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US4895975A Expired / Lapsed US ⏱️ 0.0 years remaining

Diacetylene compound and process for production of polymer containing diacetylene groups from the diacetylene compound

Assignee: National Institute of Advanced Industrial Science and Technology
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Filing: 1988-03-09
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Granted: 1990-01-23
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Expires: 2008-03-09
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Abstract

Abstract A diacetylene compound of the formula: <IMAGE> (I) wherein X is a hydroxyl group, a halogen atom, an alkoxy group, a monovalent hydrocarbon group having from 1 to 20 carbon atoms or a -OM group wherein M is an alkali metal, and each of Y1 and Y2 which may be the same or different is a hydrogen atom, a monovalent organic group having from 1 to 20 carbon atoms or a halogen atom. Further described a process for producing a polymer containing diacetylene group in its main chain using a diacetylene compound of the above.

Inventors

  • 👤 Eisuke Fujiwara

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 16:48
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C07; C07C; C07C49/00; C07C49/76; C07C49/794; C07C49/796; C07C49/80; C07C49/813; C07C63/00; C07C63/66; C07C63/68; C07C63/74; C08G63/00; C08G63/02; C08G63/12; C08G63/52; C08G63/54

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 63 words
A diacetylene compound of the formula: ##STR31## wherein X is hydroxyl, halogen, alkoxy, a monavalent hydrocarbon having from 1 to 20 carbon atoms or a --OM group wherein M is an alkali metal, and each of Y 1 and Y 2 , which are the same or different, is hydrogen, a monavalent organic group having from 1 to 20 carbon atoms or halogen.
Claim 2
Dependent Claim 63 words
A diacetylene compound of the formula: ##STR31## wherein X is hydroxyl, halogen, alkoxy, a monavalent hydrocarbon having from 1 to 20 carbon atoms or a --OM group wherein M is an alkali metal, and each of Y 1 and Y 2 , which are the same or different, is hydrogen, a monavalent organic group having from 1 to 20 carbon atoms or halogen.
Claim 3
Dependent Claim 33 words
The diacetylene compound according to claim 1, wherein X is a hydroxyl group, a halogen atom, an alkoxy group having from 1 to 6 carbon atoms, a --ONa group or a --OK group.
Claim 4
Dependent Claim 17 words
The diacetylene compound according to claim 1, wherein X is a hydroxyl group or a halogen atom.
Claim 5
Dependent Claim 15 words
The diacetylene compound according to claim 3, wherein the halogen atom is Cl or Br.
Claim 6
Dependent Claim 19 words
The diacetylene compound according to claim 1, wherein each of Y 1 and Y 2 is a hydrogen atom.
Claim 7
Dependent Claim 28 words
The diacetylene compound according to claim 1, which has the formula: ##STR32## wherein X, Y 1 and Y 2 are as defined with respect to the formula I.
Claim 8
Dependent Claim 51 words
The diacetylene compound according to claim 1, which is a coupling reaction product of an ehtynyl compound of the formula: ##STR33## wherein X is as defined with respect to the formula I and Y is the same as Y 1 or Y 2 as defined with respect to the formula I.
Claim 9
Dependent Claim 65 words
The diacetylene compound according to claim 1, wherein said diacetylene compound is a member selected from the group consisting of 1,4-bis(4-methoxycarbonylphenyl)-butadiyne, 1,4-bis(4-ethoxycarbonylphenyl)-butadiyne, 1,4-bis(4-butoxycarbonylphenyl)-butadiyne, 1,4-bis(4-phenoxycarbonylphenyl)-butadiyne, 1,4-bis(4-benzyloxyphenyl)-butadiyne, 1,4-bis(3-methoxycarbonylphenyl)-butadiyne, 1,4-bis(3-ethyoxylcarbonylphenyl)-butadiyne, 1,4-bis(3-phenoxycarbonylphenyl)-butadiyne, 1,4-bis(3-methyl-4-methoxycarbonylphenyl)-butadiyne, 1,4-bis(3-methyl-4-ethoxycarbonylphenyl)-butadiyne, 1,4-bis(3-chloro-4-methoxycarbonylphenyl)-butadiyne, 1,4-bis(3-chloro-4-ethoxycarbonylphenyl)-butadiyne, 1,4-bis(4-methlycarbonylphenyl)-butadiyne, 1,4-bis(4-ethylcarbonylphenyl)-butadiyne, 1,4-bis(4-phenylcarbonylphenyl)-butadiyne, 1,4-bis(3-methylcarbonylphenyl)-butadiyne, 1,4-bis(3-ethylcarbonylphenyl)-butadiyne, 1,4-bis(3-methyl-4-methylcarbonylphenyl)-butadiyne, 1,4-bis(2-methyl-4-methylcarbonylphenyl)-butadiyne, 1,4-bis(3-methyl-5-methylcarbonylphenyl)-butadiyne, 1,4-bis(3-chloro-4-ethylcarbonylphenyl)-butadiyne, 1,4-bis(3-chloro-5-ethylcarbonylphenyl)-butadiyne, 1,4-bis(4-hydroxycarbonylphenyl)-butadiyne, 1,4-bis(3-hydroxycarbonylphenyl)-butadiyne, 1,4-bis(3-methyl-4-hydroxycarbonylphenyl)-butadiyne, 1,4-bis(3-ethyl-4-hydroxycarbonylphenyl)-butadiyne, 1,4-bis(3-methyl-5-hydroxycarbonylphenyl)-butadiyne, 1,4-bis(2-ethyl-5- hydroxycarbonylphenyl)-butadiyne, 1,4-bis(3-chloro-4-hydroxycarbonylphenyl)-butadiyne, 1,4-bis(3-chloro-5-hydroxycarbonylphenyl)-butadiyne, 1,4-bis(2-chloro-4-hydroxycarbonylphenyl)-butadiyne, 1,4-bis(2-chloro-3-hydroxycarbonylphenyl)-butadiyne, 1,4-bis(4sodiumoxycarbonylphenyl)-butadiyne, 1,4-bis(3-sodiumoxycarbonylphenyl)-butadiyne, 1,4-bis(4-potassiumoxycarbonylphenyl)-butadiyne, 1,4-bis(4-chloroformylphenyl)-butadiyne, 1,4-bis(3-chloroformylphenyl-butadiyne, 1,4-bis(3-methyl-4-chloroformylphenyl)-butadiyne, 1,4-bis(2-methyl-4-chloroformylphenyl)-butadiyne, 1,4-bis(3-chloro-4-chloroformylphenyl)-butadiyne, 1,4-bis(3-chloro-5-chloroformylphenyl)-butadiyne, 1,4-bis(4-bromoformylphenyl)-butadiyne, and 1,4-bis(3-bromoformylphenyl)-butadiyne.
Claim 10
Dependent Claim 44 words
A diacetylene compound of the formula: ##STR34## wherein X is hydroxyl, halogen, or alkoxy and each of Y 1 and Y 2 , which are the same or different, is hydrogen, a monovalent organic group having from 1 to 20 carbon atoms or halogen.
Claim 11
Dependent Claim 44 words
A diacetylene compound of the formula: ##STR34## wherein X is hydroxyl, halogen, or alkoxy and each of Y 1 and Y 2 , which are the same or different, is hydrogen, a monovalent organic group having from 1 to 20 carbon atoms or halogen.

References Cited (Backward Citations)

US4657708A Cited

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