US4890478A
Expired / Lapsed
US
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Gas-in-oil monitoring apparatus and method
Assignee: ABB Inc USA
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Filing: 1987-09-11
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Granted: 1990-01-02
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Expires: 2007-09-11
Abstract
Abstract An on-line gas-in-oil monitoring apparatus and method extracts certain reducing or combustible gases from oil and detects their presence and concentration substantially simultaneously using a sensor. The sensors are sintered metal oxide semi-conductors with adsorbed oxygen. The presence of a reducing or combustible gas proportionally increases the conductivity of the semi-conductor. Any resultant change in conductivity indicates the presence and concentraton of the reducing or combustible gas in the semi-conductor. After the analytical cycle the sensors are regenerated by exposure to oxygen.
Inventors
- 👤 C. Clair Claiborne
- 👤 Robert A. Kurz
- 👤 Henry A. Pearce, Jr.
- 👤 Harry R. Sheppard
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 23:46
CPC Classifications
G; G01; G01N; G01N33/00; G01N33/26; G01N33/28; G01N33/2835; G01N33/2841; G01N33/0004; G01N33/0009; G01N33/0027; G01N33/0031
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
285 words
An on-line gas-in-oil monitoring apparatus for oil-filled electrical apparatus which indicates substantially simultaneously the amount of at least two predetermined gases in the oil comprising: means for separating said predetermined gases from said oil; a sensor housing; means for periodically introducing a sample of said predetermined gases separated from said oil into said housing; a first gas sensing means disposed in said sensor housing which is predominantly sensitive to a first of said predetermined gases; a second gas sensing means disposed in said sensor housing which is predominantly sensitive to a second of predetermined gases; vent means for venting said sensor housing to the atmosphere for purging said predetermined gases from the sensor housing and to admit oxygen to said sensor housing to resensitize said sensing means to said predetermined gases; control means which are responsive to a change in conductivity of said first and second sensing means in response to the presence of said first and second predetermined gases respectively, and generate an indication of the levels of the first and second predetermined gases; said first sensing means is predominantly sensitive to carbon monoxide; said second sensing means is predominantly sensitive to hydrogen; said sensing means are sintered metal oxide semiconductors with adsorbed oxygen; heating means which provide heat or voltage to said sensing means; said heating means provides a first heating voltage to said first sensing means to heat said second sensing means to a temperature which renders said first sensing means sensitive to the first of said predetermined gases; and a second heating voltage to said second sensing means to heat said second sensing means to a temperature which renders said second sensing means sensitive to the second of said predetermined gases.
Claim 2
Dependent Claim
285 words
An on-line gas-in-oil monitoring apparatus for oil-filled electrical apparatus which indicates substantially simultaneously the amount of at least two predetermined gases in the oil comprising: means for separating said predetermined gases from said oil; a sensor housing; means for periodically introducing a sample of said predetermined gases separated from said oil into said housing; a first gas sensing means disposed in said sensor housing which is predominantly sensitive to a first of said predetermined gases; a second gas sensing means disposed in said sensor housing which is predominantly sensitive to a second of predetermined gases; vent means for venting said sensor housing to the atmosphere for purging said predetermined gases from the sensor housing and to admit oxygen to said sensor housing to resensitize said sensing means to said predetermined gases; control means which are responsive to a change in conductivity of said first and second sensing means in response to the presence of said first and second predetermined gases respectively, and generate an indication of the levels of the first and second predetermined gases; said first sensing means is predominantly sensitive to carbon monoxide; said second sensing means is predominantly sensitive to hydrogen; said sensing means are sintered metal oxide semiconductors with adsorbed oxygen; heating means which provide heat or voltage to said sensing means; said heating means provides a first heating voltage to said first sensing means to heat said second sensing means to a temperature which renders said first sensing means sensitive to the first of said predetermined gases; and a second heating voltage to said second sensing means to heat said second sensing means to a temperature which renders said second sensing means sensitive to the second of said predetermined gases.
Claim 3
Dependent Claim
118 words
The apparatus of claim 1 wherein said means for separating said predetermined gases from said oil comprises a first chamber through which said oil flows; a diffusion membrane which defines a portion of said first chamber; said diffusion membrane being constructed of a material which permits the predetermined gases contained in the oil to diffuse through said membrane; a second chamber which is disposed generally adjacent to said diffusion membrane into which said predetermined gases diffuse through said diffusion membrane; and wherein said means for periodically introducing a sample of said predetermined gases into said housing includes a valve means for allowing a sample of said predetermined gases to flow from said second chamber into said sensor housing.
Claim 4
Independent Claim
161 words
A method of providing on-line measurement of a sample of at least two predetermined gases in oil substantially simultaneously comprising: separating said predetermined gases from said oil; providing a sensor housing with at least two sensing means comprised of sintered metal oxide semi-conductors with adsorbed oxygen disposed therein; periodically introducing a sample of said predetermined gases into said sensor housing whereby said sensing means are exposed to said predetermined gases; measuring the conductivity of said sensing means; and regenerating one of said sensing means predominantly sensitive to the presence of hydrogen by heating said sensing means in the presence of oxygen for a recovery period; regenerating the other of said sensing means predominantly sensitive to the presence of carbon monoxide by heating said sensing means at a higher temperature for a first recovery period; heating said sensing means at a lower temperature for a second recovery period; and heating said sensing means at a higher temperature for a third recovery period.
Claim 5
Independent Claim
161 words
A method of providing on-line measurement of a sample of at least two predetermined gases in oil substantially simultaneously comprising: separating said predetermined gases from said oil; providing a sensor housing with at least two sensing means comprised of sintered metal oxide semi-conductors with adsorbed oxygen disposed therein; periodically introducing a sample of said predetermined gases into said sensor housing whereby said sensing means are exposed to said predetermined gases; measuring the conductivity of said sensing means; and regenerating one of said sensing means predominantly sensitive to the presence of hydrogen by heating said sensing means in the presence of oxygen for a recovery period; regenerating the other of said sensing means predominantly sensitive to the presence of carbon monoxide by heating said sensing means at a higher temperature for a first recovery period; heating said sensing means at a lower temperature for a second recovery period; and heating said sensing means at a higher temperature for a third recovery period.
Claim 6
Dependent Claim
31 words
The method of claim 3 including controlling the temperature of said sensing means by means of heating means to provide a means for sensitizing the sensing means to said predetermined gases.
Claim 7
Dependent Claim
26 words
The method of claim 3 including heating the sensing means to different temperatures to sensitize said sensing means to the levels of two different gases respectively.
Claim 8
Dependent Claim
26 words
The method of claim 3 including providing a recovery period of at least about 11 hours during which time period said sensor is exposed to oxygen.
Claim 9
Dependent Claim
22 words
The method of claim 3 including heating said sensing means predominantly sensitive to hydrogen to about 350° C. during an analytical period.
Claim 10
Dependent Claim
21 words
The method of claim 7 including heating said sensing means to a temperature of about 350° C. for said recovery period.
Claim 11
Dependent Claim
14 words
The method of claim 7 including providing an analytical period of about 6 minutes.
Claim 12
Dependent Claim
22 words
The method of claim 3 including heating said sensing means at a temperature of about 350° C. for said first recovery period.
Claim 13
Dependent Claim
22 words
The method of claim 3 including heating said sensing means at a temperature of about 120° C. for said second recovery period.
Claim 14
Dependent Claim
22 words
The method of claim 3 including heating said sensing means at a temperature of about 350° C. for said third recovery period.
Claim 15
Dependent Claim
17 words
The method of claim 10 including providing a first recovery period of at least about 6 minutes.
Claim 16
Dependent Claim
17 words
The method of claim 11 including providing a second recovery period of at least about 10 hours.
Claim 17
Dependent Claim
17 words
The method of claim 12 including providing a third recovery period of at least about 45 minutes.
Claim 18
Dependent Claim
18 words
The method of claim 14 including providing a second recovery period of about 10 hours and 46 minutes.
Claim 19
Dependent Claim
15 words
The method of claim 15 including providing a third recovery period of about 1 hour.
Claim 20
Dependent Claim
14 words
The method of claim 3 including providing an analytical period of about 6 minutes.
Claim 21
Dependent Claim
21 words
The method of claim 18 including heating said sensing means to a temperature of about 120° C. during said analytical period.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-01-01 | 1993-07-03 | 1994-01-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-01-01 | 1997-07-03 | 1998-01-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-01-01 | 2001-07-03 | 2002-01-02 | $7700.00 | Window Closed / Lapsed |