US4894289A
Expired / Lapsed
US
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Laminate and molded article prepared therefrom
Assignee: Mitsui Chemicals Inc
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Filing: 1987-10-30
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Granted: 1990-01-16
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Expires: 2007-10-30
Abstract
Abstract A laminate comprising (a) a layer of a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a mixture of a peroxide-crosslinking olefin copolymer rubber and an olefinic plastic with an unsaturated carboxylic acid or derivative thereof, an unsaturated epoxy monomer or an unsaturated hydroxy monomer in the presence of an organic peroxide and (b) a layer of a polyamide, polyurethane or polyester is excellent in weatherability, heat resistance and dimension stability, and this laminate is effectively molded into an interior part or sealing material of an automobile, especially a glass run channel. The glass run channel molded from this laminate is excellent in the durability, the tightness of contact with glass at the time of closing and the sliding smoothness at the opening-closing operation.
Inventors
- 👤 Yasuhiko Otawa
- 👤 Kunihide Hiraoka
- 👤 Toshiyuki Maeda
- 👤 Katsuo Okamoto
- 👤 Noboru Sakamaki
- 👤 Shizuo Shimizu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 10:43
CPC Classifications
B; B32; B32B; B32B25/00; B32B25/04; B32B25/08; B32B25/14; B32B27/00; B32B27/34; B32B27/36; B32B27/40; B60; B60J; B60J10/00; B60J10/15; B60J10/17; B60J10/20; B60J10/27; B60J10/70; B60J10/74; B32B2270/00; B32B2307/00; B32B2307/30; B32B2307/306; B32B2307/70; B32B2307/712; B32B2307/732; B32B2307/734; B32B2605/00; B32B2605/08; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/2419; Y10T428/24198; Y10T428/29; Y10T428/2902; Y10T428/31504; Y10T428/31551; Y10T428/31573; Y10T428/31725; Y10T428/31739; Y10T428/31743; Y10T428/31786; Y10T428/31797
Claims Analysis
Total Claims: 30
Claim 1
Independent Claim
98 words
A laminate comprising a layer composed of (a) a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking olefin copolymer comprising olefin and non-conjugated diene, (ii) 0 to 90 parts by weight of an olefinic plastic, the sum of the amounts of the components (i) and (ii) being 100 parts by weight, and (iii) 0.01 to 10 parts by weight of an unsaturated carboxylic acid or derivative thereof, in the presence of an organic peroxide, and a layer of (b) a polyamide, polyurethane or polyester.
Claim 2
Dependent Claim
98 words
A laminate comprising a layer composed of (a) a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking olefin copolymer comprising olefin and non-conjugated diene, (ii) 0 to 90 parts by weight of an olefinic plastic, the sum of the amounts of the components (i) and (ii) being 100 parts by weight, and (iii) 0.01 to 10 parts by weight of an unsaturated carboxylic acid or derivative thereof, in the presence of an organic peroxide, and a layer of (b) a polyamide, polyurethane or polyester.
Claim 3
Dependent Claim
65 words
A laminate as set forth in claim 1, wherein said blend further comprises (iv) a peroxide-non-crosslinking rubbery substance, (v) a mineral oil softener, or both (iv) and (v), wherein the amount of (iv) when present is up to 100 parts by weight and the amount of (v) when present is up to 100 parts by weight, at least one of (iv) and (v) being present.
Claim 4
Dependent Claim
57 words
A laminate as set forth in claims 1 or 2, wherein the amount of the peroxide-crosslinking olefin copolymer (i) is 60 to 95 parts by weight and the amount of the olefinic plastic (ii) is 5 to 40 parts by weight, the sum of the amounts of the components (i) and (ii) being 100 parts by weight.
Claim 5
Dependent Claim
95 words
A laminate comprising a layer composed of (a) a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking olefin copolymer, (ii) 0 to 90 parts by weight of an olefinic plastic, the sum of the amounts of the components (i) and (ii) being 100 parts by weight, and (iii) 0.01 to 10 parts by weight of an unsaturated epoxy monomer or an unsaturated hydroxy monomer, in the presence of an organic peroxide, and a layer of (b) a polyamide, polyurethane or polyester.
Claim 6
Dependent Claim
95 words
A laminate comprising a layer composed of (a) a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking olefin copolymer, (ii) 0 to 90 parts by weight of an olefinic plastic, the sum of the amounts of the components (i) and (ii) being 100 parts by weight, and (iii) 0.01 to 10 parts by weight of an unsaturated epoxy monomer or an unsaturated hydroxy monomer, in the presence of an organic peroxide, and a layer of (b) a polyamide, polyurethane or polyester.
Claim 7
Dependent Claim
131 words
A laminate comprising (a) a layer composed of a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking olefin copolymer rubber, (ii) 0 to 90 parts by weight of an olefinic plastic, the sum of the amounts of the components (i) and (ii) being 100 parts by weight, and (iii) 0.01 to 10 parts by weight of at least one monomer selected from the group consisting of (1) an unsaturated carboxylic acid monomer and derivatives thereof, (2) an unsaturated epoxy monomer and (3) an unsaturated hydroxy monomer in the presence of an organic peroxide, said partially cross-linked graft-modified polyolefin elastomer having a gel content of 20 to 98% and (b) a layer of a polyamide, polyurethane or polyester.
Claim 8
Dependent Claim
131 words
A laminate comprising (a) a layer composed of a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking olefin copolymer rubber, (ii) 0 to 90 parts by weight of an olefinic plastic, the sum of the amounts of the components (i) and (ii) being 100 parts by weight, and (iii) 0.01 to 10 parts by weight of at least one monomer selected from the group consisting of (1) an unsaturated carboxylic acid monomer and derivatives thereof, (2) an unsaturated epoxy monomer and (3) an unsaturated hydroxy monomer in the presence of an organic peroxide, said partially cross-linked graft-modified polyolefin elastomer having a gel content of 20 to 98% and (b) a layer of a polyamide, polyurethane or polyester.
Claim 9
Dependent Claim
130 words
A laminate comprising (a) a layer composed of a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking ethylene/propylene/non-conjugated diene rubber having a Mooney viscosity ML 1+4 (100° C.) of 10 to 120, (ii) 0 to 90 parts by weight of isotactic polypropylene having a melt index of 0.1 to 50 as determined at 230° C. according to ASTM D-1238-65T, and (iii) 0.01 to 10 parts by weight of at least one monomer selected from the group consisting of (1) an unsaturated carboxylic acid monomer and a derivative thereof, (2) an unsaturated epoxy monomer and (3) an unsaturated hydroxyl monomer, in the presence of an organic peroxide, and (b) a layer of a polyamide, polyurethane or polyester.
Claim 10
Dependent Claim
130 words
A laminate comprising (a) a layer composed of a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking ethylene/propylene/non-conjugated diene rubber having a Mooney viscosity ML 1+4 (100° C.) of 10 to 120, (ii) 0 to 90 parts by weight of isotactic polypropylene having a melt index of 0.1 to 50 as determined at 230° C. according to ASTM D-1238-65T, and (iii) 0.01 to 10 parts by weight of at least one monomer selected from the group consisting of (1) an unsaturated carboxylic acid monomer and a derivative thereof, (2) an unsaturated epoxy monomer and (3) an unsaturated hydroxyl monomer, in the presence of an organic peroxide, and (b) a layer of a polyamide, polyurethane or polyester.
Claim 11
Dependent Claim
116 words
A laminate comprising (a) a layer composed of a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking ethylene/propylene/non-conjugated diene rubber having a Mooney viscosity ML 1+4 (100° C.) of 10 to 120, (ii) 0 to 90 parts by weight of isotactic polypropylene having a melt index of 0.1 to 50 as determined at 230° C. according to ASTM D-1238-65T, and (iii) 0.01 to 10 parts by weight of at least one monomer selected from the group consisting of maleic acid, bicyclo-(2,2,1)-hept-2-ene-5,6-dicarboxylic acid and anhydrides thereof, in the presence of an organic peroxide, and (b) a layer of a polyamide, polyurethane or polyester.
Claim 12
Dependent Claim
116 words
A laminate comprising (a) a layer composed of a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking ethylene/propylene/non-conjugated diene rubber having a Mooney viscosity ML 1+4 (100° C.) of 10 to 120, (ii) 0 to 90 parts by weight of isotactic polypropylene having a melt index of 0.1 to 50 as determined at 230° C. according to ASTM D-1238-65T, and (iii) 0.01 to 10 parts by weight of at least one monomer selected from the group consisting of maleic acid, bicyclo-(2,2,1)-hept-2-ene-5,6-dicarboxylic acid and anhydrides thereof, in the presence of an organic peroxide, and (b) a layer of a polyamide, polyurethane or polyester.
Claim 13
Dependent Claim
154 words
A laminate comprising (a) a layer composed of a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking ethylene/propylene/non-conjugated diene rubber having a Mooney viscosity ML 1+4 (100° C.) of 10 to 120, (ii) 0 to 90 parts by weight of isotactic polypropylene having a melt index of 0.1 to 50 as determined at 230° C. according to ASTM D-1238-65T, and (iii) 0.01 to 10 parts by weight of at least one unsaturated epoxy monomer selected from the group consisting of glycidyl esters of unsaturated monocarboxylic acids, monoglycidyl and diglydicyl esters of unsaturated polycarboxylic acids, unsaturated glycidyl ethers, 2-(o-vinylphenyl)-ethylene oxide, 2-(p-vinylphenyl)-ethylene oxide, 2-(o-vinylphenyl)-propylene oxide, 2-(p-vinylphenyl)-propylene oxide, 2-(o-allylphenyl-ethylene oxide, 2-(p-allylphenyl)-ethylene oxide, 2-(o-allylphenyl)-propylene oxide, 2-(p-allylphenyl)-propylene oxide, p-glycidylstyrene, 3,4-epoxy-1-butene, 3,4-epoxy-1-pentene, 3,4-epoxy-3-methyl-1-pentene, 5,6-epoxy-1-hexene, vinylcyclohexene mono-oxide and allyl-2,3-epoxycyclopentyl ether, in the presence of an organic peroxide, and (b) a layer of a polyamide, polyurethane or polyester.
Claim 14
Dependent Claim
154 words
A laminate comprising (a) a layer composed of a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking ethylene/propylene/non-conjugated diene rubber having a Mooney viscosity ML 1+4 (100° C.) of 10 to 120, (ii) 0 to 90 parts by weight of isotactic polypropylene having a melt index of 0.1 to 50 as determined at 230° C. according to ASTM D-1238-65T, and (iii) 0.01 to 10 parts by weight of at least one unsaturated epoxy monomer selected from the group consisting of glycidyl esters of unsaturated monocarboxylic acids, monoglycidyl and diglydicyl esters of unsaturated polycarboxylic acids, unsaturated glycidyl ethers, 2-(o-vinylphenyl)-ethylene oxide, 2-(p-vinylphenyl)-ethylene oxide, 2-(o-vinylphenyl)-propylene oxide, 2-(p-vinylphenyl)-propylene oxide, 2-(o-allylphenyl-ethylene oxide, 2-(p-allylphenyl)-ethylene oxide, 2-(o-allylphenyl)-propylene oxide, 2-(p-allylphenyl)-propylene oxide, p-glycidylstyrene, 3,4-epoxy-1-butene, 3,4-epoxy-1-pentene, 3,4-epoxy-3-methyl-1-pentene, 5,6-epoxy-1-hexene, vinylcyclohexene mono-oxide and allyl-2,3-epoxycyclopentyl ether, in the presence of an organic peroxide, and (b) a layer of a polyamide, polyurethane or polyester.
Claim 15
Dependent Claim
126 words
A laminate comprising (a) a layer composed of a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking ethylene/propylene/non-conjugated diene rubber having a Mooney viscosity ML 1+4 (100° C.) of 10 to 120, (ii) 0 to 90 parts by weight of isotactic polypropylene having a melt index of 0.1 to 50 as determined at 230° C. according to ASTM D-1238-65T, and (iii) 0.01 to 10 parts by weight of at least one unsaturated hydroxyl monomer selected from the group consisting of hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, hydroxypropyl methacrylate, polyethylene glycol monomethacrylate and polypropylene glycol monomethylacrylate, in the presence of an organic peroxide, and (b) a layer of a polyamide, polyurethane or polyester.
Claim 16
Dependent Claim
126 words
A laminate comprising (a) a layer composed of a partially crosslinked graft-modified polyolefin elastomer formed by dynamically heat-treating a blend comprising (i) 10 to 100 parts by weight of a peroxide-crosslinking ethylene/propylene/non-conjugated diene rubber having a Mooney viscosity ML 1+4 (100° C.) of 10 to 120, (ii) 0 to 90 parts by weight of isotactic polypropylene having a melt index of 0.1 to 50 as determined at 230° C. according to ASTM D-1238-65T, and (iii) 0.01 to 10 parts by weight of at least one unsaturated hydroxyl monomer selected from the group consisting of hydroxyethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, hydroxypropyl methacrylate, polyethylene glycol monomethacrylate and polypropylene glycol monomethylacrylate, in the presence of an organic peroxide, and (b) a layer of a polyamide, polyurethane or polyester.
Claim 17
Dependent Claim
65 words
A laminate as set forth in claim 4 wherein said blend further comprises (iv) a peroxide-non-crosslinking rubbery substance, (v) a mineral oil softener, or both (iv) and (v), wherein the amount of (iv) when present is up to 100 parts by weight and the amount of (v) when present is up to 100 parts by weight, at least one of (iv) and (v) being present.
Claim 18
Dependent Claim
57 words
A laminate as set forth in claims 4 or 10, wherein the amount of the peroxide-crosslinking olefin copolymer (i) is 60 to 95 parts by weight and the amount of the olefinic plastic (ii) is 5 to 40 parts by weight, the sum of the amounts of the components (i) and (ii) being 100 parts by weight.
Claim 19
Dependent Claim
65 words
A laminate as set forth in claim 5 wherein said blend further comprises (iv) a peroxide-non-crosslinking rubbery substance, (v) a mineral oil softener, or both (iv) and (v), wherein the amount of (iv) when present is up to 100 parts by weight and the amount of (v) when present is up to 100 parts by weight, at least one of (iv) and (v) being present.
Claim 20
Dependent Claim
58 words
A laminate as set forth in claims 5 or 12, wherein the amount of the peroxide-crosslinking olefin copolymer rubber (i) is 60 to 95 parts by weight and the amount of the olefinic plastic (ii) is 5 to 40 parts by weight, the sum of the amounts of the components (i) and (ii) being 100 parts by weight.
Claim 21
Dependent Claim
28 words
A laminate as set forth in claim 3 wherein the amount of the unsaturated carboxylic acid or derivative thereof (iii) is from 0.1 to 5 parts by weight.
Claim 22
Dependent Claim
29 words
A laminate as set forth in claim 4 wherein the amount of the unsaturated epoxy monomer or unsaturated hydroxy monomer (iii) is from 0.1 to 5 parts by weight.
Claim 23
Dependent Claim
23 words
A laminate as set forth in claim 5 wherein the amount of the monomer (iii) is from 0.1 to 5 parts by weight.
Claim 24
Dependent Claim
61 words
A laminate according to any one of claims 6, 7, 8 or 9 wherein said blend comprises from 60 to 90 parts by weight (i), from 5 to 40 parts by weight (ii), the sum of the amounts of (i) and (ii) being 100 parts by weight, and 0.1 to 5 parts by weight of said at least one monomer (iii).
Claim 25
Dependent Claim
66 words
A laminate as set forth in claim 3 wherein said blend further comprises (iv) a peroxide-non-crosslinking rubbery substance, (v) a mineral oil softener, or both (iv) and (v), wherein the amount of (iv) when present is from 5 to 50 parts by weight and the amount of (v) when present is 3 to 100 parts by weight, at least one of (iv) and (v) being present.
Claim 26
Dependent Claim
66 words
A laminate as set forth in claim 11 wherein said blend further comprises (iv) a peroxide-non-crosslinking rubbery substance, (v) a mineral oil softener, or both (iv) and (v), wherein the amount of (iv) when present is from 5 to 50 parts by weight and the amount of (v) when present is 3 to 100 parts by weight, at least one of (iv) and (v) being present.
Claim 27
Dependent Claim
66 words
A laminate as set forth in claim 13 wherein said blend further comprises (iv) a peroxide-non-crosslinking rubbery substance, (v) a mineral oil softener, or both (iv) and (v), wherein the amount of (iv) when present is from 5 to 50 parts by weight and the amount of (v) when present is 3 to 100 parts by weight, at least one of (iv) and (v) being present.
Claim 28
Dependent Claim
37 words
A laminate as set forth in any one of claims 1 or 4-9 wherein the thickness of layer (a) is from 0.1 to 50 millimeters and the thickness of layer (b) is from 3 to 50 microns.
Claim 29
Dependent Claim
19 words
A laminate as set forth in claim 1 wherein the peroxide-crosslinking olefin polymer (i) is an ethylene/propylene/non-conjugated diene rubber.
Claim 30
Dependent Claim
22 words
A laminate as set forth in claim 22 wherein the non-conjugated diene is dicyclopentadiene, 1,4-hexadiene, dicyclooctadiene, methylene-norbornene or 5-ethylidene-2-norbornene or mixtures thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-01-15 | 1993-07-17 | 1994-01-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-01-15 | 1997-07-17 | 1998-01-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-01-15 | 2001-07-17 | 2002-01-16 | $7700.00 | Window Closed / Lapsed |