Light-stabilized polymer microparticles containing epoxy groups

Claim 2

Light-stabilized polymer microparticles having a particle size distribution of 0.01-20 μm, obtainable by copolymerization of (a) one or more ethylenically unsaturated monomeric compounds or/and one or more different monomers selected from the group comprising polyalcohols, polycarboxylic acids, hydroxycarboxylic acids, lactones, aminocarboxylic acids, aminoalcohols and polyamines, and (b) at least one epoxide compound which contains at least one further reactive group, essentially only the latter taking part in the copolymerization, so that the resulting microparticles contain free epoxy groups, which microparticles contain 0.1 to 30% by weight, relative to the monomers employed, of one or more light stabilizers, wherein at least part of the polymerization of the monomers is carried out in the presence of the light stabilizer.

Claim 3

Microparticles according to claim 1, wherein the light stabilizers have at least one reactive group for chemical bonding to the polymer.

Claim 4

Microparticles according to claim 2, wherein the reactive group is a hydroxyl, carboxyl, ester, amide or epoxy group or an ethylenic double bond.

Claim 5

Microparticles according to claim 1, wherein at least one compound from the group comprising sterically hindered amines is used as the light stabilizer.

Claim 6

Microparticles according to claim 4, wherein the light stabilizer used is a 2,2,6,6-tetraalkylpiperidine derivative which contains in its molecule at least one group of the formula I ##STR50## in which R is hydrogen or methyl.

Claim 7

Microparticles according to claim 1, wherein the light stabilizer is a UV absorber.

Claim 8

Microparticles according to claim 1, wherein a UV absorber and a sterically hindered amine are used as the light stabilizers.

Claim 9

Microparticles according to claim 7, wherein the UV absorber belongs to the class of 2-(2-hydroxyphenyl)-benzotriazoles.

Claim 10

Microparticles according to claim 1, wherein the polymer is an addition polymer.

Claim 11

Microparticles according to claim 9, wherein component (a) contains at least one ethylenically unsaturated compound and component (b) is an epoxide which contains at least one ethylenically unsaturated group.

Claim 12

Microparticles according to claim 1, which comprise a crosslinked core and assentially linear to slightly branched polymer chains polymerized thereon, the light stabilizers being contained in the core or/and in the polymer chains.

Claim 13

Microparticles according to claim 12, wherein the free epoxy groups are in the core, in the polymer chains polymerized thereon or in the core and in the polymer chains.

Claim 14

A process for the preparation of light-stabilized polymer microparticles having a particle size distribution of 0.01-20 μm, which comprises (a) copolymerizing one or several different ethylenically monounsaturated or polyunsaturated monomeric compounds or/and one or several different monomers from the group comprising polyalcohols, polycarboxylic acids, hydroxycarboxylic acids, lactones, aminocarboxylic acids, aminoalcohols and polyamines with (b) at least one epoxide compound which contains at least one further reactive group, in the presence of 0.1 to 30% by weight, relative to the monomers, of one or more light stabilizers in such a way that substantially only the said further reactive groups of the epoxide compound participates in the polymerization, so that the resulting microparticles contain free epoxy groups, and that at least a part of the resulting polymer is crosslinked, and, if the polymerization is carried out in several steps, at least one polymerization step taking place in the presence of the light stabilizers.

Claim 15

A process for the preparation of light-stabilized polymer microparticles having a particle size distribution of 0.01-20 μm, which comprises (a) copolymerizing one or several different ethylenically monounsaturated or polyunsaturated monomeric compounds or/and one or several different monomers from the group comprising polyalcohols, polycarboxylic acids, hydroxycarboxylic acids, lactones, aminocarboxylic acids, aminoalcohols and polyamines with (b) at least one epoxide compound which contains at least one further reactive group, in the presence of 0.1 to 30% by weight, relative to the monomers, of one or more light stabilizers in such a way that substantially only the said further reactive groups of the epoxide compound participates in the polymerization, so that the resulting microparticles contain free epoxy groups, and that at least a part of the resulting polymer is crosslinked, and, if the polymerization is carried out in several steps, at least one polymerization step taking place in the presence of the light stabilizers.

Claim 16

A process according to claim 13, which comprises (a 1 ) copolymerizing one or several different ethylenically monounsaturated or polyunsaturated monomeric compounds or/and one or several different monomers from the group comprising polyalcohols, polycarboxylic acids, hydroxycarboxylic acids and lactones with at least one epoxide compound, which contains at least one further reactive group, with crosslinking in such a way that substantially only the said further reactive groups of the epoxide compound participates in the polymerization, so that free epoxy groups remain, (b 1 ) polymerizing one or more of the monomers mentioned under (a 1 ) to give a substantially linear to branched polymer, which polymerization can also take place in the absence of the epoxide compound, and (c 1 ) polymerizing (grafting) the polymer obtained according to (b 1 ) onto the polymer obtained according to (a 1 ), the polymerization according to (a 1 ) or according to (b 1 ) or both polymerizations being carried out in the presence of one or more light stabilizers, it being possible for the light stabilizers in the two polymerization steps to be identical or different, and the total quantity of light stabilizer being 0.1 to 30% by weight, relative to the monomers in both polymerization steps, it being possible for the polymerization (a 1 ) to take place wholly or partially in the presence of the polymer formed according to (b 1 ).

Claim 17

A process according to claim 13, which comprises (a 1 ) polymerizing one or several different ethylenically monounsaturated or polyunsaturated monomeric compounds or/and one or more different monomers from the group comprising polyalcohols, polycarboxylic acids, hydroxycarboxylic acids and lactones with crosslinking, (b 1 ) copolymerizing one or more of the monomers indicated under (a 1 ) with at least one epoxide compound, which contains at least one further reactive group, to give a substantially linear to branched polymer in such a way that substantially only the said further reactive groups of the epoxide compound participates in the polymerization, so that free epoxy groups remain, and (c 1 ) polymerizing (grafting) the polymer obtained according to (b 1 ) onto the polymer obtained according to (a 1 ), the polymerization according to (a 1 ) or according to (b 1 ) or both polymerizations being carried out in the presence of one or more light stabilizers, and it being possible for the light stabilizers in the two polymerization steps to be identical or different and the total quantity of light stabilizer being 0.1 to 30% by weight, relative to the monomers, in both polymerization steps, and it being possible for the polymerization (a 1 ) to take place wholly or partially in the presence of the polymer formed according to (b 1 ).

Claim 18

A dispersion, containing light-stabilized polymer microparticles according to claim 1 and at least one solvent in which the polymer microparticles are substantially insoluble.

Claim 19

A dispersion according to claim 16 which, as the solvent, contains water or an aliphatic, cycloaliphatic or aromatic hydrocarbon or mixtures of these solvents.

Claim 20

A coating composition, wherein the film-forming material comprises (a) 1 to 95% by volume of a disperse phase which contains microparticles according to claim 1, and (b) 99 to 5% by volume of a liquid continuous phase which has a viscosity of 0.1 to 30 poise at room temperature and is capable of curing together with the disperse phase to give a film-forming polymer, the total volume of (a) and (b) being 100% and the disperse phase participating in curing the coating.

Claim 21

A coating composition according to claim 18, wherein the film-forming material comprises (a) 5-85% by volume of the disperse phase containing at least 50% by volume of microparticle according to the invention, and (b) 95-15% by volume of the liquid continuous phase having a viscosity of 0.1 to 20 poise at room temperature.

Claim 22

A coating composition according to claim 19, wherein the continuous phase (b) also contains one or more light stabilizers.

Claim 23

A coating composition according to claim 18, wherein the liquid continuous phase (b) contains a thermosetting resin.

Claim 24

A coating composition according to claim 21, wherein the resin is a crosslinkable acrylic resin, polyester/alkyd resin or polyurethane resin, which may be crosslinked with aminoplasts, polyisocyanate or polyepoxides.

Claim 25

A coating composition according to claim 18, wherein the liquid continuous phase (b) contains a reactive diluent which is itself not curable but contains reactive groups, by means of which it can participate in the curing of the film-forming material.