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US4895465A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermal transfer ribbon especially for impressions on rough paper

Assignee: Pelikan Produktions AG
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Filing: 1987-10-15
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Granted: 1990-01-23
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Expires: 2007-10-15
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Abstract

Abstract A thermocarbon ribbon is formed by emulsifying two mutually incompatible thermoplastic polymers melting at heat-transfer temperatures of a wax. The emulsion containing a pigment is applied to a ribbon support and the solvent is evaporated. The ribbon has multi-strike capabilities and improved sharpness of transfer to rough paper resulting from the presence in the solid continuous phase of beads or microspheres of a dispersed phase, both phases being formed by the polymers.

Inventors

  • 👤 Norbert Mecke
  • 👤 Heinrich Krauter

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 05:23
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/382; B41M5/38207; B41J; B41J31/00; Y; Y10; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249994; Y10T428/249995; Y10T428/249996

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 91 words
A thermal-transfer ribbon, comprising: a support strip; and a thermally transferable image-transfer layer on said support strip comprising a solid continuous phase in which a pigment is dispersed, a pigment-containing discontinuous phase consisting of solid beads of a polymer meltable during the thermal-transfer process and distributed in said continuous phase, said solid continuous phase being formed by at least in part a polymer different from and mutually incompatible with the polymer of said beads, and a wax substance selected from the group which consists of a wax and a waxlike material.
Claim 2
Dependent Claim 91 words
A thermal-transfer ribbon, comprising: a support strip; and a thermally transferable image-transfer layer on said support strip comprising a solid continuous phase in which a pigment is dispersed, a pigment-containing discontinuous phase consisting of solid beads of a polymer meltable during the thermal-transfer process and distributed in said continuous phase, said solid continuous phase being formed by at least in part a polymer different from and mutually incompatible with the polymer of said beads, and a wax substance selected from the group which consists of a wax and a waxlike material.
Claim 3
Dependent Claim 14 words
The thermal-transfer ribbon defined in claim 1 wherein said substance is an ester wax.
Claim 4
Dependent Claim 28 words
The thermal-transfer ribbon defined in claim 1 wherein the polymer of said beads is at least one polymer selected from the group consisting of polystyrenes, polyacrylates and polyamides.
Claim 5
Dependent Claim 33 words
The thermal-transfer ribbon defined in claim 1 wherein said polymer forming said solid continuous phase is at least one polymer selected from the group which consists of polyethylenevinylacetate, a polyvinylether and a polyvinylester.
Claim 6
Independent Claim 135 words
A method of making a thermal-transfer ribbon which comprises the steps of: forming a solution in a vaporizable solvent of two different mutually incompatible thermoplastic polymers which are meltable during a thermal transfer process to form a two-phase liquid/liquid phase-separation system in the solution; adding to said two-phase liquid/liquid phase-separation system with stirring at least one pigment and a wax to form a color emulsion in said solvent; coating said color emulsion onto a support strip; and evaporating said solvent from said color emulsion on said support strip to form a thermally transferrable image-transfer layer on said support strip comprising a solid continuous phase of one of said polymers in which said pigment is dispersed, and a pigment-containing discontinuous phase consisting of solid beads of the other of said polymers distributed in said continuous phase.
Claim 7
Independent Claim 135 words
A method of making a thermal-transfer ribbon which comprises the steps of: forming a solution in a vaporizable solvent of two different mutually incompatible thermoplastic polymers which are meltable during a thermal transfer process to form a two-phase liquid/liquid phase-separation system in the solution; adding to said two-phase liquid/liquid phase-separation system with stirring at least one pigment and a wax to form a color emulsion in said solvent; coating said color emulsion onto a support strip; and evaporating said solvent from said color emulsion on said support strip to form a thermally transferrable image-transfer layer on said support strip comprising a solid continuous phase of one of said polymers in which said pigment is dispersed, and a pigment-containing discontinuous phase consisting of solid beads of the other of said polymers distributed in said continuous phase.
Claim 8
Dependent Claim 13 words
The method defined in claim 5 wherein said wax is an ester wax.
Claim 9
Dependent Claim 13 words
The method defined in claim 5 wherein said solvent is an aromatic hydrocarbon.
Claim 10
Dependent Claim 11 words
The method defined in claim 7 wherein said solvent is toluol.
Claim 11
Dependent Claim 30 words
The method defined in claim 7 wherein said one of said polymers is at least one polymer selected from the group which consists of polyethylenevinylacetate, a polyvinylether and a polyvinylester.
Claim 12
Dependent Claim 27 words
The method defined in claim 7 wherein said other of said polymers is at least one polymer selected from the group consisting of polystyrenes, polyacrylates and polyamides.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-01-22 1993-07-24 1994-01-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-01-22 1997-07-24 1998-01-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-01-22 2001-07-24 2002-01-23 $7700.00 Window Closed / Lapsed

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