Nitrogen compounds that delay the metathesis polymerization of cycloolefins

Claim 2

A polymerization feed composition comprising: (a) a metathesis polymerizable cycloolefin; (b) a metathesis polymerization catalyst; (c) a catalyst activator comprising an alkyl aluminum compound; and (d) a reaction rate moderator, wherein said reaction moderator is a nitrogen compound represented by the formula: ##STR3## wherein X represents an aryl, alkaryl, or haloaryl group; Y represents an alkyl group or hydrogen and Z represents an alkyl, aralkyl, or cycloalkyl group or hydrogen, and wherein when neither Y nor Z represent hydrogen, X, Y and Z all must represent alkyl groups.

Claim 3

The polymerization feed composition of claim 1 wherein said metathesis polymerizable cycloolefin is a monomer selected from the group consisting of dicyclopentadiene, norbornene, norbornadiene, dimethanohexahydronaphthalene and substituted derivatives of said monomers, or a mixture of two or more of said monomers.

Claim 4

The polymerization feed composition of claim 2 wherein said metathesis polymerizable cycloolefin is dicyclopentadiene.

Claim 5

The polymerization feed composition of claim 3 wherein said reaction rate moderator comprises an additive selected from the group consisting of alkylarylamines and aryl amines.

Claim 6

The composition of claim 4 wherein the reaction rate moderator is an alkylarylamine selected from the group consisting of N-ethylaniline and aniline.

Claim 7

The composition of claim 5 wherein dichlorodiphenylmethane is added to said metathesis polymerization catalyst.

Claim 8

In a process for preparing molded objects wherein a liquid reaction mass comprising a metathesis polymerizable cycloolefin, a metathesis polymerization catalyst, an alkyl aluminum catalyst activator and a reaction rate moderator are charged to a mold in which polymerization will take place, the improvement wherein said reaction rate moderator comprises: ##STR4## wherein X represents an aryl, alkaryl, or haloaryl group; Y represents an alkyl group or hydrogen and Z represents an alkyl, aralkyl, or cycloalkyl group or hydrogen, and wherein when neither Y nor Z represents hydrogen, X, Y and Z all must represent alkyl groups.

Claim 9

In a process for preparing molded objects wherein a liquid reaction mass comprising a metathesis polymerizable cycloolefin, a metathesis polymerization catalyst, an alkyl aluminum catalyst activator and a reaction rate moderator are charged to a mold in which polymerization will take place, the improvement wherein said reaction rate moderator comprises: ##STR4## wherein X represents an aryl, alkaryl, or haloaryl group; Y represents an alkyl group or hydrogen and Z represents an alkyl, aralkyl, or cycloalkyl group or hydrogen, and wherein when neither Y nor Z represents hydrogen, X, Y and Z all must represent alkyl groups.

Claim 10

The process of claim 7 wherein said cycloolefin is a monomer selected from the group consisting of dicyclopentadiene, norbornene, norbornadiene, dimethanooctahydronaphthalene, dimethanohexahydronaphthalene and substituted derivatives of said monomers, or a mixture of two or more of said monomers.

Claim 11

The process of claim 8 wherein said cycloolefin is dichclopentadiene.

Claim 12

The process of claim 9 wherein said reaction rate moderator is selected from the group consisting of alkylarylamines and aryl amines.

Claim 13

The process of claim 10 wherein said alkylarylamine is selected from the group consisting of aniline and N-ethylaniline.

Claim 14

The process of claim 7 wherein dichlorodiphenylmethane is added to said methatesis polymerization catalyst.