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US4906497A Expired / Lapsed US ⏱️ 0.0 years remaining

Microwave-activatable hot-melt adhesive

Assignee: UZIN-WERK GEORG UTZ & Co KG DIESELSTR 3 7900 ULM WEST GERMANY GmbH
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Filing: 1988-11-04
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Granted: 1990-03-06
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Expires: 2008-11-04
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Abstract

Abstract A hot-melt adhesive comprising at least one component which under the action of microwaves on the dry hot-melt adhesive leads to an increased heating-up rate compared with a corresponding dry hot-melt adhesive without said component contains with a view to universal application with highest possible activatability and constant property characteristic as microwave-activatable component electrically conductive substances with an electrical conductivity higher than that of the dry hot-melt adhesive without said component. Provided as electrically conductive substances are in particular carbon fibres, carbon black, graphite, antistatic agents and metal particles, either on their own or in mixtures adapted to the use. Hot-melt adhesive coatings or self-supporting hot-melt adhesive films having these additives have a heating-up rate by microwaves which is greater by a factor of up to 400 than that of conventional microwave-activatable adhesives. This results in an appreciable reduction of the consumption of electrical energy when adhering by microwave activation or a corresponding increase in the laying capacity of the material to be stuck. The new hot-melt adhesive is suitable preferably for microwave-activated hot-melt adhering of sheet substrates, in particular floor coverings, and by rendering the activatability largely independent of the water content of usual adhesives also achieves the uniformity and reproduceability of the activation and melting-on behavior necessary for industrial uses and production.

Inventors

  • 👤 Horst D. Hellmann
  • 👤 Roland Krieger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 17:22
CPC Classifications
H; H01; H01B; H01B1/00; H01B1/20; H01B1/24; C; C09; C09J; C09J7/00; C09J7/10; H01B1/22; Y; Y10; Y10S; Y10S412/00; Y10S412/90; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/13; Y10T428/1334; Y10T428/1338; Y10T428/1352; Y10T428/1355; Y10T428/1372; Y10T428/16; Y10T428/163; Y10T428/164; Y10T428/166; Y10T428/167; Y10T428/23907; Y10T428/23921; Y10T428/23993; Y10T428/25; Y10T428/256; Y10T428/28; Y10T428/2813; Y10T428/2817; Y10T428/2826; Y10T428/2852; Y10T428/2878; Y10T428/2887

Claims Analysis

Total Claims: 42
Claim 1
Independent Claim 108 words
Hot-melt adhesive comprising at least one component which under the action of microwaves on the dry hot-melt adhesive leads to an increase heating up rate compared with a corresponding dry hot-melt adhesive without said component and thereby to a higher melting-on rate, further comprising a binder base of one or more thermoplastic polymers and a microwave-activatable electrically electrically conductive substance having an electrical conductivity greater than that of a dry hot-melt adhesive without said substance, which adhesive after application to a material to be adhered forms an adhesive coating which is dry after the drying or hardening or setting and only weakly tacky to non-tacky at room temperature.
Claim 2
Dependent Claim 108 words
Hot-melt adhesive comprising at least one component which under the action of microwaves on the dry hot-melt adhesive leads to an increase heating up rate compared with a corresponding dry hot-melt adhesive without said component and thereby to a higher melting-on rate, further comprising a binder base of one or more thermoplastic polymers and a microwave-activatable electrically electrically conductive substance having an electrical conductivity greater than that of a dry hot-melt adhesive without said substance, which adhesive after application to a material to be adhered forms an adhesive coating which is dry after the drying or hardening or setting and only weakly tacky to non-tacky at room temperature.
Claim 3
Dependent Claim 15 words
Hot-melt adhesive according to claim 1, the hot-melt adhesive sheet is weakly tacky to non-tacky.
Claim 4
Dependent Claim 19 words
Hot-melt adhesive according to claim 1, wherein the thickness of the hot-melt adhesive sheet is up to 5 mm.
Claim 5
Dependent Claim 21 words
Hot-melt adhesive according to claim 1, wherein the hot-melt adhesive sheet is formed web-shaped a width of up to 3 meters.
Claim 6
Dependent Claim 14 words
Hot-melt adhesive according to claim 1, wherein said electrically conductive substance comprises carbon fibres.
Claim 7
Dependent Claim 21 words
Hot-melt adhesive according to claim 5, wherein said carbon fibres have a mean length in a range up to 50 mm.
Claim 8
Dependent Claim 26 words
Hot-melt adhesive according to claim 5, wherein said carbon fibres are provided in a proportion of 0.5-30% by weight with respect to the dry adhesive composition.
Claim 9
Dependent Claim 18 words
Hot-melt adhesive according to claim 1, wherein said electrically conductive substance comprises carbon black or carbon black pigments.
Claim 10
Dependent Claim 30 words
Hot-melt adhesive according to claim 8, wherein said carbon black or carbon black pigments are provided in a proportion of 0.5-20% by weight with respect to the dry adhesive composition.
Claim 11
Dependent Claim 13 words
Hot-melt adhesive according to claim 1, wherein said electrically conductive substance is graphite.
Claim 12
Dependent Claim 25 words
Hot-melt adhesive according to claim 10, wherein said graphite is provided in a proportion of 2-40% by weight with respect to the dry adhesive composition.
Claim 13
Dependent Claim 26 words
Hot-melt adhesive according to claim 1, wherein said electrically conductive substance comprises metal particles in the form of powder, flakes, grains, folia, fibres or the like.
Claim 14
Dependent Claim 26 words
Hot-melt adhesive according to claim 12, wherein said metal particles are provided in a proportion of 1-70% by weight with respect to the dry adhesive composition.
Claim 15
Dependent Claim 14 words
Hot-melt adhesive according to claim 1, wherein said electrically conductive substance comprises antistatic agents.
Claim 16
Dependent Claim 26 words
Hot-melt adhesive according to claim 14, wherein said antistatic agents are provided in a proportion of 0.5-20% by weight with respect to the dry adhesive composition.
Claim 17
Dependent Claim 33 words
Hot-melt adhesive according to claim 1, wherein said electrically conductive substance comprises together two or more of the substances carbon fibres, carbon black or carbon black pigments, graphite, metal particles and antistatic agents.
Claim 18
Dependent Claim 30 words
Hot-melt adhesive according to claim 1, wherein organic amines are provided as modifying agent in a proportion of up to 20% by weight with respect to the dry adhesive composition.
Claim 19
Dependent Claim 32 words
Hot-melt adhesive according to claim 1, wherein organic ethers or polyethers are provided as modifying agent in an amount of up to 40% by weight with respect to the dry adhesive composition.
Claim 20
Dependent Claim 23 words
Hot-melt adhesive according to claim 1, wherein hollow body fillers are provided having a mean particle diameter in the range of 10-90 μm.
Claim 21
Dependent Claim 34 words
Method of forming a hot-melt adhesive application on a material to be stuck in accordance with claim 1 wherein said hot-melt adhesive is prepared as solution or dispersion or emulsion in water and applied.
Claim 22
Dependent Claim 34 words
Method of forming a hot-melt adhesive coating on a material to be stuck according to claim 1, wherein said hot-melt adhesive is prepared as solution or dispersion or emulsion in organic solvents and applied.
Claim 23
Dependent Claim 32 words
Method of forming a hot-melt adhesive coating on a material to be stuck in accordance with claim 1, wherein said hot-melt adhesive is applied in molten form without volatile liquid carrier medium.
Claim 24
Dependent Claim 15 words
Method according to claim 20, wherein said hot-melt adhesive is applied in mechanically foamed form.
Claim 25
Dependent Claim 15 words
Method according to claim 21, wherein said hot-melt adhesive is applied in mechanically foamed form.
Claim 26
Dependent Claim 15 words
Method according to claim 22, wherein said hot-melt adhesive is applied in mechanically foamed form.
Claim 27
Dependent Claim 18 words
Method according to claim 20, wherein said hot-melt adhesive is foamed chemically before, during or after the application.
Claim 28
Dependent Claim 18 words
Method according to claim 21, wherein said hot-melt adhesive is foamed chemically before, during or after the application.
Claim 29
Dependent Claim 18 words
Method according to claim 22, wherein said hot-melt adhesive is foamed chemically before, during or after the application.
Claim 30
Dependent Claim 72 words
Method of forming a self-supporting hot-melt adhesive sheet or foil from a hot-melt adhesive according to claim 1, wherein said hot-melt adhesive is applied in liquid or molten-on form by means of brushing, rolling, splashing, spraying or another application method over part or all of the area to an intermediate carrier and after the drying or hardening or setting is detached from the intermediate carrier as self-supporting hot-melt adhesive foil or sheet.
Claim 31
Dependent Claim 96 words
A hot-melt adhesive sheet comprising at least one component which under the action of microwaves on the dry hot-melt adhesive leads to an increased heating up rate compared with a corresponding dry hot-melt adhesive without said component and thereby to a higher melting-on rate, a binder base of one or more thermoplastic polymers and a microwave-activatable electrically conductive substance having an electrical conductivity greater than that of a dry hot-melt adhesive without said electrically conductive substance, wherein the hot-melt adhesive is formed as a self-supporting sheet after the drying or hardening or setting of the adhesive.
Claim 32
Dependent Claim 96 words
A hot-melt adhesive sheet comprising at least one component which under the action of microwaves on the dry hot-melt adhesive leads to an increased heating up rate compared with a corresponding dry hot-melt adhesive without said component and thereby to a higher melting-on rate, a binder base of one or more thermoplastic polymers and a microwave-activatable electrically conductive substance having an electrical conductivity greater than that of a dry hot-melt adhesive without said electrically conductive substance, wherein the hot-melt adhesive is formed as a self-supporting sheet after the drying or hardening or setting of the adhesive.
Claim 33
Dependent Claim 17 words
Hot-melt adhesive according to claim 30, wherein the hot-melt adhesive is a sheet having holes formed therein.
Claim 34
Dependent Claim 16 words
A hot-melt adhesive sheet according to claim 30, wherein said electrically conductive substance comprises carbon fibres.
Claim 35
Dependent Claim 20 words
A hot-melt adhesive sheet according to claim 30, wherein said electrically conductive substance comprises carbon black or carbon black pigments.
Claim 36
Dependent Claim 15 words
A hot-melt adhesive sheet according to claim 30, wherein said electrically conductive substance is graphite.
Claim 37
Dependent Claim 28 words
A hot-melt adhesive sheet according to claim 30, wherein said electrically conductive substance comprises metal particles in the form of powder, falkes, grains, folia, fibres or the like.
Claim 38
Dependent Claim 16 words
A hot-melt adhesive sheet according to claim 30, wherein said electrically conductive substance comprises antistatic agents.
Claim 39
Dependent Claim 41 words
A hot-melt adhesive sheet according to claim 30, wherein said electrically conductive substance comprises together two or more of the substances selected from the group consisting of carbon fibres, carbon black or carbon black pigments, graphite, metal particles and antistatic agents.
Claim 40
Dependent Claim 33 words
A hot-melt adhesive sheet according to claim 30, wherein organic amines are provided as a modifying agent in a proportion of up to 20% by weight with respect to the dry adhesive composition.
Claim 41
Dependent Claim 35 words
A hot-melt adhesive sheet according to claim 30, wherein organic ethers or polyethers are provided as a modifying agent in an amount of up to 40% by weight with respect to the dry adhesive composition.
Claim 42
Dependent Claim 28 words
A hot-melt adhesive sheet according to claim 30, wherein hollow body fillers are provided having a mean particle, diameter in the range of 10 to 90 μ m.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-03-05 1993-09-04 1994-03-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-03-05 1997-09-04 1998-03-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-03-05 2001-09-04 2002-03-06 $7700.00 Window Closed / Lapsed

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