US4892565A
Expired / Lapsed
US
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Adsorptive separation utilizing multiple adsorption beds
Assignee: Air Products and Chemicals Inc
•
Filing: 1988-12-16
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Granted: 1990-01-09
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Expires: 2008-12-16
Abstract
Abstract A process is described for recovery of a more selectively adsorbed key component from a gas mixture containing the key component and one or more less selectively adsorbed secondary components using vacuum swing adsorption. The process minimizes capital costs by reducing or eliminating gas storage vessels and reduces power requirements by operating without a feed compressor or elevated pressure feed, whereby feed is induced at least in part by vacuum conditions achieved by pressure equalization between parallel adsorption beds. Alternatively, at least a minor amount of less selectively adsorbed secondary component roduct can be recovered.
Inventors
- 👤 William P. Schmidt
- 👤 Ravi Kumar
- 👤 Alan D. Abel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 03:50
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/02; B01D53/04; B01D53/047; B01D53/0476; B01D2253/00; B01D2253/10; B01D2253/102; B01D2253/106; B01D2253/108; B01D2257/00; B01D2257/10; B01D2257/102; B01D2257/50; B01D2259/00; B01D2259/40; B01D2259/40011; B01D2259/40043; B01D2259/4005; B01D2259/40052; B01D2259/40058; B01D2259/40062; B01D2259/40064; B01D2259/403; B01D2259/404; Y; Y02; Y02C; Y02C20/00; Y02C20/40
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
235 words
A process for the production of high purity more selectively adsorbed key component from a gas mixture containing the key component and one or more less selectively adsorbed secondary components using a plurality of parallel adsorption beds which comprises: (a) drawing said gas mixture through the feed end of a first bed of adsorbent by connecting the effluent end of said bed to the effluent end of a parallel bed, which is presently evacuated, so as to selectively adsorb said key component on said first bed of adsorbent and allow said one or more secondary components to pass through said first bed; (b) cocurrently rinsing said first bed with high purity key component to remove any co-adsorbed secondary component and void space secondary component from said bed; (c) countercurrently desorbing said first bed by pressure reduction in one or more stages to a subatmospheric pressure to recover a rinse gas for another of said plurality of beds presently undergoing step (b) and a high purity key component product; (d) countercurrently repressurizing said first bed by connecting the effluent end of said first bed at its subatmospheric pressure at the end of step (c) with the effluent end of another of said plurality of beds presently undergoing the adsorption of step (a), and (e) continuing this series of steps with the plurality of beds to form a continuous process for production of high purity key component.
Claim 2
Dependent Claim
235 words
A process for the production of high purity more selectively adsorbed key component from a gas mixture containing the key component and one or more less selectively adsorbed secondary components using a plurality of parallel adsorption beds which comprises: (a) drawing said gas mixture through the feed end of a first bed of adsorbent by connecting the effluent end of said bed to the effluent end of a parallel bed, which is presently evacuated, so as to selectively adsorb said key component on said first bed of adsorbent and allow said one or more secondary components to pass through said first bed; (b) cocurrently rinsing said first bed with high purity key component to remove any co-adsorbed secondary component and void space secondary component from said bed; (c) countercurrently desorbing said first bed by pressure reduction in one or more stages to a subatmospheric pressure to recover a rinse gas for another of said plurality of beds presently undergoing step (b) and a high purity key component product; (d) countercurrently repressurizing said first bed by connecting the effluent end of said first bed at its subatmospheric pressure at the end of step (c) with the effluent end of another of said plurality of beds presently undergoing the adsorption of step (a), and (e) continuing this series of steps with the plurality of beds to form a continuous process for production of high purity key component.
Claim 3
Dependent Claim
29 words
The process of claim 1 wherein the rinse gas recovered from one bed undergoing step (c) is directly used as the rinse gas of another bed undergoing step (b).
Claim 4
Dependent Claim
48 words
The process of claim 1 wherein step (c) has two stages, a first stage ending at ambient pressure in which the desorbed gas is used to rinse a parallel bed and a second stage ending at said subatmospheric pressure in which the desorbed gas is key component product.
Claim 5
Dependent Claim
30 words
The process of claim 1 wherein any water and carbon dioxide contained in the gas mixture is adsorbed in an initial portion of the adsorbent of said plurality of beds.
Claim 6
Dependent Claim
44 words
The process of claim 4 wherein each adsorbent bed contains an adsorbent selective for water and carbon dioxide in the initial portion of the bed adjacent to the influent end and an adsorbent selective for the key component in the remainder of the bed.
Claim 7
Dependent Claim
21 words
The process of claim 1 wherein the bed undergoing step (d) repressurization is repressurized to a pressure of approximately 14.7 psia.
Claim 8
Dependent Claim
23 words
The process of claim 1 wherein step (a) feed is conducted over a pressure variation from approximately 12.7 psia to approximately 14.7 psia.
Claim 9
Dependent Claim
18 words
The process of claim 1 wherein step (c) evacuation is conducted to a pressure of approximately 50-250 torr.
Claim 10
Dependent Claim
17 words
The process of claim 1 wherein the key component product has a purity of at least 95.0%.
Claim 11
Dependent Claim
16 words
The process of claim 1 wherein the key component product has a purity of approximately 99.9%.
Claim 12
Dependent Claim
11 words
The process of claim 1 wherein four parallel beds are utilized.
Claim 13
Dependent Claim
20 words
The process of claim 1 wherein key component recovered in step (c) is supplied to a key component storage vessel.
Claim 14
Dependent Claim
27 words
The process of claim 1 wherein each of the steps (a) feed, (b) rinse, (c) desorption and (d) repressurization is conducted in an equal period of time.
Claim 15
Dependent Claim
24 words
The process of claim 1 wherein an idle step follows the repressurization step in which said first bed is not involved in active operation.
Claim 16
Dependent Claim
11 words
The process of claim 14 wherein three parallel beds are utilized.
Claim 17
Dependent Claim
50 words
The process of claim 14 wherein the total of step (a) feed and step (b) rinse are of the same time duration as the step (c) desorption and the total of step (d) repressurization and said idle step are also of the same time duration as the step (c) desorption.
Claim 18
Dependent Claim
21 words
The process of claim 14 wherein key component recovered in step (c) desorption is supplied to a key component storage vessel.
Claim 19
Dependent Claim
27 words
The process of claim 1 wherein a portion of the secondary component passing through said first bed in step (a) is recovered as a secondary component product.
Claim 20
Dependent Claim
11 words
The process of claim 1 wherein five parallel beds are utilized.
Claim 21
Dependent Claim
25 words
The process of claim 1 wherein the effluent from the rinse of step (b) is recycled and mixed with said gas mixture of step (a).
Claim 22
Dependent Claim
28 words
The process of claim 1 wherein the key component is selected from the group consisting of nitrogen, carbon dioxide, carbon monoxide or lower alkyl hydrocarbons (C 2+ ).
Claim 23
Dependent Claim
18 words
The process of claim 1 wherein the feed gas mixture pressure is at or less than 10 psig.
Claim 24
Dependent Claim
18 words
The process of claim 1 wherein the feed gas mixture pressure is at or less than 5 psig.
Claim 25
Dependent Claim
19 words
The process of claim 1 wherein the key component is carbon dioxide and the adsorbent is sodium X zeolite.
Claim 26
Dependent Claim
19 words
The process of claim 1 wherein the key component is carbon monoxide and the adsorbent is calcium 5A zeolite.
Claim 27
Dependent Claim
23 words
The process of claim 1 wherein the key component is a lower alkyl and the adsorbent is sodium X zeolite or activated carbon.
Claim 28
Dependent Claim
18 words
The process of claim 1 wherein nitrogen is the key component and the adsorbent is calcium X zeolite.
Claim 29
Dependent Claim
17 words
The process of claim 1 wherein step (b) is followed by cocurrent depressurization to approximately 14.7 psia.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-01-08 | 1993-07-10 | 1994-01-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-01-08 | 1997-07-10 | 1998-01-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-01-08 | 2001-07-10 | 2002-01-09 | $7700.00 | Window Closed / Lapsed |