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US4894402A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyphenylene compositions having improved melt behavior and impact

Assignee: General Electric Co
•
Filing: 1987-04-30
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Granted: 1990-01-16
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Expires: 2007-04-30
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Abstract

Abstract Impact-improved polyphenylene ether resin compositions which also exhibit improved melt behavior without degradation of other themal properties are provided by combining a polyphenylene ether polymer, an alkyl or aralkyl sulfonate of an alkali metal, where the alkyl or aralkyl radical has 5 to 25 carbon atoms, and an acrylate-styrene-acrylonitrile terpolymer.

Inventors

  • 👤 Visvaldis Abolins
  • 👤 Joseph C. Golba, Jr.
  • 👤 Thomas A. Morelli

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 19:30
CPC Classifications
C; C08; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123; C08K; C08K5/00; C08K5/36; C08K5/41; C08K5/42; Y; Y10; Y10S; Y10S525/00; Y10S525/905

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 89 words
A thermoplastic composition having improved impact strength and melt behavior consisting essentially of: (a) a polyphenylene ether resin having an intrinsic viscosity less than approximately, 0.42 dl/g as measured in chloroform at 25° C.; (b) a compound of the formula R-SO 3 X wherein R represents an alkyl or aralkyl radical having 5 to 25 carbon atoms and X represents an alkali metal ion, in an amount effective for improving the melt behavior of said polyphenylene ether resin; and (c) an impact strength improving amount of an acrylate-styrene-acrylonitrile terpolymer.
Claim 2
Dependent Claim 89 words
A thermoplastic composition having improved impact strength and melt behavior consisting essentially of: (a) a polyphenylene ether resin having an intrinsic viscosity less than approximately, 0.42 dl/g as measured in chloroform at 25° C.; (b) a compound of the formula R-SO 3 X wherein R represents an alkyl or aralkyl radical having 5 to 25 carbon atoms and X represents an alkali metal ion, in an amount effective for improving the melt behavior of said polyphenylene ether resin; and (c) an impact strength improving amount of an acrylate-styrene-acrylonitrile terpolymer.
Claim 3
Dependent Claim 35 words
A composition as in claim 1 wherein the compound of formula R-SO 3 X is present in an amount of, approximately, 0.5 to 5.0 parts by weight per 100 parts of the polyphenylene ether resin.
Claim 4
Dependent Claim 26 words
A composition as in claim 1 wherein the acrylate-styrene-acrylonitrile terpolymer is present in an amount of, approximately, 1 to 20 parts of the polyphenylene ether resin.
Claim 5
Dependent Claim 40 words
A composition as in claim 1 wherein the acrylate-styrene-acrylonitrile terpolymer is comprised of, approximately, 5 to 50 weight percent of at least one crosslinked acrylate, 5 to 35 weight percent crosslinked styrene-acrylonitrile, and 15 to 90 weight percent uncrosslinked styrene-acrylonitrile.
Claim 6
Dependent Claim 34 words
A composition as in claim 1 wherein the compound of formula R--SO 3 X is a mixture of compounds having said formula and R represents alkyl radicals independently having 12 to 20 carbon atoms.
Claim 7
Dependent Claim 18 words
A composition as in claim 1 wherein in the formula R--SO 3 X, X represents a sodium ion.
Claim 8
Dependent Claim 16 words
A composition as in claim 1 wherein the polyphenylene ether is a homopolymer or a copolymer.
Claim 9
Dependent Claim 12 words
A composition as in claim 7 wherein the polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene)ether.
Claim 10
Dependent Claim 20 words
A composition as in claim 1 wherein the polyphenylene ether has an intrinsic viscosity of approximately, 0.38 to 0.42 dl/g.
Claim 11
Dependent Claim 11 words
A molded article comprised of the thermoplastic composition of claim 1.

References Cited (Backward Citations)

US4128602A Cited
US4128602B1 Cited
US3944631A Cited
US4360618A Cited
US4529761A Cited
US4551494A Cited
NL8204761A Cited
US4681906A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-01-15 1993-07-17 1994-01-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-01-15 1997-07-17 1998-01-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-01-15 2001-07-17 2002-01-16 $7700.00 Window Closed / Lapsed

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