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US4902654A Expired / Lapsed US ⏱️ 0.0 years remaining

Mixed lanthanide-magnesium aluminates and lasers using monocrystals of these aluminates

Assignee: Centre National de la Recherche Scientifique
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Filing: 1987-06-16
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Granted: 1990-02-20
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Expires: 2007-06-16
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Abstract

Abstract Mixed lanthanide-magnesium aluminates and lasers using monocrystals of these aluminates. These lasers in particular incorporate two flash lamps for longitudinally pumping a monocrystalline rod of a magnetoplumbite-aluminate emitting visible or infrared light, amplified between a mirror, a polarizing prism being used for passing to the outside of the laser the amplified light beam. The aluminate is of formula: (La.sub.1-x Tr.sub.x).sub.1-y-v Mg.sub.1-z-t Al.sub.11-u+y+2z/3 Cr.sub.u O 19-t-3v/3 . in which Tr represents a) at least one single trivalent substance chosen from among lanthanides, Y 3+ , Sc 3+ , or b) at least one pair of lanthanides formed from a divalent element and a trivalent element, while retaining the electrical neutrality by adding aluminium or oxygen deficiencies, or any combination of (a) and (b); x is a number such that 0≦x<1; y and v are numbers such that 0≦y+v≦0.4; z and t are numbers such that 0≦z+t<1, provided that when z=t=0, y+v is ≠0 for Tr representing a single trivalent lanthanide; u is a number between 0 and 2, provided that when Tr represents Y 3+ or Sc 3+ u is ≠0, that when x=0 u is ≠0 and that when u=0 x is ≠0.

Inventors

  • 👤 Jean-Jacques Aubert
  • 👤 Anne-Marie Lejus
  • 👤 Bruno Viana
  • 👤 Daniel Vivien

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 14:31
CPC Classifications
C; C30; C30B; C30B29/00; C30B29/10; C30B29/16; C30B29/22; C30B15/00

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 178 words
A mixed lanthanide-magnesium aluminate of the formula: (La.sub.1-x Tr.sub.x).sub.1-y-v Mg.sub.1-z-t Al.sub.11-u+y+2z/3 Cr.sub.u O.sub.19-t-3v/2 in which Tr represents (a) at least one single trivalent substance chosen from among yttrium, scandium and lanthanides other than lanthanum or (b) at least one pair of lanthanides other than lanthanum formed from a divalent element and a trivalent element, whilst retaining the electrical neutrality by adding aluminum or oxygen deficiencies, or any combination of said single substance and pairs; x represents a number such that 0≦x<1; y and v represent numbers such that 0≦y+v≦0.4; z and t represent numbers such that 0≦z+t<1, provided that when z+t=0, y+v is ≠0 and when y+v=0, z+t is ≠0 for Tr representing a single trivalent lanthanide provided that t or v ≠0 when Tr is a single trivalent lanthanide when x=0; u represents a number from 0 to 2, provided that when Tr represents Y 3+ or Sc 3+ , u is ≠0, that when x=0 u is ≠0 and that when u=0, x is ≠0 said aluminate being a monophase and having the structure of magnetoplumbite.
Claim 2
Dependent Claim 178 words
A mixed lanthanide-magnesium aluminate of the formula: (La.sub.1-x Tr.sub.x).sub.1-y-v Mg.sub.1-z-t Al.sub.11-u+y+2z/3 Cr.sub.u O.sub.19-t-3v/2 in which Tr represents (a) at least one single trivalent substance chosen from among yttrium, scandium and lanthanides other than lanthanum or (b) at least one pair of lanthanides other than lanthanum formed from a divalent element and a trivalent element, whilst retaining the electrical neutrality by adding aluminum or oxygen deficiencies, or any combination of said single substance and pairs; x represents a number such that 0≦x<1; y and v represent numbers such that 0≦y+v≦0.4; z and t represent numbers such that 0≦z+t<1, provided that when z+t=0, y+v is ≠0 and when y+v=0, z+t is ≠0 for Tr representing a single trivalent lanthanide provided that t or v ≠0 when Tr is a single trivalent lanthanide when x=0; u represents a number from 0 to 2, provided that when Tr represents Y 3+ or Sc 3+ , u is ≠0, that when x=0 u is ≠0 and that when u=0, x is ≠0 said aluminate being a monophase and having the structure of magnetoplumbite.
Claim 3
Dependent Claim 39 words
A mixed aluminate according to claim 1, wherein x is ≠0 and Tr is chosen from among neodymium, praseodymium, erbium, holmium, thulium, divalent europium-neodymium pairs, divalent europium-praseodymium pairs and the pairs cerium-neodymium, cerium-praseodyium, praseodymium-samarium, praseodymium-dysprosium, praseodymium-thulium, cerium-erbium and cerium-holmium.
Claim 4
Dependent Claim 9 words
A mixed aluminate according to claim 1, wherein x=0.
Claim 5
Dependent Claim 18 words
A mixed aluminate according to claim 1, wherein Tr represents neodymium and x is between 0.2 and 0.5.
Claim 6
Dependent Claim 17 words
A mixed aluminate according to claim 1, wherein Tr represents neodymium and x is about to 0.1.
Claim 7
Dependent Claim 9 words
A mixed aluminate of claim 1 in monocrystal form.
Claim 8
Dependent Claim 19 words
A mixed aluminate according to claim 1 wherein it is of the formula (La.sub.0.90 Nd.sub.0.10).sub.0.9 Mg.sub.0.8 Al.sub.11.383 Cr.sub.0.05 O.sub.19.

References Cited (Backward Citations)

FR43776E Cited
US4606846A Cited

USPTO Annuity & Maintenance Windows

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3.5 Years (Year 4) 1993-02-19 1993-08-21 1994-02-20 $2000.00 Window Closed / Lapsed
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