the composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.

Inventors

  • 👤 Robert J. Barsotti
  • 👤 Patrick H. Corcoran

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 06:09
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/10; C09D133/12; C09D163/00; C09D133/062; C09D133/064; C08; C08L; C08L33/00; C08L33/04; C08L33/06; C08L33/062; C08L63/00

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 210 words
A coating composition comprising 20-80% by weight of reactive binder components and 80-20% by weight of an organic liquid carrier; wherein the binder consists essentially of about (a) 25-94% by weight, based on the weight of the binder, of an anhydride acrylic polymer having at least two reactive anhydride groups that consists of polymerized monomers of an ethylenically unsaturated anhydride or an ethylenically unsaturated dicarboxylic acid and polymerized monomers selected from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000; (b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups; (c) 1 to 40% by weight, based on the weight of the binder, of a self stabilized dispersed resin formed by polymerizing in solution the following constituents; (1) an acrylic solution polymer, (2) monomers of alkyl methacrylate or acrylate and hydroxy ethyl acrylate or methacrylate, wherein either the acrylic solution polymer contains post reacted glycidyl methacrylate or acrylate or the monomers additionally contain glycidyl methacrylate or acrylate, and the composition contains about 0.1-5% by weight, based on the weight of the binder, of a catalyst.
Claim 2
Dependent Claim 210 words
A coating composition comprising 20-80% by weight of reactive binder components and 80-20% by weight of an organic liquid carrier; wherein the binder consists essentially of about (a) 25-94% by weight, based on the weight of the binder, of an anhydride acrylic polymer having at least two reactive anhydride groups that consists of polymerized monomers of an ethylenically unsaturated anhydride or an ethylenically unsaturated dicarboxylic acid and polymerized monomers selected from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000; (b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups; (c) 1 to 40% by weight, based on the weight of the binder, of a self stabilized dispersed resin formed by polymerizing in solution the following constituents; (1) an acrylic solution polymer, (2) monomers of alkyl methacrylate or acrylate and hydroxy ethyl acrylate or methacrylate, wherein either the acrylic solution polymer contains post reacted glycidyl methacrylate or acrylate or the monomers additionally contain glycidyl methacrylate or acrylate, and the composition contains about 0.1-5% by weight, based on the weight of the binder, of a catalyst.
Claim 3
Dependent Claim 56 words
The coating composition of claim 1 in which the glycidyl component is selected from the group consisting of polyglycidyl ethers of low molecular weight polyols, epoxy resins of epichlorohydrin and bisphenol A, polyglycidyl esters of polyacids, polyglycidyl ethers of isocyanurates, glycidyl methacrylate or glycidyl acrylate containing acrylic polymers or compatible mixtures of any of the above.
Claim 4
Dependent Claim 33 words
The coating composition of claim 1 in which the anhydride acrylic polymer additionally contains about 0.1-50% by weight of monomers selected from the group consisting of styrene, acrylonitrile, methacrylonitrile and any mixtures thereof.
Claim 5
Dependent Claim 31 words
The coating composition of claim 1 in which the anhydride acrylic polymer has a glass transition temperature of 0° to 70° C. and a weight average molecular weight of about 3,000-25,000.
Claim 6
Dependent Claim 71 words
The coating composition of claim 3 in which the anhydride acrylic polymer consists essentially of 20-40% by weight, based on the weight of the anhydride acrylic polymer, of methyl methacrylate, styrene or mixture of methyl methacrylate and styrene, 35-55% by weight of an alkyl methacrylate or an alkyl acrylate having 2-4 carbon atoms in the alkyl group and 5-55% by weight of polymerizable ethylenically unsaturated anhydride or ethylenically unsaturated dicarboxylic acid.
Claim 7
Dependent Claim 35 words
The coating composite which the acrylic solution polymer in the self-stabilized dispersed resin consists essentially of polymerized monomers of styrene, alkyl methacrylate, alkyl acrylate, hydroxy alkyl acrylate or methacrylate and acrylic acid or methacrylic acid.
Claim 8
Dependent Claim 35 words
The coating composite which the acrylic solution polymer in the self-stabilized dispersed resin consists essentially of polymerized monomers of styrene, alkyl methacrylate, alkyl acrylate, hydroxy alkyl acrylate or methacrylate and acrylic acid or methacrylic acid.
Claim 9
Dependent Claim 23 words
The coating composition of claim 6 in which the acrylic solution polymer in the self-stabilized dispersed resin is post reacted with glycidyl methacrylate.
Claim 10
Dependent Claim 60 words
The coating composition of claim 6 in which the acrylic solution polymer in the self-stabilized dispersed resin consists essentially of 5-25% by weight styrene, 20-40% by weight butyl methacrylate, 20-40% by weight butyl acrylate, 5-15% by weight hydroxy ethyl acrylate, 1-5% by weight acrylic acid, 10-20% by weight ethyl methacrylate and has a weight average molecular weight of about 7,000-15,000.
Claim 11
Dependent Claim 70 words
The coating composition of claim 7 in which the acrylic solution polymer in the self-stabilized dispersed resin consists essentially of 5-25% by weight styrene, 25-35% by weight butyl methacrylate, 20-40% butyl acrylate, 5-15% by weight hydroxy ethyl acrylate, 1-5% by weight acrylic acid, 10-20% by weight ethyl methacrylate and 1-5% by weight glycidyl methacrylate post reacted with acrylic acid and has a weight average molecular weight of 7,000 to 15,000.
Claim 12
Dependent Claim 26 words
The coating composition of claim 9 in which the glycidyl component comprises a polyglycidyl ether of a polyol or a di- or polyglycidylester of an acid
Claim 13
Dependent Claim 24 words
The coating composition of claim 10 in which the anhydride acrylic polymer consists of polymerized monomers of methyl methacrylate, butyl acrylate and itaconic acid.
Claim 14
Dependent Claim 28 words
The coating composition of claim 10 in which the anhydride acrylic polymer consists of polymerized monomers of butyl acrylate, maleic anhydride and maleic acid and in addition styrene.
Claim 15
Dependent Claim 62 words
The coating composition of claim 5 in which the anhydride acrylic polymer consists essentially of polymerized monomers of methyl methacrylate, styrene, butyl acrylate and itaconic anhydride; and the glycidyl component consists essentially of sorbitol polyglycidyl ether or the di- or polyglycidylester of an acid or a mixture thereof and the catalyst is triethylene diamine or dimethyl ethanol amine or a mixture thereof.
Claim 16
Dependent Claim 64 words
The coating composition of claim 5 in which the anhydride acrylic polymer consists essentially of polymerized monomers of methyl metghacrylate butyl acrylate, styrene, maleic anhydride and maleic acid; and the glycidyl component consists essentially of sorbitol polyglycidyl ether or the di- or polyglycidylester of an acid or a mixture thereof and the catalyst is triethylene diamine or dimethyl ethanol amine or a mixture thereof.
Claim 17
Dependent Claim 20 words
The coating composition of claim 1 containing about 0.1-200% by weight, based on the weight of the binder, of pigment.
Claim 18
Dependent Claim 45 words
The coating composition of claim 1 in which the anhydride acrylic polymer additionally contains up to about 40% by weight of polymerized monomers selected from the group consisting of alkyl acrylate or alkyl methacrylate having 9-12 carbon atoms in the alkyl groups or mixtures thereof.

References Cited (Backward Citations)

US3136736A Cited
GB994881A Cited
US4452948A Cited
US4507411A Cited
EP0123793A1 Cited
US4591533A Cited
US4816500A Cited
US4732791A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-03-12 1993-09-11 1994-03-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-03-12 1997-09-11 1998-03-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-03-12 2001-09-11 2002-03-13 $7700.00 Window Closed / Lapsed

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