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US4883825A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the manufacture of low density, flexible polyurethane foams

Assignee: Union Carbide Chemicals and Plastics Technology LLC
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Filing: 1987-12-30
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Granted: 1989-11-28
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Expires: 2007-12-30
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Abstract

Abstract A process for the manufacture of low density flexible polymethane foam via a catalyzed reaction of a highly reactive, high ethylene oxide, high functionality polyol, a hydrophilic polyhydric compound, water and polyisocyanates.

Inventors

  • 👤 Paul M. Westfall
  • 👤 Frank E. Critchfield
  • 👤 William A. Gill

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 21:38
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/02; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/48; C08G18/30; C08G18/32; C08G18/4833; C08G18/4837; C08G18/4841; C08G18/63; C08G18/632; C08G18/65; C08G18/6552; C08G18/6558; C08G18/66; C08G18/6666; C08G18/667; C08G18/6674; C08G18/6677; C08L; C08L75/00; C08G2110/00; C08G2110/0008; C08G2110/0041; C08G2110/005; C08G2110/0083; C08J2375/00; C08J2375/04; C08J2375/08

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 186 words
A process for the manufacture of low density, flexible polyurethane foams which comprises reacting: (a) a polymer/polyol formed insitu in a polyether polyol having at least 85 percent primary hydroxyl groups, a nominal functionality of at least three, and an ethylene oxide content of from 8 to 30 percent of the polyether polyol; (b) 0.1 to 5 parts per hundred parts of polyol of a polyhydric material selected from the group consisting of glycerine, trimethylol propane, sorbitol, erythritol, sucrose, simple carbohydrates, and low molecular weight polyethylene oxide polyols which is reactive with isocyanate groups but not more reactive with an isocyanate group than are the primary hydroxyl groups on the polyether polyol (a), said polyhydric material also being sufficiently hydrophillic so as to be at least 40 weight percent soluble in 25° C. water; (c) water in an amount from 4.0 to 20 parts per hundred parts of polyol; (d) an organic polyisocyanate; and (e) 0.001 to 5 percent, based on the weight of (a), b, c and d, of a catalyst for the reaction of (a) and (d) in the presence of a foam stabilizer.
Claim 2
Dependent Claim 186 words
A process for the manufacture of low density, flexible polyurethane foams which comprises reacting: (a) a polymer/polyol formed insitu in a polyether polyol having at least 85 percent primary hydroxyl groups, a nominal functionality of at least three, and an ethylene oxide content of from 8 to 30 percent of the polyether polyol; (b) 0.1 to 5 parts per hundred parts of polyol of a polyhydric material selected from the group consisting of glycerine, trimethylol propane, sorbitol, erythritol, sucrose, simple carbohydrates, and low molecular weight polyethylene oxide polyols which is reactive with isocyanate groups but not more reactive with an isocyanate group than are the primary hydroxyl groups on the polyether polyol (a), said polyhydric material also being sufficiently hydrophillic so as to be at least 40 weight percent soluble in 25° C. water; (c) water in an amount from 4.0 to 20 parts per hundred parts of polyol; (d) an organic polyisocyanate; and (e) 0.001 to 5 percent, based on the weight of (a), b, c and d, of a catalyst for the reaction of (a) and (d) in the presence of a foam stabilizer.
Claim 3
Dependent Claim 16 words
The process of claim 1 wherein the polyhydric material is completely water soluble at 25 C.
Claim 4
Dependent Claim 11 words
The process of claim 1 wherein the polyhydric material is glycerine.
Claim 5
Dependent Claim 25 words
The process of claim 1 wherein the polyhydric material is employed in an amount equal to 0.5 to 2.5 parts per hundred parts of polyol.
Claim 6
Dependent Claim 21 words
The process of claim 1 wherein the water level employed ranges from 6.5 to 8 parts per hundred parts of polyol.
Claim 7
Dependent Claim 10 words
The process of claim 1 wherein the catalyst is hexamethylenetetramine.
Claim 8
Dependent Claim 12 words
The process of claim, 6 wherein the hexamethylenetetramine is dissolved in glycerine.
Claim 9
Dependent Claim 16 words
The process of claim 1 wherein the organic polyisocyanate is TDI, MDI or a mixture thereof.
Claim 10
Dependent Claim 14 words
The process of claim 1 wherein the foam stabilizer is a polysiloxane-polyoxyalkylene block copolymer.
Claim 11
Dependent Claim 28 words
The process of claim 9 wherein the foam stabilizer is employed in an amount ranging from 0.001 to 5.0 percent based on the weight of the reaction mixture.
Claim 12
Dependent Claim 17 words
The process of claim 1 wherein the foam density is less than 2.0 pounds per cubic foot.
Claim 13
Dependent Claim 11 words
A flexible polyurethane foam manufactured by the process of claim 1.
Claim 14
Dependent Claim 19 words
The polyurethane foam of claim 12 is having a foam density of less than 2.0 pounds per cubic foot.
Claim 15
Dependent Claim 18 words
The process of claim 13 wherein the foam density is no greater than 1.5 pound per cubic foot.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-11-27 1993-05-29 1993-11-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-11-27 1997-05-29 1997-11-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-11-27 2001-05-29 2001-11-28 $7700.00 Window Closed / Lapsed

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