US4902416A
Expired / Lapsed
US
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Membrane separation device
Assignee: Dow Chemical Co
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Filing: 1989-01-26
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Granted: 1990-02-20
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Expires: 2009-01-26
Abstract
Abstract This invention relates to a hollow fiber membrane device which can accommodate large changes in fiber dimension due to fiber swelling or contraction during operation.
Inventors
- 👤 Lawrence R. Schroeder
- 👤 Terrence L. Caskey
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 11:34
CPC Classifications
B; B01; B01D; B01D63/00; B01D63/02; B01D63/024; B01D63/0241; B01D63/025; B01D63/031; B01D63/04; B01D63/043; B01D63/046
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
212 words
A hollow fiber membrane device comprised of: (1) a plurality of non-woven hollow fiber membranes formed into at least one non-random bundle wherein the membranes are capable of separating at least one of the components from a liquid feed mixture; (2) at least one tubesheet comprised of a thermoplastic or thermoset material wherein the end(s) of the hollow fiber bundle(s) are embedded in the tubesheet(s); (3) at least one core wherein at least one non-woven hollow fiber bundle is wrapped in a spiral fashion about at least one core in such a manner that the non-woven hollow fiber bundle(s) is first formed and then wrapped spirally about the core(s) as a completed bundle(s) such that the fibers comprising the bundle(s) may expand and contract without substantial damage to the fibers; (4) a means for introducing the feed into the membrane device; (5) a means for removing the non-permeate from the membrane device; (6) a means for removing the permeate from the membrane device; and (7) a case which contains the hollow fiber bundle(s), core(s) and tubesheet(s) wherein the case allows the hollow fibers to expand and contract without substantial damage to the fibers, wherein there is substantial void volume within the case external to the hollow fiber bundle(s) which is nonuniformly distributed.
Claim 2
Dependent Claim
212 words
A hollow fiber membrane device comprised of: (1) a plurality of non-woven hollow fiber membranes formed into at least one non-random bundle wherein the membranes are capable of separating at least one of the components from a liquid feed mixture; (2) at least one tubesheet comprised of a thermoplastic or thermoset material wherein the end(s) of the hollow fiber bundle(s) are embedded in the tubesheet(s); (3) at least one core wherein at least one non-woven hollow fiber bundle is wrapped in a spiral fashion about at least one core in such a manner that the non-woven hollow fiber bundle(s) is first formed and then wrapped spirally about the core(s) as a completed bundle(s) such that the fibers comprising the bundle(s) may expand and contract without substantial damage to the fibers; (4) a means for introducing the feed into the membrane device; (5) a means for removing the non-permeate from the membrane device; (6) a means for removing the permeate from the membrane device; and (7) a case which contains the hollow fiber bundle(s), core(s) and tubesheet(s) wherein the case allows the hollow fibers to expand and contract without substantial damage to the fibers, wherein there is substantial void volume within the case external to the hollow fiber bundle(s) which is nonuniformly distributed.
Claim 3
Dependent Claim
26 words
The membrane device of claim 1 wherein the device is capable of accommodating longitudinal expansion of the hollow fiber bundle(s) of up to about 100 percent.
Claim 4
Dependent Claim
59 words
The membrane device of claim 2 wherein the minimum inner diameter of the case, ID min is defined by the equation: ##EQU4## wherein D is the core diameter, s is the maximum longitudinal swelling expressed as a fraction of the original fiber length, d' is the diameter of the bundle after radial swelling, and θ is the wrap angle.
Claim 5
Dependent Claim
20 words
The membrane device of claim 3 wherein the device is adapted with inlet and outlet means for a shellside fluid.
Claim 6
Dependent Claim
15 words
The membrane device of claim 4 wherein the device is further comprised of end plates.
Claim 7
Dependent Claim
13 words
The membrane device of claim 5 wherein the core is a perforated tube.
Claim 8
Dependent Claim
32 words
The membrane device of claim 5 wherein the fiber bundle is wrapped in a spiral fashion about the core and passes through an aperture in the core to form a U-shaped configuration.
Claim 9
Dependent Claim
16 words
The membrane device of claim 5 wherein the device is comprised of two or more tubesheets.
Claim 10
Dependent Claim
17 words
The membrane device of claim 8 wherein the device is comprised of two or more fiber bundles.
Claim 11
Dependent Claim
24 words
The membrane device of claim 5 wherein the core is from about 15 to about 90 percent of the length of the hollow fibers.
Claim 12
Dependent Claim
20 words
The membrane device of claim 10 wherein each hollow fiber bundle contains between about 5 and 30,000 hollow fibers each.
Claim 13
Dependent Claim
21 words
The membrane device of claim 11 wherein the hollow fibers have a wall thickness of between about 20 and 200 microns.
Claim 14
Dependent Claim
22 words
The membrane device of claim 12 wherein the hollow fibers have an outer dimension of from about 100 to about 1000 microns.
Claim 15
Dependent Claim
44 words
The membrane device of claim 13 wherein the hollow fiber membranes are comprised of carboxy methyl cellulose; polyvinyl alcohol; sulfonated polyurea and salts thereof; aromatic polyamide; natural or synthetic rubbers including butyl or silicone rubber; or a perfluorosulfonic acid polymer or metal salt thereof.
Claim 16
Dependent Claim
114 words
The membrane device of claim 14 wherein the membrane is comprised of a polymer of perfluorosulfonic acid or metal salt thereof and is comprised of units which correspond to the formula ##STR3## wherein R 1 is independently in each occurrence fluorine or a C 1-10 perfluoroalkyl group; R 2 is independently in each occurrence fluorine or a C 1-10 perfluoroalkyl group; X is hydrogen or a metal; z is an integer of from about 0 to about 6; m is a positive real number of from about 5 to about 15; p is an integer of from about 0 to about 16; and q is an integer of from about 1 to about 16.
Claim 17
Dependent Claim
26 words
The membrane device of claim 15 wherein the tubesheet is comprised of a polyglycidyl ether of a polyhydric phenol, or resin thereof, and a curing agent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-02-19 | 1993-08-21 | 1994-02-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-02-19 | 1997-08-21 | 1998-02-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-02-19 | 2001-08-21 | 2002-02-20 | $7700.00 | Window Closed / Lapsed |