US4894290A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Coated glass
Assignee: Pilkington Group Ltd
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Filing: 1988-01-13
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Granted: 1990-01-16
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Expires: 2008-01-13
Abstract
Abstract Bent and/or toughened silver coated glass having light transmission is produced by depositing layers of additional metal over, or both under and over, the silver layer. When the additional metal is used over the silver layer, it is selected from aluminium, titanium, zinc and tantalum. When the additional metal is used both under and over the silver, it is selected from aluminium, titanium, zinc, tantalum and zirconium. The additional metal is used in an amount such that the light transmission of the coated glass increases on bending and/or toughening. The bent and/or toughened coated glass is useful for architectural glazing and as vehicle windows.
Inventors
- 👤 Peter Chesworth
- 👤 Martin Lowe
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 10:42
CPC Classifications
C; C03; C03C; C03C21/00; C03C17/00; C03C17/34; C03C17/36; C03C17/3602; C03C17/3615; B; B32; B32B; B32B17/00; B32B17/06; B32B17/10; B32B17/10005; B32B17/10165; B32B17/10174; C03C17/3618; C03C17/3644; C03C17/3647; C03C17/3652; C03C17/3681; C03C17/3689
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
138 words
A coated glass substrate with a coating comprising a layer of additional metal selected from aluminum, titanium, zinc, tantalum and zirconium, a silver layer from 5 nm to 30 nm thick over the layer of additional metal, a further layer of additional metal selected from aluminum, titanium, zinc, tantalum and zirconium over the silver layer, and an anti-reflection metal oxide layer over said further layer of additional metal which coated glass substrate, when subjected to a bending and/or toughening cycle in which the glass is heated in air to a temperature above the softening temperature of the glass, develops an increased light transmission, with the thickness of any anti-reflection metal oxide layer overlying the silver layer plus the thickness of the oxidised additional metal over the silver being in the range of from 10 nm to 80 nm.
Claim 2
Dependent Claim
138 words
A coated glass substrate with a coating comprising a layer of additional metal selected from aluminum, titanium, zinc, tantalum and zirconium, a silver layer from 5 nm to 30 nm thick over the layer of additional metal, a further layer of additional metal selected from aluminum, titanium, zinc, tantalum and zirconium over the silver layer, and an anti-reflection metal oxide layer over said further layer of additional metal which coated glass substrate, when subjected to a bending and/or toughening cycle in which the glass is heated in air to a temperature above the softening temperature of the glass, develops an increased light transmission, with the thickness of any anti-reflection metal oxide layer overlying the silver layer plus the thickness of the oxidised additional metal over the silver being in the range of from 10 nm to 80 nm.
Claim 3
Dependent Claim
24 words
A coated glass substrate according to claim 1 which develops an increased light transmission of at least 70% during the bending and/or toughening cycle.
Claim 4
Dependent Claim
32 words
A coated glass substrate according to claim 1 which develops an increased light transmission of at least 80% of the light transmission of the base glass during the bending and/or toughening cycle.
Claim 5
Dependent Claim
40 words
A coated glass substrate according to claim 1 wherein the total amount of additional metal is such that the light transmission of the coated glass increases by at least 10% of its original value on bending and/or toughening in air.
Claim 6
Dependent Claim
35 words
A coated glass substrate according to claim 1 wherein the total amount of additional metal is sufficient to provide a metal layer having a thickness in the range of from 4 nm to 15 nm.
Claim 7
Dependent Claim
23 words
A coated glass substrate according to claim 1 wherein the additional metal in each layer of additional metal is aluminium, zinc or titanium.
Claim 8
Dependent Claim
29 words
A coated glass substrate according to claim 6 wherein the additional metal is aluminium in a total amount equivalent to a layer from 5 nm to 10 nm thick.
Claim 9
Dependent Claim
28 words
A coated glass substrate according to claim 1 wherein the coating additionally comprises an anti-reflection layer or layers of metal oxide between the glass and the silver layer.
Claim 10
Dependent Claim
31 words
A coated glass substrate according to claim 8 wherein the total thickness of any metal oxide layers between the glass and the silver layer is from 20 nm to 60 nm.
Claim 11
Dependent Claim
149 words
A bent and/or toughened silver-coated glass substrate having a light transmission of at least 80% of that of the uncoated glass the coating being deposited directly on the glass substrate and comprising an anti-reflection metal oxide layer, an oxidised layer of metal selected from aluminum, titanium, tantalum and zirconium over the anti-reflection layer, a silver layer from 5 nm to 30 nm thick over said oxidised metal layer, a further oxidised layer of metal selected from aluminum, titanium, tantalum and zirconium over said silver layer, and an overlying anti-reflection metal oxide layer, the said two layers of oxidised metal having a combined total thickness in the range of from 8 nm to 30 nm, and the thickness of any anti-reflection metal oxide layer overlying the silver layer plus the thickness of the oxidised additional metal over the silver being in the range of from 10 nm to 80 nm.
Claim 12
Dependent Claim
149 words
A bent and/or toughened silver-coated glass substrate having a light transmission of at least 80% of that of the uncoated glass the coating being deposited directly on the glass substrate and comprising an anti-reflection metal oxide layer, an oxidised layer of metal selected from aluminum, titanium, tantalum and zirconium over the anti-reflection layer, a silver layer from 5 nm to 30 nm thick over said oxidised metal layer, a further oxidised layer of metal selected from aluminum, titanium, tantalum and zirconium over said silver layer, and an overlying anti-reflection metal oxide layer, the said two layers of oxidised metal having a combined total thickness in the range of from 8 nm to 30 nm, and the thickness of any anti-reflection metal oxide layer overlying the silver layer plus the thickness of the oxidised additional metal over the silver being in the range of from 10 nm to 80 nm.
Claim 13
Dependent Claim
34 words
A bent and/or toughened silver-coated glass substrate according to claim 10 wherein each of the said two oxidised layers of metal has a thickness in the range of from 4 nm to 15 nm.
Claim 14
Dependent Claim
122 words
A bent and/or toughened silver-coated glass substrate having a light transmission of at least 80% of the uncoated glass, the coating being deposited directly on the glass substrate and comprising an anti-reflection metal oxide layer, a silver layer from 5 nm to 30 nm thick over said anti-reflection layer, and an oxidised layer of titanium or tantalum over said silver layer, and an overlying anti-reflection metal oxide layer, the said layer of oxidised metal having a thickness in the range of from 8 nm to 30 nm, and the thickness of any anti-reflection metal oxide layer overlying the silver layer plus the thickness of the oxidised additional metal over the silver being in the range of from 10 nm to 80 nm.
Claim 15
Dependent Claim
122 words
A bent and/or toughened silver-coated glass substrate having a light transmission of at least 80% of the uncoated glass, the coating being deposited directly on the glass substrate and comprising an anti-reflection metal oxide layer, a silver layer from 5 nm to 30 nm thick over said anti-reflection layer, and an oxidised layer of titanium or tantalum over said silver layer, and an overlying anti-reflection metal oxide layer, the said layer of oxidised metal having a thickness in the range of from 8 nm to 30 nm, and the thickness of any anti-reflection metal oxide layer overlying the silver layer plus the thickness of the oxidised additional metal over the silver being in the range of from 10 nm to 80 nm.
Claim 16
Dependent Claim
19 words
A bent and/or toughened silver-coated glass substrate according to claim 12 having a light transmission of at least 70%.
Claim 17
Dependent Claim
93 words
A bent and/or toughened silver-coated glass substrate having a light transmission of at least 80% of the uncoated glass, the coating being deposited directly on the glass substrate and comprising an anti-reflection metal oxide layer, a silver layer from 5 nm to 30 nm thick over said anti-reflection metal oxide layer and an overlying anti-reflection metal oxide layer, with oxidised zinc distributed through all the layers of the coating, with the thickness of any anti-reflection metal oxide layer overlying the silver layer being in the range of from 10 nm to 80 nm.
Claim 18
Dependent Claim
93 words
A bent and/or toughened silver-coated glass substrate having a light transmission of at least 80% of the uncoated glass, the coating being deposited directly on the glass substrate and comprising an anti-reflection metal oxide layer, a silver layer from 5 nm to 30 nm thick over said anti-reflection metal oxide layer and an overlying anti-reflection metal oxide layer, with oxidised zinc distributed through all the layers of the coating, with the thickness of any anti-reflection metal oxide layer overlying the silver layer being in the range of from 10 nm to 80 nm.
Claim 19
Dependent Claim
30 words
A bent and/or toughened silver-coated glass according to claim 14 wherein the zinc is present in an amount equivalent to a layer of zinc 4 nm to 15 nm thick.
Claim 20
Dependent Claim
18 words
A bent and/or toughened silver-coated glass according to claim 14 having a light transmission of at least 70%.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-01-15 | 1993-07-17 | 1994-01-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-01-15 | 1997-07-17 | 1998-01-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-01-15 | 2001-07-17 | 2002-01-16 | $7700.00 | Window Closed / Lapsed |